Stabilized fabric softening built detergent composition containing enzymes

• US 4,842,769 A
• Filed: 09/02/1987
• Issued: 06/27/1989
• Est. Priority Date: 07/26/1985
• Status: Expired due to Fees

• Current Assignee: Colgate-Palmolive Company
• Original Assignee: Colgate-Palmolive Company
• Inventors: Shulman, Jan E., Ramachandran, Pallassana
• Primary Examiner(s): WILLIS JR, PRINCE E
• Application Number:
  US07/153,362
• Time in Patent Office: 664 Days
• Field of Search: 252/8.6, 252/8.7, 252/174.12, 252/174.21, 252/174.25, 252/532, 252/534, 252/539, 252/546, 252/DIG. 12, 252/DIG. 14
• US Class Current: 510/321
• CPC Class Codes: C11D 3/1266 in liquid compositions
• CPC Class Codes: C11D 3/38663 Stabilised liquid enzyme compositions

Abstract

A stabilized enzyme-containing built liquid detergent is provided comprising

(a) from about 5 to 20%, by weight, of one or more surface active detergent compounds selected from the group consisting of anionic, nonionic and amphoteric detergent compounds;

from about 5 to 30%, by weight, of one or more builder salts selected from the group consisting of alkali metal tripolyphosphates, alkali metal carbonates, alkali metal nitrilotriacetates and polyacetal carboxylates;

(c) from about 5 to 20%, by weight, of a swelling bentonite clay;

(d) an effective amount of an enzyme or an enzyme mixture selected from the group consisting of alkaline protease enzymes and alpha-amylase enzymes;

(e) an enzyme-stabilizing system containing, based on the weight of the detergent composition, (i) from about 1% to 10% glycerine; (ii) from about 1 to 8% of a boron compound selected from the group consisting of boric acid, boric oxide and alkali metal borates; and (iii) from about 0.5 to 8% of a carboxylic acid compound selected from the group consisting of mono, di and/or polycarboxylic acids having 1 to 8 carbon atoms and water-soluble salts thereof; and

(f) the balance comprising water.

Claims

1. A stabilized fabric softening enzyme-containing built liquid detergent composition comprising:

(a) from about 5 to B 20%, by weight, of one or more surface active detergent compounds selected from the group consisting of anionic, nonionic and amphoteric detergent compounds;

(b) from about 5 to 30%, by weight, of one or more builder salts selected from the group consisting of alkali metal tripolyphosphates, and alkali metal carbonates;

(c) from about 5 to 20%, of a swelling bentonite clay;

(d) an effective amount of an enzyme or an enzyme mixture for stain removal selected from the group consisting of alkali protease enzymes and alpha-amylase enzymes;

(e) an enzyme-stabilizing system containing, based on the weight of the detergent composition, (i) from about 1% to 10% glycerine;

(ii) from about 1 to 8% of a boron compound selected from the group consisting of boric acid, boric oxide and alkali metal borates; and

(iii) from about 0.5 to 8% of a carboxylic acid compound selected from the group consisting of di and/or polycarboxylic acids selected from the group consisting of oxalic acid, malonic acid, maleic acid, succinic acid, malic acid, tartaric acid, aspartic acid and citric acid and water-soluble salts thereof;

(f) the balance comprising water.

2. A liquid detergent composition according to claim 1 comprising:

(a) from about 5 to 15% of an alkali metal alkylbenzene sulfonate wherein the alkyl group contains 12 to 15 carbon atoms;

(b) from about 0.5 to 5% of an alkali metal alkyl polyethoxy sulfate wherein the alkyl group contains 10 to 18 carbon atoms and the polyethoxy is of 3 to 11 ethylene oxide groups, the weight ratio of (a) to (b) being from about 2;

1 to about 6;

1;

(c) from about 5 to 20% of sodium tripolyphosphate;

(d) from about 1 to 10% of sodium carbonate, sodium bicarbonate or mixtures thereof, the weight ratio of (c) to (d) being from about 2;

1 to about 6;

1;

(e) from about 10 to 15% of a sodium bentonite;

(f) an effective amount of said enzyme or enzyme mixture;

(g) the enzyme stabilizing system containing, based on the weight of the detergent composition, (i) from about 1 to 5% glycerine (ii) from about 1 to 5% of an alkali metal borate and (iii) from about 0.5 to 4% of said carboxylic acid compound; and

(h) the balance comprising water.

3. A liquid detergent composition according to claim 2 wherein said alkali metal alkylbenzene sulfonate is sodium linear tridecylbenzene sulfonate and said alkali metal alkyl polyethoxy sulfate is one wherein the alkali metal is sodium, the alkyl group contains 12 to 15 carbon atoms and the polyethoxy is of about 3 ethylene oxide groups.

4. A liquid detergent composition according to claim 3 wherein the ratio of tridecylbenzene sulfonate to polyethoxy sulfate is from about 2:

1 to about 4;

1.

5. A liquid detergent composition according to claim 2 wherein said boron compound is an alkali metal borate.

6. A liquid detergent composition according to claim 5 wherein said borate is borax.

7. A liquid detergent composition according to claim 2 which contains from about 8 to 16% sodium tripolyphosphate and from about 2 to 6% sodium carbonate, sodium bicarbonate or mixtures thereof.

8. A liquid detergent composition according to claim 2 wherein said carboxylic acid compound is aspartic acid or a water-soluble salt thereof.

9. A liquid detergent composition according to claim 2 wherein said carboxylic acid compound is tartaric acid or a water-soluble salt thereof.

10. A liquid detergent according to claim 2 wherein said carboxylic acid compound is citric acid or a water-soluble salt thereof.

11. A liquid detergent composition according to claim 2 wherein said carboxylic acid compound is malonic acid or a water-soluble salt thereof.

12. A liquid detergent composition according to claim 2 wherein said carboxylic acid compound is malic acid or a water-soluble salt thereof.

13. A method of laundering comprising contacting the stained and/or soiled fabrics to be laundered with a stabilized enzyme-containing built liquid detergent composition comprising

(a) from about 5 to 20%, by weight, of one or more surface active detergent compounds selected from the group consisting of anionic, nonionic and amphoteric detergent compounds;

(b) from about 5 to 30%, by weight, of one or more builders salts selected from the group consisting of alkali metal tripolyphosphates, and alkali metal carbonates;

(c) from about 5 to 20%, by weight, of a swelling bentonite clay;

(d) an effective amount of enzyme or an enzyme mixture for stain removal selected from the group consisting of alkaline protease enzymes and alpha-amylase enzymes;

(e) an enzyme-stabilizing system containing, based on the weight of the detergent composition, (i) from 1% to 10% glycerine (ii) from about 1 to 8% of a boron compound selected from the group consisting of boric acid, boric oxide and alkali metal borates; and

(iii) from about 0.5 to 8% of a carboxylic acid compound selected from the group consisting of di and/or polycarboxylic acids selected from the group consisting of oxalic acid, malonic acid, maleic acid, succinic acid, malic acid, tartaric acid, aspartic acid and citric acid and water-soluble salts thereof; and

(f) the balance comprising water.

14. A method according to claim 13 wherein said liquid detergent composition comprises:

(a) from about 5 to 15% of an alkali metal alkylbenzene sulfonate wherein the alkyl group contains 12 to 15 carbon atoms;

(b) from about 0.5 to 5% of an alkali metal alkyl polyethoxy sulfate wherein the alkyl group contains 10 to 18 carbon atoms and the polyethoxy is of 3 to 11 ethylene oxide groups, the weight ratio of (a) to (b) being from about 2;

1 to about 6;

1;

(c) from about 5 to 20% of sodium tripolyphosphate;

(d) from about 1 to 10% of sodium carbonate, sodium bicarbonate or mixtures thereof, the weight ratio of (c) to (d) being from about 2;

1 to about 6;

1;

(e) from about 10 to 15% of a sodium bentonite;

(f) an effective amount of said enzyme or enzyme mixture;

(g) the enzyme stabilizing system containing, based on the weight of the detergent composition, (i) from about 1 to 5% glycerine (ii) from about 1 to 5% of an alkali metal borate and (iii) from about 0.5 to 4% of said carboxylic acid compound; and

(h) the balance comprising water and optionally minor adjuvants

15. A method according to claim 14 wherein said alkali metal alkylbenzene sulfonate is sodium linear tridecylbenzene sulfonate and said alkali metal alkyl polyethoxy sulfate is one wherein the alkali metal is sodium, the alkyl group contains 12 to 15 carbon atoms and the polyethoxy is of about 3 ethylene oxide groups.

16. A method according to claim 15 wherein the ratio of tridecylbenzene sulfonate to polyethoxy sulfate is from about 2:

1 to about 4;

1.

17. A method according to claim 14 wherein said boron compound is borax.

18. A method according to claim 14 wherein the liquid detergent composition contains from about 8 to 16% sodium tripolyphosphate and from about 2 to 6% sodium carbonate, sodium bicarbonate or mixtures thereof;

19. A method according to claim 14 wherein the carboxylic acid compound is aspartic acid or a water-soluble salt thereof.

20. A method according to claim 14 wherein the carboxylic acid compound is citric acid or a water-soluble salt thereof.

21. A method according to claim 14 wherein the carboxylic acid compound is malic acid or a water-soluble salt thereof.

22. A method according to claim 14 wherein the carboxylic acid compound is malonic acid or a water-soluble salt thereof.