Porous electronic current collector bodies for electrochemical cell configurations

• US 4,833,045 A
• Filed: 12/10/1987
• Issued: 05/23/1989
• Est. Priority Date: 12/10/1987
• Status: Expired due to Fees

• Current Assignee: Westinghouse Electric Company LLC (Brookfield Asset Management Incorporated)
• Original Assignee: Westinghouse Electric Company LLC (Brookfield Asset Management Incorporated)
• Inventors: Pollack, William, Reichner, Philip
• Primary Examiner(s): Kalafut, Stephen J.
• Application Number:
  US07/130,918
• Time in Patent Office: 530 Days
• Field of Search: 429/30-32, 252/513
• US Class Current: 429/468
• CPC Class Codes: H01B 1/16 the conductive material comprising metals or alloys
• CPC Class Codes: H01M 2008/1293 Fuel cells with solid oxide electrolytes
• CPC Class Codes: H01M 2300/0074 Ion conductive at high temperature
• CPC Class Codes: H01M 8/0232 Metals or alloys
• CPC Class Codes: H01M 8/0245 in the form of layered or coated products
• CPC Class Codes: H01M 8/0247 characterised by the form characterised by a channel configuration H01M8/0258
• CPC Class Codes: H01M 8/0252 tubular
• CPC Class Codes: H01M 8/243 Grouping of unit cells of tubular or cylindrical configuration
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A high-temperature, solid electrolyte electrochemical cell configuration is made comprising a plurality of elongated electrochemical cells 1, having inner electrodes 3, outer electrodes 6 and solid electrolyte 4 therebetween, the cells being electronically connected in series and parallel by flexible, porous, fibrous strips 7, where the strips contain flexible, electronically conductive fibers bonded together and coated with a refractory oxide, and where the oxide coating is effective to prevent additional bonding of fibers during electrochemical cell operation at high temperatures.

Claims

1. A high-temperature solid electrolyte electrochemical cell configuration, comprising a plurality of elongated electrochemical cells, the cells having inner electrodes and outer electrodes, with solid electrolyte therebetween and being elecronically connected by porous, electronically conductive, fibrous strips, the improvement characterized in that the fibrous strips are from 80% to 95% porous, and comprise flexible, electronically conductive fibers selected from the group consisting of nickel fibers and cobalt fibers bonded together and coated with a refractory oxide, where the fibrous strips electronically connect the inner electrode of one cell to the outer electrode of the next adjacent cell through interconnection material disposed on the inner electrodes, and also electronically connect the outer electrode of one cell to the outer electrode of the next adjacent cell, and where the refractory oxide is effective to prevent additional bonding of fibers during electrochemical cell operation at high temperatures.

2. The high-temperature cell configuration of claim 1, where the fibrous strips consist essentially of fibers selected from the group consisting of:

(a) nickel fibers and cobalt fibers bonded together and coated with a refractory oxide having a melting point over 1500°

C., and (b) fibers of refractory oxide having a melting point over 1500°

C., where from 70 wt. % to 100 wt. % of the fibers are fibers coated with refractory oxide.

3. The high-temperature cell configuration of claim 1, where all of the fibers of the fibrous strips are nickel fibers having a coating of refractory oxide with a melting point over 1500°

C.

4. The high-temperature cell configuration of claim 1, where the cells are fuel cells.

5. A flexible, 80% to 98% porous, electronically conducting fibrous body, in elongated strip form, where the fibers in the body are bonded together at their contact points and comprise electronically conducting nickel fibers, where the bonded fibers are coated with a refractory oxide selected from the group consisting of aluminum oxide, zirconium oxide, and magnesium oxide, and where two opposite exterior sides of the fibrous strip are free of oxide.