Reliquefaction of boil-off from liquefied natural gas

• US 4,846,862 A
• Filed: 09/06/1988
• Issued: 07/11/1989
• Est. Priority Date: 09/06/1988
• Status: Expired due to Term

• Current Assignee: Air Products and Chemicals Incorporated Allentown Pennsylvania 18195
• Original Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Inventors: Cook, Philip J.
• Primary Examiner(s): Capossela, Ronald C.
• Application Number:
  US07/241,158
• Time in Patent Office: 308 Days
• Field of Search: 62/54, 62/514 R, 62/9
• US Class Current: 62/48.2
• CPC Class Codes: F17C 2265/03 Treating the boil-off
• CPC Class Codes: F25J 1/0025 Boil-off gases "BOG" from storages
• CPC Class Codes: F25J 1/005 by expansion of a gaseous refrigerant stream with extraction of work
• CPC Class Codes: F25J 1/0052 by vaporising a liquid refrigerant stream
• CPC Class Codes: F25J 1/0072 Nitrogen
• CPC Class Codes: F25J 1/0204 as a single flow SCR cycle
• CPC Class Codes: F25J 1/0277 Offshore use, e.g. during shipping
• CPC Class Codes: F25J 2290/62 Details of storing a fluid in a tank

Abstract

The present invention relates to an improved process for the reliquefaction of boil-off gas containing up to 10% nitrogen resulting from the evaporation of liquefied natural gas (LNG) contained in a storage vessel. In the process, a closed-loop refrigeration cycle is utilized wherein an isenthalpically expanded stream is warmed against an initially cooled boil-off stream. The boil-off LNG stream is initially cooled by indirect heat exchange with an isentropically expanded refrigerant stream.

Claims

1. In a process for liquifying boil-off gas resulting from the evaporation of liquified natural gas contained in a storage vessel, the boil-off gas being cooled and liquified in a closed-loop refrigeration system and then returned to said storage vessel wherein, said closed-loop refrigeration system comprises the steps:

compressing nitrogen as a working fluid in a compressor system to form a compressed working fluid;

splitting said compressed working fluid into a first and second stream;

isenthalpically expanding said first stream to produce a cooled first stream, then warming against boil-off gas and compressed working fluid; and

isentropically expanding the second stream to form a cooled expanded stream which is then warmed against boil-off gas to form at least partially condensed boil-off prior to warming against the working fluid and prior to return to the compressor system;

the improvement for reliquifying a boil-off gas having from about 0 to 5% nitrogen by volume, which comprises;

(a) effecting isenthalpic expansion of said first stream when the nitrogen content is from about 0-5%, under conditions such that at least a liquid fraction is generated at a pressure higher than the isentropically expanded stream;

(b) warming the liquid fraction against the partially condensed boil-off gas and against the compressed working fluid prior to returning said fractions to the compressor system.

2. The process of claim 1 wherein the nitrogen working fluid is compressed to a pressure of from 600-900 psig.

3. The process of claim 2 wherein the first stream fluid is isenthalpically expanded to a pressure of from about 200-320 psia.

4. The process of claim 3 wherein the temperature of the first stream is cooled to about -240 to -265°

F. prior to expansion.

5. The process of claim 4 wherein the second stream is cooled to a temperature of about -80 to about -120°

F prior to expansion.

6. The process of claim 4 wherein the second stream is expanded to a pressure from about 70 to about 120 psia.

7. In a process for liquifying boil-off gas resulting from the evaporation of liquified natural gas contained in a storage vessel, the boil-off gas being cooled and liquified in a closed-loop refrigeration system and then returned to said storage vessel wherein said closed-loop refrigeration system comprises the steps:

compressing nitrogen as a working fluid in a compressor system to form a compressed working fluid;

splitting said compressed working fluid into a first and second stream;

isenthalpically expanding said first stream to produce a cooled first stream, then warming against recycle compressed working fluid and boil-off gas;

isentropically expanding the second stream to form a cooled expanded stream which is then warmed against boil-off gas and working fluid prior to return to the compressor system;

the improvement for reliquefying a boil-off gas containing from about 5 to 10% nitrogen by volume which comprises;

(a) effecting isenthalpic expansion of said first stream under conditions such that at least a liquid fraction is generated at a pressure higher than the isentropically expanded stream;

(b) separating any vapor fraction, if generated, from the liquid fraction;

(c) warming the vapor fraction, if generated, against boil-off gas and recycle compressed working fluid;

(d) splitting the liquid fraction formed in step (a) into a first major portion and a second minor portion;

(e) warming the first major portion of the liquid fraction against boil-off gas in parallel with the warming of said isentropically expanded second stream; and

(f) isenthalpically expanding the second minor portion to produce a second cooled liquid fraction and a second vapor fraction and then warming the second cooled liquid fraction and said second vapor fraction against the partially condensed boil-off gas for effecting final condensation.

8. The process of claim 7 wherein the nitrogen working fluid is compressed to a pressure from about 600 to 900 psia.

9. The process of claim 8 wherein the first stream is cooled to a temperature from about -270 to -282°

F. prior to the first isenthalpic expansion.

10. The process for claim 9 wherein the first stream is expanded to a pressure from 130 to 260 psia in the first isenthalpic expansion.

11. The process of claim 10 wherein the second stream is cooled to a temperature of from about -80°

to -120°

F. prior to isentropic expansion.

12. The process of claim 11 wherein the second stream is expanded to a pressure from about 60 to 100 psia.

13. The process of claim 12 wherein the pressure is reduced to about 35 to 50 psia by the second isenthalpic expansion of the first stream.