Liquid curable polyorganosiloxane compositions

• US 4,845,164 A
• Filed: 11/07/1986
• Issued: 07/04/1989
• Est. Priority Date: 03/03/1986
• Status: Expired due to Fees

• Current Assignee: Dow, Inc.
• Original Assignee: Dow, Inc.
• Inventors: Gutek, Beth I.
• Primary Examiner(s): Bleutge, John C.
• Assistant Examiner(s): Dean, Jr., Ralph H.
• Application Number:
  US06/927,997
• Time in Patent Office: 970 Days
• Field of Search: 528/15, 528/31, 528/32, 525/478
• US Class Current: 528/15
• CPC Class Codes: C08G 77/12 containing silicon bound to hydrogen C08G77/045 takes precedence
• CPC Class Codes: C08G 77/20 containing silicon bound to unsaturated aliphatic groups C08G77/045 takes precedence
• CPC Class Codes: C08G 77/24 halogen-containing groups
• CPC Class Codes: C08G 77/70 Siloxanes defined by use of the MDTQ nomenclature
• CPC Class Codes: C08L 83/00 Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 83/04 Polysiloxanes

Abstract

The curable polyorganosiloxane compositions of this invention comprise at least one vinyl-terminated liquid polydiorganosiloxane, a resinous organosiloxane reinforcing agent that includes diorganovinylsiloxy, triorganosiloxy and SiO₂ units, an organosiloxane curing agent containing an average of at least three silicon-bonded hydrogen atoms per molecule, a diorganohydrogensiloxy terminated polydiorganosiloxane as a chain extender in an amount sufficient to provide from 10 to 85 percent of the silicon-bonded hydrogen atoms in the composition, and a platinum-containing hydrosilation catalyst. The compositions contain at least 1.5 vinyl radicals for each silicon-bonded hydrogen atom present in the composition. The cured elastomer is compressible, resilient and exhibits a hardness value of up to 100 on the Shore 00 durometer scale.

Claims

1. A curable composition yielding an optically transparent polyorganosiloxane elastomer, said cmposition comprising the product obtained by blending the following ingredients to homogeneity:

A. at least one liquid polydiorganosiloxane exhibiting a viscosity of from 0.1 to 40 Pa.s at 25°

C. and containing a vinyl radical at each of the two terminal positions;

B. from 5 to about 40 percent, based on the total weight of said composition, of a benzene soluble resinous copolymer consisting essentially of triorganosiloxy units of the general formula R"₃ SiO_1/2, diorganovinylsiloxy units of the general formula CH₂ ═

CH(R'"'"'")₂ SiO_1/2, and SiO₂ units, where R'"'"' and R'"'"'" are individually monovalent hydrocabon or halohydrocarbon radicals containing from 1 to about 20 carbon atoms and free of ethylenic unsaturation, the molar ratio of combined triorganosiloxy units and diorganovinylsiloxy units to SiO₂ units is from 0.7 to 1.2 and said copolymer contains from 0.1 to 8 weight percent of silicon-bonded vinyl radicals;

C. an organohydrogensiloxane curing agent containing at least three silicon-bonded hydrogen atoms per molecule,

D. a diorganohydrogensiloxy terminated polydiorganosiloxane containing two silicon-bonded hydrogen atoms and an average of up to 50 diorganosiloxane units per molecule in an amount sufficient to provide from 10 to 85 percent of the silicon-bonded hydrogen atoms present in said composition, and

E. a platinum-containing hydrosilation catalyst in an amount sufficient to promote curing of said composition;

with the proviso that the composition contains at least 1.5 vinyl radicals for each silicon-bonded hydrogen atom, and the combined concentration of said curing agent and said diorganohydrogensiloxy terminated polydiorganosiloxane is sufficient to cure said composition.

2. A composition according to claim 1 where the vinyl-containing polydiorganosiloxane (A) is represented by the general formula ##STR2## where R represents a monovalent hydrocarbon radical or a monovalent haloydrocarbon radical, Vi represents a vinyl radical, and n represents a degree of polymerization equivalent to a viscosity of from 40 Pa.s at 25°

C.

3. A composition according to claim 2 where R represents a monovalent hydrocarbon or halogenated hydrocarbon radical containing from 1 to 10 carbon atoms, said organohydrogensiloxane (C) contains at least three repeating units per molecule that are selected from the group consisting of HSiO₁.5, R'"'"'_HSiO0.5, where R'"'"' represents a monovalent hydrocarbon or hologenated hydrocarbon radical containing from 1 to 10 carbon atoms, and any remaining repeating units are selected from the group consisting of monoorganosiloxane, diorganosiloxane, triorganosiloxy and SiO₂.

4. A composition according to claim 3 where the viscosity of said composition does not exceed 100 Pa.s at 25°

C., and R, R'"'"' , R'"'"' and R'"'"'" are methyl, phenyl or 3,3,3-trifluoropropyl.

5. A composition according to claim 4 where R, R'"'"', R" and R'"'"'" are methyl, the curing agent comprises a dimethylsiloxane/methylhydrogensiloxane copolymer containing an average of from 10 to 50 repeating units and from 3 to 5 silicon-bonded hydrogen atoms per molecule, the composition contains from two to four moles of vinyl radicals per mole of silicon-bonded hydrogen atoms, the silicon-bonded hydrocarbon radicals of the diorganoydrohensiloxy terminated polydiorganosiloxane are methyl and said platinum-containing hydrosilation catalyst is a reaction product of hexachloroplatinic acid and a vinyl containing organosiloxane compound.

6. A composition according to claim 5 where said composition contains two of said liquid polydiorganosiloxanes, the first of which exhibits a viscosity of from 0.1 to 3 Pa.s at 25°

C. and the second of which exhibits a viscosity of from 20 to 40 Pa.s at 25°

C., and the dimethylhydrogensiloxy terminated polydimethylsiloxane contains from 30 to 70 mole percent of the silicon-bonded hydrogen atoms present in said composition.

7. A composition according to claim 6 that contains a platinum catalyst inhibitor.

8. A composition according to claim 7 where said platinum catalyst inhibitor is an acetylenic alcohol.