Solid compositions for fuel cells, sensors and catalysts

• US 4,851,303 A
• Filed: 11/26/1986
• Issued: 07/25/1989
• Est. Priority Date: 11/26/1986
• Status: Expired due to Fees

• Current Assignee: SRI International, Inc.
• Original Assignee: SRI International, Inc.
• Inventors: Madou, Marc J., Sher, Arden, Otagawa, Takaaki
• Primary Examiner(s): Kalafut, Stephen J.
• Application Number:
  US06/935,289
• Time in Patent Office: 972 Days
• Field of Search: 429/33, 429/191, 429/13, 252/62.2, 204/426
• US Class Current: 429/489
• CPC Class Codes: B01J 23/002 Mixed oxides other than spinels, e.g. perovskite
• CPC Class Codes: B01J 2523/00 Constitutive chemical elements of heterogeneous catalysts
• CPC Class Codes: B01J 2523/13 Potassium
• CPC Class Codes: B01J 2523/24 Strontium
• CPC Class Codes: B01J 2523/3706 Lanthanum
• CPC Class Codes: B01J 2523/44 Lead
• CPC Class Codes: B01J 2523/72 Manganese
• CPC Class Codes: B01J 2523/845 Cobalt
• CPC Class Codes: B01J 2523/847 Nickel
• CPC Class Codes: B01J 27/12 Fluorides
• CPC Class Codes: B01J 37/024 Multiple impregnation or coating
• CPC Class Codes: G01N 27/4073 Composition or fabrication of the solid electrolyte
• CPC Class Codes: H01M 4/90 Selection of catalytic material
• CPC Class Codes: H01M 8/124 characterised by the process of manufacturing or by the material of the electrolyte
• CPC Class Codes: Y02E 60/50 Fuel cells
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product

Abstract

The present invention relates to solid materials for use as electrolyte for a fuel cell, or for a sensor, or as a catalyst. Representative structures include lanthanum fluoride, lead potassium fluoride, lead bismuth fluoride, lanthanum strontium fluoride, lanthan strontium lithium fluoride, calcium uranium, cesium fluoride, PbSnFy, KSn₂ F₄, SrCl₂.KCl, LaOF₂, PbSnF₈.PbSnO, lanthanum oxyfluoride, oxide, calcium fluoride, SmNdFO, and the like. In another aspect, the present invention relates to a composite and a process to obtain it of the formula:

A.sub.1-y ByQO.sub.3

having a perovskite or a perovskite-type structure as an electrode catalyst in combination with:

A.sub.y B.sub.1-y F.sub.2+y

as a discontinuous surface coating solid electrolyte solid electrolyte wherein A is independently selected from lanthanum, cerium, neodymium, praseodymium, and scandium, B is independently selected from strontium, calcium, barium or magnesium, Q is independently selected from nickel, cobalt, iron or manganese, and y is between about 0.0001 and 1, which process comprises:

(a) obtaining a particulate of:

A.sub.1-y B.sub.y QO.sub.3

wherein A, B and y are defined hereinabove having an average size distribution of between about 50 and 200 Angstroms in diameter;

(b) reacting the particle of step (a) with a vapor comprising:

A.sub.y B.sub.1-y F.sub.2+y

wherein A, B and y are defined hereinabove, at about ambient pressure at between about 0° and 1000° C.: for between about 10 and 30 hr. obtain a composite of between about 25 to 1000 microns in thickness;

(c) recovering the composite of step (b) having multiple interfaces between the electrode and electrolyte. In another aspect the invention relates to the heating of these solid materials with oxygen and water to obtain higher ionic conductivity. In another aspect the invention relates to the electrochemical doping of oxide ions present by treatment of the electrode-lanthanum fluoride interface at between about 0° and 400° C. in an oxygen environment at between about 10^-3 and 10^-6 amperes per square centimeter for between 1 and 60 minutes. The invention also includes the use of the fuel cells disclosed to generate electricity.

Claims

1. A use of a solid material as an electrolyte for a fuel cell each solid material having a polycrystal or single crystal structure, comprising:

(a) a structure of the formula;

space="preserve" listing-type="equation">AF.sub.3

wherein A is independently selected from lanthanum, cerium, neodymium, praseodymium, scandium or mixtures thereof;

wherein AF₃ is a single crystal or portion thereof;

or

(b) a structure of the formula;

space="preserve" listing-type="equation">A.sub.y B.sub.1-y F.sub.2+y

wherein;

A as defined hereinabove,

B is independently selected from strontium, calcium, barium or magnesium, and y is between about 0.0001 and 1,

wherein the solid material as an electrolyte is a thin layer having one side coated with a noble metal which is in contact with a gaseous fuel for a fuel cell and the other side of the thin solid material for the electrolyte is also coated with a noble metal which is in contact with gaseous oxygen, or air or mixtures thereof.

4. The use of a solid material as an electrolyte for a fuel cell of claim 1 wherein the fuel cell has a useful operational temperature range of between about 0 and 1000°

C.

5. The use of a solid material of claim 4 as an electrolyte wherein the structure in subpart (a) is AF₃ wherein A is lanthanum as a single crystal.

6. The use of a solid material as an electrolyte of claim 5 wherein the operational temperature is between about 15 °

and 30°

C.

7. The use of the solid material of claim 1 wherein the solid material as a single crystal has a thickness of between 100 and 200 micrometers.

8. The use of the solid material of claim 1 wherein the solid material as a single crystal has a thickness of between about 10 and 100 mils.

14. The use of a solid material of claim 1 wherein a single crystal has a thickness of between about 10 and 100 mils.

15. The use of a solid material of claim 14 wherein the single crystal is LaF₃.

16. The use of a solid material of claim 15 wherein the LaF₃ has a thickness of about 100 micrometers.

17. The use of a solid material of claim 1 wherein the solid material used as a electrolyte in a fuel cell which has a useful operational temperature of between 0°

and 1000°

C.

18. The use of a solid material of claim 15 wherein the solid material is LaF₃.

19. The use of a solid material of claim 15 wherein the useful operational temperature is between about 15 and 30°

C.

22. The use of the solid material of claim 1 wherein in (d) A is lanthanum and B is strontium.

23. The use of the solid material of claim 22 wherein y is 0.5.

24. The use of the solid material of claim 22 wherein y is 0.7.

25. The use of the solid material of claim 22 wherein y is 0.9.

2. A use of a solid material as an electrolyte for a fuel cell having a single crystal structure, comprising:

(a) a structure of the formula;

space="preserve" listing-type="equation">AF.sub.3

wherein A is independently selected from lanthanum, cerium, neodymium, praseodymium, scandium or mixtures thereof;

or

(b) a structure of the formula;

space="preserve" listing-type="equation">A.sub.y B.sub.1-y F.sub.2+y

wherein;

A as defined hereinabove,

B is independently selected from strontium, calcium, barium or magnesium, and y is between about 0.0001 and 1.

3. The use of a solid material as an electrolyte for a fuel cell of claim 2 wherein the single crystal has a thickness of between about 100 micrometers and 2.5 millimeters.

9. A use of a composite is a fuel cell, said composite consisting essentially of:

space="preserve" listing-type="equation">A.sub.1-y B.sub.y QO.sub.3

having a perovskite or a perovskite-type structure as a solid electrode catalyst in combination with;

space="preserve" listing-type="equation">A.sub.y B.sub.1-y F.sub.2+y

as a discontinuous surface coating solid electrolyte on the perovskite wherein A is independently selected from lanthanum, cerium, neodymium, praseodymium, or scandium, B is independently selected from strontium, calcium, barium or magnesium, Q is independently selected from nickel, cobalt, iron or manganese, and y is between about 0.0001 and 1 wherein the perovskite has an average size distribution of between about 50 and 200 Angstroms in diameter; and

the composite layer of between about 25 and 1000 microns in thickness;

said composite having multiple interfaces between;

space="preserve" listing-type="equation">A.sub.1-y B.sub.y QO.sub.3

space="preserve" listing-type="equation">and

space="preserve" listing-type="equation">A.sub.y B.sub.1-y F.sub.2+y

and a pore size of between about 25 and 200 Angstroms and a surface area of between about 10 and 100 meters ² /gram.

10. The use of a composite of claim 9 which further includes a suitable inorganic support.

11. A process for the generation of electricity, which process comprises, contacting a solid material having a polycrystal or single crystal structure, comprising:

(a) a structure of the formula;

space="preserve" listing-type="equation">AF.sub.3

wherein A is independently selected from lanthanum, cerium, neodymium, praseodymium, scandium or mixtures thereof;

or

(b) a structure of the formula;

space="preserve" listing-type="equation">A.sub.y B.sub.1-y F.sub.2+y

wherein;

A as defined hereinabove,

B is independently selected from strontium, calcium, barium or magnesium, and y is between about 0.0001 and 1with a suitable fuel at between 0 and 1000°

C.

12. The process of claim 11 wherein the fuel for the fuel cell is selected from hydrogen, hydrazine, ammonia, fossil fuels, separate components of fossil fuels, or mixtures thereof, wherein all fuels have a boiling point at ambient pressure of 250°

C. or less.

13. The process of claim 12 wherein the operating temperature is between about 10°

and 30°

C.

20. A process for improving the ionic conductivity for a solid material having a polycrystal or monocrystal structure, which process comprises:

(a) pretreating a solid material having a structure of the formula;

space="preserve" listing-type="equation">AF.sub.3

wherein A is independently selected from lanthanum, cerium, neodymium, praseodymium, scandium or mixtures thereof;

wherein AF₃ is a single crystal or portion thereof;

or

(b) a structure of the formula;

space="preserve" listing-type="equation">A.sub.y B.sub.1-y F.sub.2+y

wherein;

A as defined hereinabove,

B is independently selected from strontium, calcium, barium or magnesium, and y is between about 0.0001 and 1by contacting the solid material with a polarizing electrical current wherein about 1 gram of solid material is subjected to about 10^-3 amperes per square centimeter for between about 1 to 15 hr. at between about 0° and

400°

C.

21. The process of claim 20 wherein the solid material is lanthanum fluoride.