Process for the production of multi-metallic amorphous alloy coatings on a substrate and product

• US 4,851,296 A
• Filed: 11/17/1986
• Issued: 07/25/1989
• Est. Priority Date: 07/03/1985
• Status: Expired due to Term

• Current Assignee: Standard Oil Company (BP PLC)
• Original Assignee: Standard Oil Company (BP PLC)
• Inventors: Grasselli, Robert K., Henderson, Richard S., Tenhover, Michael A.
• Primary Examiner(s): NOT, DEFINED
• Application Number:
  US06/931,494
• Time in Patent Office: 981 Days
• Field of Search: 427/249, 427/255, 427/255.2, 427/252, 427/124, 427/132, 427/314, 427/319, 428/457, 428/689, 428/697, 428/698, 428/704, 428/627, 428/668, 428/681, 428/660, 428/662, 428/663, 428/669, 428/680, 428/674
• US Class Current: 428/457
• CPC Class Codes: C23C 16/06 characterised by the deposition of metallic material
• CPC Class Codes: C23C 16/30 Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
• CPC Class Codes: Y10T 428/12576 Boride, carbide or nitride component
• CPC Class Codes: Y10T 428/12903 Cu-base component
• CPC Class Codes: Y10T 428/12944 Ni-base component
• CPC Class Codes: Y10T 428/12951 Fe-base component
• CPC Class Codes: Y10T 428/31678 Of metal

Abstract

A process is disclosed for the formation of amorphous multi-metallic alloy coatings. More specifically, a chemical vapor deposition process is described wherein precursor compounds are induced to decompose upon a substrate under controlled parameters so as to form a coating on the substrate that is a substantially amorphous multi-metallic alloy. Preferred amorphous alloy compositions are also taught that are ideally synthesized by the claimed process.

Claims

1. A process for depositing a substantially amorphous multi-metallic coating of the formula:

space="preserve" listing-type="equation">M.sub.a M'"'"'.sub.b R.sub.c

wherein

M is at least one element selected from the group consisting of Mo, W, Nb and Ta;

M'"'"' is at least one element selected from the group consisting of Fe, Ni, Co, Mn and Cr; and

R is at least one element selected from the group consisting of P, B, N, As, S, Si and C; and

wherein

a ranges from about 0.15 to about 0.85;

b ranges from about 0.15 to about 0.85; and

c ranges from greater than zero to about 0.25

with the proviso that when M'"'"' includes Cr, then the sum (due to M'"'"' elements other than Cr plus C) will be at least 0.15;

on to a substrate, which process comprises the steps of;

(a) providing at least two precursor metal-bearing compounds and one precursor nonmetallic element-bearing compound that each contain one of the metals and non-metal desired in said amorphous multi-metallic coating and which precursor compounds decompose at a temperature below the crystallization temperature of the amorphous multi-metallic coating to be formed;

(b) heating said substrate in an enclosed system to a temperature of at least the decomposition temperature of said precursor compounds;

(c) volatilizing said precursor compounds; and

(d) contacting the volatilized precursor compounds with the substrate in said enclosed system so as to cause said substantially amorphous multimetallic coating to be formed on said substrate.

2. The process in accordance with claim 1 wherein said precursor metal-bearing compounds include organo-metallic compounds.

3. The process in accordance with claim 1 wherein said substrate comprises a material selected from the group including glass, titanium, steel, copper, carbon, alumina and nickel.

4. The process in accordance with claim 1 wherein said substrate is heated to a temperature between about 100°

C. and about 700°

C.

5. The process in accordance with claim 1 wherein said substrate is heated to a temperature between about 250°

C. and about 400°

C.

6. The process in accordance with claim 1 wherein said enclosed system is maintained at a pressure of from about 1×

10^-6 torr to about 700 torr.

7. The process in accordance with claim 1 wherein the atmosphere within said enclosed system comprises an inert gas.

8. The process in accordance with claim 1 wherein the atmosphere within said enclosed system comprises a precursor non-metallic compound.

9. A substrate having a substantially amorphous multi-metallic alloy coating of the formula:

space="preserve" listing-type="equation">M.sub.a M'"'"'.sub.b R.sub.c

wherein

M is at least one element selected from the group consisting of Mo, W, Nb and Ta;

M'"'"' is at least one element selected from the group consisting of Fe, Ni, Co, Mn and Cr; and

R is at least one element selected from the group consisting of P, B, N, As, S, Si and C; and

wherein

a ranges from about 0.15 to about 0.85;

b ranges from about 0.15 to about 0.85; and

c ranges from greater than zero to about 0.25

with the proviso that when M'"'"' includes Cr, then the sum (due to M'"'"' elements other than Cr plus C) will be at least 0.15 thereon formed by the process which comprises the steps of;

(a) providing at least two precursor metal-bearing compounds and one precursor nonmetallic element-bearing compound that each contain one of the metals and non metals desired in said amorphous multi-metallic coating and which precursor compounds decompose at a temperature below the crystallization temperature of the amorphous multi-metallic coating to be formed;

(b) heating said substrate in an enclosed system to a temperature of at least the decomposition temperature of said precursor compounds;

(c) volatilizing said precursor compounds; and

(d) contacting the volatilized precursor compounds with the substrate in said enclosed system so as to cause said substantially amorphous multi-metallic coating to be formed on said substrate.

10. The substantially amorphous multi-metallic alloy coating in accordance with claim 9 wherein said alloy is at least eighty percent amorphous.

11. The substantially amorphous multi-metallic alloy coating in accordance with claim 9 wherein said alloy is about one hundred percent amorphous.

12. The substantially amorphous multi-metallic alloy coating in accordance with claim 9 wherein said alloy comprises Cr, Mo and N.

13. The substantially amorphous multi-metallic alloy coating in accordance with claim 12 wherein said alloy has an approximate composition Cr₄₀ Mo₄₀ N₂₀.

14. The substantially amorphous multi-metallic alloy coating in accordance with claim 9 wherein said alloy comprises Cr, Mo and C.

15. The substantially amorphous multi-metallic alloy coating in accordance with claim 14 wherein said alloy has an approximate composition Cr₄₀ Mo₄₀ C₂₀.