Light-sensitive silver halide photographic material
First Claim
1. A light-sensitive silver halide photographic material comprising at least one silver halide emulsion layer on at least one side of a support and at least one auxiliary layer adjacent to aid silver halide emulsion layer, said silver halide emulsion layer containing a surface latent type silver halide emulsion and a silver halide emulsion having fog internally of the grains, and said auxiliary layer containing compounds represented by formula (I) and formula (II) shown below:
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space="preserve" listing-type="equation">RfSO.sub.3 M Formula (I)wherein Rf is a substituted or unsubstituted alkyl group or a substituted or unsubstituted aralkyl group, containing at least 3 fluorine atoms, and M represents hydrogen atom, an alkali metal or ammonium group;
space="preserve" listing-type="equation">R.sub.1 --L--(CH.sub.2 CH.sub.2 O).sub.m --H Formula (II)wherein R1 is a substituted or unsubstituted alkyl group, alkenyl group or aryl group, L represents oxygen atom, sulfur atom, a -N-R2 group ##STR36## and R2 represents hydrogen atom, an alkyl group or --(CH2 CH2 O)m --H, and m represents an integer of 2 to 50.
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Accused Products
Abstract
Disclosed is a light-sensitive silver halide photographic material comprising at least one silver halide emulsion layer on at least one side of a support and at least auxiliary layer adjacent to the silver halide emulsion layer, the silver halide emulsion layer containing a surface latent type silver halide emulsion and a silver halide emulsion having fog internally of the grains, and the auxiliary layer containing a compound represented by the formula (I) shown below:
RfSO.sub.3 M Formula (I)
wherein Rf is a substituted or unsubstituted alkyl group or a substituted or unsubstituted aralkyl group, containing at least 3 fluorine atoms, and M represents hydrogen atom, an alkali metal or ammonium group.
According to the present invention, a light-sensitive silver halide photographic material improved in antistatic performance and also improved in storability without accomplaniment of lowering in sensitivity, which can give images with sensitivity, high contrast as well as high covering power is provided.
25 Citations
13 Claims
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1. A light-sensitive silver halide photographic material comprising at least one silver halide emulsion layer on at least one side of a support and at least one auxiliary layer adjacent to aid silver halide emulsion layer, said silver halide emulsion layer containing a surface latent type silver halide emulsion and a silver halide emulsion having fog internally of the grains, and said auxiliary layer containing compounds represented by formula (I) and formula (II) shown below:
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space="preserve" listing-type="equation">RfSO.sub.3 M Formula (I)wherein Rf is a substituted or unsubstituted alkyl group or a substituted or unsubstituted aralkyl group, containing at least 3 fluorine atoms, and M represents hydrogen atom, an alkali metal or ammonium group;
space="preserve" listing-type="equation">R.sub.1 --L--(CH.sub.2 CH.sub.2 O).sub.m --H Formula (II)wherein R1 is a substituted or unsubstituted alkyl group, alkenyl group or aryl group, L represents oxygen atom, sulfur atom, a -N-R2 group ##STR36## and R2 represents hydrogen atom, an alkyl group or --(CH2 CH2 O)m --H, and m represents an integer of 2 to 50. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13)
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13. The light-sensitive silver halide photographic material of claim 10 wherein the compound of formula (I) is ##STR45##
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Specification