Phosphor, Radiation image recording and reproducing method and radiation image storage panel

• US 4,835,398 A
• Filed: 11/04/1987
• Issued: 05/30/1989
• Est. Priority Date: 07/10/1984
• Status: Expired due to Term

• Current Assignee: Fuji Photo Film Co Limited (Fujifilm Holdings Corporation)
• Original Assignee: Fuji Photo Film Co Limited (Fujifilm Holdings Corporation)
• Inventors: Nakamura, Takashi
• Primary Examiner(s): Fields, Carolyn E.
• Assistant Examiner(s): HANIG, RICHARD E
• Application Number:
  US07/119,202
• Time in Patent Office: 573 Days
• Field of Search: 250/327.2, 250/484.1, 252/301.4 H
• US Class Current: 250/484.4
• CPC Class Codes: C09K 11/7773 with alkali or alkaline earth metal
• CPC Class Codes: G21K 4/00 Conversion screens for the conversion of the spatial distribution of X-rays or particle radiation into visible images, e.g. fluoroscopic screens photographic processes using X-ray intensifiers G03C5/17; discharge tubes comprising luminescent screens H01J1/62; cathode ray tubes for X-ray conversion with optical output H01J31/50

Abstract

A cerium activated rare earth halide phosphor having the formula (I):

LnX.sub.3 ·aM.sup.I X'"'"':xCe.sup.3+                 (I)

in which Ln is at least one rare earth element selected from the group consisting of Y, La, Gd and Lu; M^I is at least one alkali metal selected from the group consisting of Li, Na, K, Cs and Rb; each of X and X'"'"' is at least one halogen selected from the group consisting of Cl, Br and I; and a and x are numbers satisfying the conditions of O<a≦10.0 and O<x≦0.2, respectively. A process for the preparation of said phosphor, a radiation image recording and reproducing method utilizing said phosphor, and a radiation image storage panel employing said phosphor are also disclosed.

Claims

1. A radiation image recording and reproducing method comprising steps of:

(i) causing a cerium activated rare earth halide phosphor having the formula (I);

LnX₃ ·

aM^I X'"'"';

Ce³⁺ (I)

in which Ln is at least one rare earth element selected from the group consisting of Y, La, Gd and Lu;

M^I is at least one alkali metal selected from the group consisting of Li, Na, K, Cs and Rb;

each of X and X;

is at least one halogen selected from the group consisting of Cl, Br and I; and

a and x are numbers satisfying the conditions of 0<

a≦

10.0 and 0<

×

0.2, respectively. to absorb a radiation having passed through an object or having radiated from an object;

(ii) exciting said stimulable phosphor with an electromagnetic wave having a wavelength within the range of 500-850 nm to release the radiation energy stored therein as light emission; and

(iii) detecting the emitted light.

2. The radiation image recording and reproducing method as claimed in claim 1, in which a in the formula (I) is a number satisfying the condition of 0.1≦

a≦

2.0.

3. The radiation image recording and reproducing method as claimed in claim 2, in which a in the formula (I) is a number satisfying the condition of 0.2≦

a≦

1.0.

4. The radiation image recording and reproducing method as claimed in claim 1, in which Ln in the formula (I) is at least one rare earth element selected from the group consisting of Y and La.

5. The radiation image recording and reproducing method as claimed in claim 1, in which M^I in the formula (I) is at least one alkali metal selected from the group consisting of Cs and Rb.

6. The radiation image recording and reproducing method as claimed in claim 1, in which each of X and X'"'"' in the formula (I) is Cl or Br, and X≠

X".

7. The radiation image recording and reproducing method as claimed in claim 1, in which x in the formula (I) is a number satisfying the condition of 10^-5 ≦

x≦

10^-2.

8. The radiation image recording and reproducing method as claimed in claim 1, in which the said electromagnetic wave is one having a wavelength within the range of 500-700 nm.

9. The radiation image recording and reproducing method as claimed in claim 1, in which said electromagnetic wave is a laser beam.

10. A radiation image storage panel comprising a support and a phosphor layer provided thereon which comprises a binder and a stimulable phosphor dispersed therein, in which said phosphor layer contains a cerium activated rare earth halide phosphor having the formula (I):

space="preserve" listing-type="equation">LnX.sub.3 ·

aM.sup.I X'"'"';

xCe.sup.3+ (I)

in which Ln is at least one rare earth element selected from the group consisting of Y, La, Gd and Lu;

M^I is at least one alkali metal selected from the group consisting of Li, Na, K, Cs and Rb;

each of X and X'"'"' is at least one halogen selected from the group consisting of Cl, Br and I; and

a and x are numbers satisfying the conditions of 0≦

a≦

10.0 and 0<

x≦

0.2, respectively.

11. The radiation image storage panel as claimed in claim 10, in which a in the formula (I) is a number satisfying the condition of 0.1≦

a≦

2.0.

12. The radiation image storage panel as claimed in claim 11, in which a in the formula (I) is a number satisfying the condition of 0.2≦

a≦

1.0.

13. The radiation image storage panel as claimed in claim 10, in which Ln in the formula (I) is at least one rare earth element selected from the group consisting of Y and La.

14. The radiation image storage panel as claimed in claim 10, in which M^I in the formula (I) is at least one alkali metal selected from the group consisting of Cs and Rb.

15. The radiation image storage panel as claimed in claim 10, in which each of X and X'"'"' in the formula (I) is Cl or Br, and X≠

X'"'"'.

16. The radiation image storage panel as claimed in claim 10, in which x in the formula (I) is a number satisfying the condition of 10^-5 ≦

x≦

10^-2.