Stable liquid laundry detergent/fabric conditioning composition

• US 4,844,821 A
• Filed: 02/10/1988
• Issued: 07/04/1989
• Est. Priority Date: 02/10/1988
• Status: Expired due to Term

• Current Assignee: The Procter & Gamble Company
• Original Assignee: The Procter & Gamble Company
• Inventors: Mermelstein, Robert, Hartman, Frederick A.
• Primary Examiner(s): NOT, DEFINED
• Assistant Examiner(s): Franklin, Susan B.
• Application Number:
  US07/154,552
• Time in Patent Office: 510 Days
• Field of Search: 252/8.6, 252/8.9, 252/547, 252/174.23, 252/DIG. 2, 252/174.25
• US Class Current: 510/328
• CPC Class Codes: C11D 3/0015 liquid
• CPC Class Codes: C11D 3/1266 in liquid compositions

Abstract

Disclosed are stable liquid laundry detergent and liquid fabric softener compositions containing a Smectite-type clay fabric softener and an antisettling agent in a low water/polyol formulation and, optionally, a softness enhancing amount of a polymeric clay-flocculating agent. Also disclosed is a method for producing these compositions and a step-wise method of using them to obtain fabric softening.

Claims

1. A stable liquid laundry care composition comprising:

(a) from about 1% to about 25%, by weight, of a Smectite-type clay having a longest individual particle dimension of less than about one micron and an ion exchange capacity of at least about 50 meq/100 g;

(b) from about 0.25% to about 5%, by weight, of an antisettling agent selected from the group consisting of organophillic organo-clays, fumed silicas or mixtures thereof;

(c) from about 5% to about 45% by weight of water; and

(d) from 0% to about 5%, by weight, of a polyol containing from about 2 to about 6 carbon atoms and from about 2 to about 6 hydroxy groups, such that the combined water and polyol content of the composition does not exceed about 45%, by weight;

wherein said antisettling agent is sufficiently activated by high shear mixing such that said composition has a Brookfield Yield Value of at least about 1.5 dynes/cm².

2. A composition according to claim 1 further comprising an effective softness enhancing amount of a polymeric clay-flocculating agent.

3. A composition according to claim 2 wherein the clay-flocculating agent is a polymer derived from monomers selected from the group consisting of ethylene oxide, acryl amide, acrylic acid, dimethylamino ethyl methacrylate, vinyl alcohol, vinyl pyrrolidone, ethylene imine, and mixtures thereof.

4. A composition according to claim 3 wherein the polymeric clay-flocculating agent is polyethylene oxide with a molecular weight between about 300,000 and about 5,000,000.

5. A composition according to claim 4 comprising from about 0.001% to about 10%, by weight, of the polyethylene oxide clay-flocculating agent.

6. A composition according to claim 1 wherein the Smectite-type clay is selected from the group consisting of montmorillonites, volchonskoites, nontronites, hectorites, saponites, sauconites, vermiculites, and mixtures thereof.

7. A composition according to claim 6 wherein the Smectitetype clay is montmorillonite.

8. A composition according to claim 1 wherein the antisettling agent is an organophillic organo-clay comprising the reaction product of an organic cation containing at least one alkyl group containing at least 10 carbon atoms and a montmorillonite clay.

9. A composition according to claim 8 wherein the organic cation reagent is a quaternized ammonium cation.

10. A composition according to claim 1 wherein the polyol is selected from the group comprising of 1,2-propanediol, ethylene glycol, glycerol, and mixtures thereof.

11. A composition according to claim 10 wherein the polyol is 1,2-propanediol.

12. A composition according to claim 1 comprising (a) from about 2% to about 7%, by weight, of a montmorillonite clay, (b) from about 0.01% to about 0.3%, by weight, of polyethylene oxide with a molecular weight between about 300,000 and about 5,000,000, (c) from about 0.5% to about 2%, by weight, of an organophillic quaternized organo-montmorillonite antisettling agent and (d) a combined water and 1,2-propanediol content from about 5% to about 45%, by weight.

13. A liquid detergent composition according to claim 1 further comprising from about 1% to about 40%, by weight, of a detersive surfactant selected from the group consisting of anionic, nonionic, semi-polar, ampholytic, zwitterionic, and cationic surfactants, and mixtures thereof.

14. A composition according to claim 13 wherein the detersive surfactant is selected from the group consisting of linear alkyl benzene sulfonates, alkyl polyethoxylated alcohols, alkyl sulfates, and mixtures thereof.

15. A liquid fabric softener composition according to claim 1 further comprising from about 10% to about 55%, by weight, of liquid carrier selected from the group consisting of monohydric alcohols containing from about 1 to about 6 carbon atoms, and mixtures thereof.

22. A method of softening fabrics comprising the steps of:

(a) placing the fabrics in an aqueous solution;

(b) adding to the solution the composition according to claim 1 at a concentration from about 0.004% to about 2%, by weight; and

(c) commencing agitation of the solution within about 5 minutes after step (b).

16. A method for producing a stable liquid laundry care composition comprising the high shear mixing, at a shear rate of greater than about 10,000 sec^-1, at a liquid temperature from about 70°

F. to about 100°

F., for about 4 to about 10 passes, of a mixture comprising;

(a) from about 1% to about 25%, by weight, of a Smectite-type clay having an ion exchange capacity of at least about 50 meq/100 g;

(b) from about 0.5% to about 2%, by weight, of an antisettling agent selected from the group consisting of organophillic quaternized organo-clays, fumed silicas, and mixtures thereof;

(c) from about 5% to about 45%, by weight, of water; and

(d) from 0% to about 5%, by weight, of a polyol containing from about 2 to about 6 carbon atoms and from about 2 to about 6 hydroxy groups, such that the combined water and polyol content of the composition does not exceed about 45%, by weight;

such that the fabric softening clay particle size is reduced to less than about one micron and the antisettling agent is fully dispersed and activated such that the composition has a Brookfield Yield Value of at least about 1.5 dynes/cm².

17. A method according to claim 16 wherein the mixture comprises from about 2% to about 7%, by weight, of a montmorillonite clay, an organophillic quaternized organomontmorillonite antisettling agent, and a combined water and 1,2-propanediol content from about 5% to about 45%, by weight.

18. A method according to claim 16 wherein the mixture further comprises an effective softness enhancing amount of a polymeric clay-flocculating agent.

19. A method according to claim 18 wherein the mixture comprises from about 2% to about 7%, by weight, of a montmorillonite clay, from about 0.01% to about 0.3%, by weight, of polyethylene oxide with a molecular weight between about 300,000 and about 5,000,000, an organophillic quaternized organo-montmorillonite antisettling agent, and a combined water and 1,2-propanediol content from about 5% to about 45, by weight.

20. A stable liquid laundry care composition produced in accordance with the process of claim 16.

21. A stable liquid laundry care composition produced in accordance with the process of claim 18.