Zeolite beta containing hydrocarbon conversion catalyst of stability

• US 4,837,396 A
• Filed: 12/11/1987
• Issued: 06/06/1989
• Est. Priority Date: 12/11/1987
• Status: Expired due to Fees

• Current Assignee: Mobil Oil Corporation (Exxon Mobil Corporation)
• Original Assignee: Mobil Oil Corporation (Exxon Mobil Corporation)
• Inventors: Herbst, Joseph A., Huang, Yun-Yang
• Primary Examiner(s): DEES, CARL
• Application Number:
  US07/131,595
• Time in Patent Office: 543 Days
• Field of Search: 502/64, 502/67, 502/68
• US Class Current: 502/67
• CPC Class Codes: B01J 2229/26 to stabilize the total catalyst structure
• CPC Class Codes: B01J 2229/36 Steaming
• CPC Class Codes: B01J 2229/42 Addition of matrix or binder particles
• CPC Class Codes: B01J 29/084 Y-type faujasite
• CPC Class Codes: B01J 29/7007 Zeolite Beta
• CPC Class Codes: B01J 29/7057 Zeolite Beta
• CPC Class Codes: B01J 29/80 Mixtures of different zeolites
• CPC Class Codes: C10G 11/05 Crystalline alumino-silicates, e.g. molecular sieves

Abstract

Hydrocarbon conversion catalysts containing zeolite beta as a catalytically active component, either on its own or with other zeolites, especially faujasites such as ultrastable zeolite Y (USY) are produced by including a metal cationic complex compound such as aluminum hydroxychloride or aluminum zirconium hydroxychloride as a stabilizing component to improve the hydrothermal stability and physical strength of the catalyst. The zeolites may be formulated into catalysts for catalytic cracking, hydrocracking, dewaxing, alkylation, isomerization, hydration and other hydrocarbon conversion processes using porous matrix materials such as silica, silica alumina or clays.

Claims

1. A method of improving the hydrothermal stability of a zeolite beta hydrocarbon conversion catalyst which method comprises compositing zeolite beta with a stabilizing compound which comprises a hydroxychloride of aluminum.

2. A method according to claim 1 in which the stabilizing compound comprises aluminum hydroxychloride.

3. A method according to claim 1 in which the stabilizing compound comprises aluminum zirconium hydroxychloride or glycine aluminum zirconium hydroxychloride.

4. A method according to claim 1 in which the stabilizing compound comprises aluminum hydroxychloride of the formula [Al₂ (OH)₅ Cl]_x.

5. A method according to claim 1 in which the stabilizing compound comprises aluminum zirconium hydroxychloride of the formula:

Al₃ Zr(OH)₉ Cl₄.

6. A method according to claim 1 in which a porous matrix material is composited with the zeolite beta and the stabilizing compound.

7. A method according to claim 6 in which the porous matrix material is composited with the zeolite and the stabilizing compound and the composite so produced is calcined.

8. A method according to claim 1 in which a second zeolite having cracking activity is composited with the zeolite beta and the stabilizing compound.

9. A method according to claim 8 in which the second zeolite is a large pore size zeolite.

10. A method according to claim 8 in which the large pore size zeolite is zeolite Y.

11. A method according to claim 8 in which the large pore size zeolite is ZSM-20.

12. A method according to claim 8 in which the second zeolite is an intermediate pore size zeolite.

13. A method according to claim 8 in which the zeolite beta, the second zeolite and the stabilizing compound are composited with a matrix material comprising a synthetic metal oxide or oxides, a clay or a mixture of a synthetic metal oxide or oxides and a clay.