Method for producing buried regions of raised refractive index in a glass member by ion exchange

• US 4,842,629 A
• Filed: 11/12/1987
• Issued: 06/27/1989
• Est. Priority Date: 12/01/1986
• Status: Expired due to Fees

• Current Assignee: Siemens AG
• Original Assignee: Siemens AG
• Inventors: Thoma, Christoph, Clemens, Peter, Michel, Herbert
• Primary Examiner(s): Schor, Kenneth M.
• Application Number:
  US07/119,563
• Time in Patent Office: 593 Days
• Field of Search: 65/17, 65/30.1, 65/30.11, 65/30.13, 65/31, 65/60.1, 65/60.51, 65/61, 65/3.14, 156/663, 156/655, 156/657
• US Class Current: 65/30.13
• CPC Class Codes: C03C 21/00 Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
• CPC Class Codes: C03C 23/00 Other surface treatment of glass not in the form of fibres or filaments
• CPC Class Codes: C23F 1/14 Aqueous compositions
• CPC Class Codes: G02B 6/1345 using ion exchange ion exchange in glass C03C21/00

Abstract

An improvement for a method of producing buried regions of raised refractive index in a glass member by ion exchange characterized by removing a titanium mask from the glass member after a first ion exchange to raise the refractive index of exposed portions of the glass member with an EDTA disodium etching solution followed by a slight material erosion of the glass after removal of the titanium mask prior to an implementation of a second field-assisted ion exchange.

Claims

1. In a method for producing a buried region of a raised refractive index in a glass member by ion exchange process, said method comprising providing a glass member having one surface provided with a mask of a titanium coating to block the penetration of the ions from

a salt melt of refractive-index-raising ions into the glass and said one surface of said glass member having surface areas free of the titanium coating, conducting a first field-assisted ion exchange having an ion for raising the refractive index of the glass coming from a salt melt contacting the exposed surfaces of the glass through the mask to thereby raise the refractive index of the glass immediately beneath the exposed surface portions

and thus provide regions of raised refrative index immediately beneath the exposed surface portions, then etching away the titanium coating with an etching solution and then burying the regions of raised refractive index by a second field-assisted ion exchange with another ion contacting the surface of the glass member containing the regions of raised refractive index, said another ion having a neutral effect with regard to the refractive index of the glass, the improvements comprising the step of etching away the titanium coating which has been exposed to a hot salt melt of the first ion exchange being etched away with an

ethylene dinitrilo tetraacetic acid (EDTA) disodium etching solution, and then removing any ion barrier on the surface free of the titanium coating by creating a slight material erosion of the surface freed of the titanium coating without deteriorating the regions of the raised refractive index at the surface prior to implementing the second field-assisted ion exchange step.

2. In a method according to claim 1, wherein the etching solution contains 200 ml of H₂ O and at least 0.1 g of EDTA disodium which has a chemical formula of C₁₀ H₁₄ N₂ Na₂ 0₈.2H₂ O.

3. In a method according to claim 2, wherein the etching solution which also contains additions of H₂ O₂ and NH₃.

4. In a method according to claim 2, wherein the etching solution also includes an addition of NH₃.

5. In a method according to claim 1, wherein the etching solution is composed of 200 ml H₂ O, 0.1 g-25 g of EDTA disodium, 0 g-80 g H₂ O₂ and 0 g-80 g NH₃.

6. In a method according to claim 1, wherein the step of slight material erosion comprises polishing the surface of the glass member which is freed of the titanium coating.

7. In a method according to claim 1, wherein the step of slight material erosion is produced by briefly etching the surface of the glass freed of the titanium coating.

8. In a method according to claim 1, wherein the step of slight material erosion is produced by dry-etching the surface of the glass freed of the titanium coating.