Fiber optic fluid detector

• US 4,834,497 A
• Filed: 02/27/1987
• Issued: 05/30/1989
• Est. Priority Date: 02/27/1987
• Status: Expired due to Term

• Current Assignee: United States Department of Energy (Government of the United States of America)
• Original Assignee: The United States of America As Represented By The Secretary of Agriculture
• Inventors: Angel, S. Michael
• Primary Examiner(s): Sikes, William L.
• Assistant Examiner(s): Gonzalez, Frank
• Application Number:
  US07/019,841
• Time in Patent Office: 823 Days
• Field of Search: 350/96.10, 350/96.15, 350/96.29, 350/96.30, 350/96.34, 250/227, 356/73.1, 356/432, 356/433, 356/435, 356/448
• US Class Current: 385/12
• CPC Class Codes: B01D 2015/3895 using light
• CPC Class Codes: G01N 2021/432 comprising optical fibres
• CPC Class Codes: G01N 2021/6434 Optrodes
• CPC Class Codes: G01N 21/648 using evanescent coupling or surface plasmon coupling for the excitation of fluorescence
• CPC Class Codes: G01N 21/7703 using reagent-clad optical fibres or optical waveguides using measurement of total internal reflection or attenuated total reflection G01N21/552; optical fibres or waveguides per se G02B
• CPC Class Codes: G01N 30/02 Column chromatography
• CPC Class Codes: G02B 6/02 Optical fibres with cladding with or without a coating

Abstract

Particular gases or liquids are detected with a fiber optic element (11, 11a to 11j) having a cladding or coating of a material (23, 23a to 23j) which absorbs the fluid or fluids and which exhibits a change of an optical property, such as index of refraction, light transmissiveness or fluoresence emission, for example, in response to absorption of the fluid. The fluid is sensed by directing light into the fiber optic element and detecting changes in the light, such as exit angle changes for example, that result from the changed optical property of the coating material. The fluid detector (24, 24a to 24j) may be used for such purposes as sensing toxic or explosive gases in the atmosphere, measuring ground water contamination or monitoring fluid flows in industrial processes, among other uses.

Claims

1. In fiber optic apparatus for detecting a predetermined fluid or any of a predetermined group of fluids, said apparatus having at least one fiber optic element which includes a light transmissive core and a coating thereon, a light source positioned to direct light into said fiber optic element for transmission therealong by repetitive internal reflections at the interface between said core and coating, and light detection means for detecting light which is emitted from said fiber optic element, the improvement comprising:

said fiber optic element being absorptive of said fluid or fluids, said coating along at least a portion of said core being a material which is absorptive of said fluid or fluids and which has an optical property that changes upon absorption of said fluid or fluids, and wherein said light detection means detects changes in a property of said emitted light that are caused by said changes of the optical property of the coating; and

wherein said coating material has an index of refraction that changes upon absorption of said fluid or fluids and wherein said light is emitted from a first end of said fiber optic element, and wherein said light detection means includes a light detector spaced apart from said end of said fiber optic element, further including an opaque shield disposed between said first end and said light detector and having a configuration which blocks a portion of said emitted light from said detector.

2. The fiber optic apparatus of claim 1 wherein the light emitted from said first end of said fiber optic element diverges to define a cone of light and wherein said opaque shield has a light transmissive passage therethrough that has an area smaller than the area of said cone of light at the plane of said shield.

3. The fiber optic apparatus of claim 1 wherein the light emitted from said first end of said fiber optic element diverges to define a cone of light and wherein said opaque shield has an area smaller than the area of said cone of light at the plane of said shield.

4. In fiber optic apparatus for detecting a predetermined fluid or any of a predetermined group of fluids, said apparatus having at least one fiber optic element which includes a light transmissive core and a coating thereon, a light source positioned to direct light into said fiber optic element for transmission therealong by repetitive internal reflections at the interface between said core and coating, and light detection means for detecting light which is emitted from said fiber optic element, the improvement comprising:

said fiber optic element being absorptive of said fluid or fluids, said coating along at least a portion of said core being a material which his absorptive of said fluid or fluids and which has an optical property that changes upon absorption of said fluid or fluids, and wherein said light detection means detects changes in a property of said emitted light that are caused by said changes of the optical property of the coating; and

wherein said light is emitted from a first end of said fiber optic element and diverges therefrom to define a cone of light having an axis which is coincident with the axis of said first end of said fiber optic element, and wherein said light detection means includes a light detector having a light sensitive region that is offset from said axis of said cone of light by a distance at least equal to the radius of said core of said fiber optic element.

5. In fiber optic apparatus for detecting a predetermined fluid or any of a predetermined group of fluids, said apparatus having at least one fiber optic element which includes a light transmissive core and a coating thereon, a light source positioned to direct light into said fiber optic element for transmission therealong by repetitive internal reflections at the interface between said core and coating, and light detection means for detecting light which is emitted from said fiber optic element, the improvement comprising:

said fiber optic element being absorptive of said fluid or fluids, said coating along at least a portion of said core being a material which is absorptive of said fluid or fluids and which has an optical property that changes upon absorption of said fluid or fluids, and wherein said light detection means detects changes in a property of said emitted light that are caused by said changes of the optical property of the coating; and

an opaque housing having at least one fluid entry opening, and a light baffle positioned to inhibit entry of external light into said housing, and wherein at least a portion of said fiber optic element having said fluid absorptive coating material thereon is disposed within said housing.

6. In fiber optic apparatus for detecting a predetermined fluid or any of a predetermined groups of fluids, said apparatus having at least one fiber optic element which includes a light transmissive core and a coating thereon, a light source positioned to direct light into said fiber optic element for transmission therealong by repetitive internal reflections at the interface between said core and coating, and light detection means for detecting light which is emitted from said fiber optic element, the improvement comprising:

said fiber optic element being absorptive of said fluid or fluids, said coating along at least a portion of said core being a material which is absorptive of said fluid or fluids and which has an optical property that changes upon absorption of said fluid or fluids, and wherein said light detection means detects changes in a property of said emitted light that are caused by said changes of the optical property of the coating; and

wherein said light detection means includes a first light detector producing a first output voltage that varies in accordance with variations in the amount of light received by the first light detector, further including an additional fiber optic element having a core with coating material thereon that does not absorb said fluid or fluids, means for directing a portion of the light from said light source into said additional fiber optic element, a second light detector positioned to receive light which is emitted from said additional fiber optic element and producing a second output voltage that varies in accordance with variations in the light received by the second light detector, means for producing a ratio signal that varies in accordance with variations of the ratio of said first and second output voltages, and means for indication changes in said ratio signal and wherein said means for directing a portion of the light from said light source into said additional fiber optic element directs substantially one half of said light into said additional fiber optic element, and wherein said fiber optic elements have substantially similar dimensions.

7. In fiber optic apparatus for detecting a predetermined fluid or any of a predetermined group of fluids, said apparatus having at least one fiber optic element which includes a light transmissive core and a coating thereon, a light source positioned to direct light into said fiber optic element for transmission therealong by repetitive internal reflections at the interface between said core and coating, and light detection means for detecting light which is emitted from said fiber optic element, the improvement comprising:

said fiber optic element being absorptive of said fluid or fluids, said coating along at least a portion of said core being a material which is absorptive of said fluid or fluids and which has an optical property that changes upon absorption of said fluid or fluids, and wherein said light detection means detects changes in a property of said emitted light that are caused by said changes of the optical property of the coating; and

wherein said light source and said light detection means are both located at a first end of said fiber optic element, further including a mirror disposed at the opposite end of said fiber optic element, said mirror being oriented to return light back to said first end of said fiber optic element and wherein said mirror is spaced apart from said opposite end of said fiber optic element and is located to intercept and return only a portion of the light which is emitted from said opposite end.

8. In a fiber optic apparatus for detecting a predetermined fluid or any of a predetermined group of fluids, said apparatus having at least one fiber optic element which includes a light transmissive core and a coating thereon, a light source positioned to direct light into said fiber optic element for transmission therealong by repetitive internal reflections at the interface between said core and coating, and light detection means for detecting light which is emitted from said fiber optic element, the improvement comprising:

said fiber optic element being absorptive of said fluid or fluids, said coating along at least a portion of said core being a material which is absorptive of said fluid or fluids and which has an optical property that changes upon absorption of said fluid or fluids, and wherein said light detection means detects changes in a property of said emitted light that are caused by said changes of the optical property of the coating; and

wherein said light source and said light detection means are located at a first end of said fiber optic element and said light is transmitted to the opposite end thereof, further including a return fiber optic element with a first end positioned to receive light from said opposite end of said fiber optic element and with a second end at the first end of the fiber optic element positioned to transmit said light back to said light detection means and wherein said absorptive coating material is on a portion of said core that is remote from said light source and light detection means and wherein portions of said core that are closer to said light source and light detection means are coated with non-absorptive coating material, said return fiber optic element also having a coating of non-absorptive coating material.

9. In fiber optic apparatus for detecting a predetermined fluid or any of a predetermined group of fluids, said apparatus having at least one fiber optic element which includes a light transmissive core and a coating thereon, a light source positioned to direct light into said fiber optic element for transmission therealong by repetitive internal reflections at the interface between said core and coating, and light detection means for detecting light which is emitted from said fiber optic element, the improvement comprising:

said fiber optic element being absorptive of said fluid or fluids, said coating along at least a portion of said core being a material which is absorptive of said fluid or fluids and which has an optical property that changes upon absorption of said fluid or fluids, and wherein said light detection means detects changes in a property of said emitted light that are caused by said changes of the optical property of the coating; and

wherein said light source and said light detection means are located at a first end of said fiber optic element and said light is transmitted to the opposite end thereof, further including a return fiber optic element with a first end positioned to receive light from said opposite end of said fiber optic element and with a second end at the first end of the fiber optic element positioned to transmit said light back to said light detection means and wherein the light emitted from said opposite end diverges therefrom to define a cone of light, and wherein the light input end of said return fiber optic element is spaced apart from said opposite end and intercepts only a portion of said cone of light.

10. In fiber optic apparatus for detecting a predetermined fluid or any of a predetermined group of fluids, said apparatus having at least one fiber optic element which includes a light transmissive core and a coating thereon, a light source positioned to direct light into said fiber optic element for transmission therealong by repetitive internal reflections at the interface between said core and coating, and light detecting means for detecting light which is emitted from said fiber optic element, the improvement comprising:

said fiber optic element being absorptive of said fluid or fluids, said coating along at least a portion of said core being a material which is absorptive of said fluid or fluids and which has an optical property that changes upon absorption of said fluid or fluids, and wherein said light detection means detects changes in a property of said emitted light that are caused by said changes of the optical property of the coating; and

wherein said coating material is a material which produces fluorescent light in response to light from said light source and which exhibits a change light transmissivity in response to absorption of said fluid or fluids, and wherein said light detection means detects said fluorescent light.

11. The fiber optic apparatus of claim 10 wherein said light source is positioned to direct light into a first end of said fiber optic element, further including an opaque end cap disposed at the opposite end of said fiber optic element, and means for directing fluorescent light that is emitted from said first end of said fiber optic element to said light detection means.

12. The fiber optic apparatus of claim 10 wherein said coating material is a polymeric substance impregnated with a fluorescent organic dye.

13. In fiber optic apparatus for detecting a predetermined fluid or any of a predetermined group of fluids, said apparatus having at least one fiber optic element which includes a light transmissive core and a coating thereon, a light source positioned to direct light into said fiber optic element for transmission therealong by repetitive internal reflections at the interface between said core and coating, and light detection means for detecting light which is emitted from said fiber optic element, the improvement comprising:

said fiber optic element being absorptive of said fluid or fluids, said coating along at least a portion of said core being a material which is absorptive of said fluid or fluids and which has an optical property that changes upon absorption of said fluid or fluids, and wherein said light detection means detects changes in a property of said emitted light that are caused by said changes of the optical property of the coating; and

wherein said coating material on said fluid absorbent fiber optic element is a material which exhibits changes of light transmissivity in response to absorption of said fluid or fluids, further including at least one additional fiber optic element disposed against said coating material, and wherein said light detection means detects light which leaks into said additional fiber optic element through said coating material.

14. The fiber optic apparatus of claim 13 wherein said fluid absorbent fiber optic element and said additional fiber optic element each have first and second ends, said light source being positioned to direct light into said first end of said fluid absorbent fiber optic element and wherein said light detection means detects light emitted from said first end of said additonal fiber optic element, further including first and second opaque end caps disposed at said second ends of fluid absorbent fiber optic element and said additional fiber optic element respectively.

15. The fiber optic apparatus of claim 14 wherein each of said end caps is a mirror.

16. The fiber optic apparatus of claim 13 wherein at least a portion of said additonal fiber optic element has said fluid absorptive coating material thereon and wherein said coating materials of said fluid absorbent fiber optic element and said additional fiber optic element are fused together.