Silver complex diffusion transfer processing

• US 4,845,010 A
• Filed: 06/09/1988
• Issued: 07/04/1989
• Est. Priority Date: 07/06/1987
• Status: Expired due to Fees

• Current Assignee: Agfa-Gevaert N.V.
• Original Assignee: Agfa-Gevaert N.V.
• Inventors: Stroobants, Marcel, Matthe, Herman L., Coppens, Paul J.
• Primary Examiner(s): Schilling, Richard L.
• Application Number:
  US07/204,232
• Time in Patent Office: 390 Days
• Field of Search: 430/204, 430/244, 430/230, 430/606
• US Class Current: 430/204
• CPC Class Codes: G03C 1/005 Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein catalytic amounts of silver halide in dry silver systems or thermographic systems using noble metal compounds G03C1/494
• CPC Class Codes: G03C 1/12 Methine and polymethine dyes
• CPC Class Codes: G03C 5/02 Sensitometric processes, e.g. determining sensitivity, colour sensitivity, gradation, graininess, density; Making sensitometric wedges
• CPC Class Codes: G03C 8/06 Silver salt diffusion transfer
• CPC Class Codes: G03F 7/07 used for diffusion transfer G03F7/063 takes precedence

Abstract

A method for the production of a photographic image by silver complex diffusion transfer processing wherein a negative working silver halide emulsion material having particularly high exposure latitude and being manipulatable under room light conditions without prohibitive fogging is used, said material having a low intensity reciprocity failure (L.I.R.F). The material is contact-exposed with visible light through a sheet support carrying paper paste-up material with its information facing the silver halide emulsion layer of the photographic material, and the resulting latent image is developed in the presence of a silver halide complexing agent and the thus developed silver halide emulsion material is contacted with an image-receiving material to form according to a preferred embodiment a planographic printing plate.

Claims

1. A method for the production of a photographic image by silver complex diffusion transfer processing comprising the steps of:

(1) providing a negative working silver halide emulsion material which can be handled under room light conditions without prohibitive fogging, said material having a low intensity reciprocity failure (L.I.R.F) obtained by the absence of intentional chemical sensitization and by the presence in combination with the silver halide of at least one electron accepting compound, and being spectrally sensitized within the visible light spectrum in the wavelength range of 480 to 580 nm;

the low intensity reciprocity failure of said material when graphically depicted in an orthogonal coordinate system having in the abscissa the logarithm of the irradiance (I) in lux and in the ordinate the logarithm of the product of the irradiance (I) with exposure time (t) in seconds is defined by a graph representing the product of a minimal exposure time with a certain irradiance being put against said irradiance. wherein said minimal exposure time is the shortest exposure time for the in the abscissa defined irradiance giving rise to a silver image density in the exposed and DTR-processed photographic material thus high that in corresponding area of a therewith DTR-processed image-receiving material no visible silver metal fog density is formed;

the curvature of said graph being such that;

(1) the derivative of dlog 1.t/dlog I has a value less than minus 0.5 at values of irradiance below 100 lux, and

(2) the absolute value of the derivative of dlog I.t/dlog I is not higher than 0.2 at values of irradiance in the range of 500 lux to 5000 lux;

(2) contact-exposing said photographic material with visible light through a sheet support carrying paper paste-up material with its information facing the silver halide emulsion layer of the photographic material, and

(3) developing the resulting latent image in the presence of a silver halide complexing agent and contacting the thus developed silver halide emulsion material with an image-receiving material to form thereon a silver image.

2. A method according to claim 1, wherein the image-receiving material is an aluminium sheet which after silver image formation thereon is used as planographic printing plate.

3. A method according to claim 1, wherein the exposure proceeds in a contact exposure apparatus provided with an exposure light source emitting ultra-violet radiation and some visible light as is used in the exposure of presensitized plates.

4. A method according to claim 1, wherein the negative working silver halide emulsion material can be handled without substantial fogging under exposure conditions corresponding with an irradiance of 200 lux during 120 seconds with a fluorescent lamp having an emmission spectrum as illustrated in FIG. 4.

5. A method according to claim 1, wherein the electron-accepting compound is pinakryptol yellow being used in an amount by weight in the range of 0.1 to 10 g with respect to 100 g of silver nitrate equivalent with the applied silver halide.

6. A method according to claim 1, wherein the type of silver halide used in the negative working silver halide emulsion is mainly silver chloride.

7. A method according to claim 1, wherein the silver halide is spectrally sensitized with a sensitizing dye corresponding to one of the following structural formulae 1 to 6:

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8. A method according to claim 1, wherein the material comprises in working contact with the electron accepting compound a reducing agent.

9. A method according to claim 8, wherein said reducing agent is a compound commonly used as silver halide developing agent in a silver halide photographic material but is used in said material in an amount insufficient to effect full development of the exposed silver halide.

10. A method according to claim 9, wherein said reducing agent is hydroquinone.