Insecticidal composition comprising diazinon and process for the preparation thereof

• US 4,851,227 A
• Filed: 07/29/1987
• Issued: 07/25/1989
• Est. Priority Date: 07/31/1986
• Status: Expired due to Term

• Current Assignee: Ben Gurion University of The Negev
• Original Assignee: Ben Gurion University of The Negev
• Inventors: Markus, Arie, Pelah, Zvi
• Primary Examiner(s): Dixon, Jr., William R.
• Assistant Examiner(s): Johnson, Jerry D.
• Application Number:
  US07/079,116
• Time in Patent Office: 727 Days
• Field of Search: 424/417, 424/418, 424/419, 424/408, 424/404, 424/407, 424/409
• US Class Current: 424/419
• CPC Class Codes: A01N 2300/00 Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
• CPC Class Codes: A01N 25/28 Microcapsules or nanocapsules
• CPC Class Codes: A01N 57/16 containing heterocyclic radicals
• CPC Class Codes: B01J 13/16 Interfacial polymerisation

Abstract

The invention provides an insecticidal composition comprising Diazinon ensulated in microcapsules, the microcapsules having an encapsulating wall formed essentially from the reaction product of toluene diisocyanate and a polyfunctional amine, and further provides a process for encapsulating Diazinon in a microcapsular formulation comprising providing an aqueous phase containing a non-basic emulsifier, providing an organic phase containing toluene diisocyanate and Diazinon, combining the aqueous and organic phase to form an oil in water emulsion, and adding an aqueous solution of a polyfunctional amine with agitation to the emulsion, whereby the amine reacts with the toluene diisocyanate to form microcapsular envelopes about the Diazinon material.

Claims

1. An insecticidal composition comprising Diazinon encapsulated in an encapsulating wall substantially free of cross linkages formed essentially from the reaction product of toluene diisocyanate and an effectively difunctional amine.

2. An insecticidal composition as defined in claim 1 wherein said effectively difunctional amine is a di or triamine.

3. A process for encapsulating Diazinon in a microcapsular formulation comprising:

(a) providing an aqueous phase containing a non-basic emulsifier;

(b) providing an organic phase containing toluene diisocyanate and Diazinon;

(c) combining said aqueous and organic phase to form an oil in water emulsion; and

(d) adding an aqueous solution of an effectively difunctional amine with agitation to said emulsion, whereby said amine reacts with said toluene diisocyanate to form microcapsular envelopes substantially free of cross linkages.

4. A process according to claim 3 comprising the additional step of:

(e) adding a suspending agent to enhance the suspension of said microcapsules in solution.

5. A process as defined in claim 3 wherein said non-basic emulsifier is selected from the group consisting of low and high density polyvinylalcohol, tween 20, tween 40 or tween 80.

6. A process according to claim 4 wherein said suspending agent is selected from Xantan gum, Karya gum and Locust bean gum.