Method for removal of nitrogen oxides from exhaust gas of diesel engine

• US 4,854,123 A
• Filed: 01/27/1988
• Issued: 08/08/1989
• Est. Priority Date: 01/27/1987
• Status: Expired due to Fees

• Current Assignee: Nippon Shokubai Kagaku Kogyo Company Limited 5-1 Koraibashi Higashi-Ku Osaka Japan
• Original Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
• Inventors: Inoue, Akira, Kobayashi, Motonobu, Mitsui, Kiichiro, Kinoshita, Futoru
• Primary Examiner(s): Hart, Douglas
• Application Number:
  US07/148,877
• Time in Patent Office: 559 Days
• Field of Search: 60/274, 60/301, 60/286
• US Class Current: 60/274
• CPC Class Codes: B01D 53/9431 Processes characterised by a specific device
• CPC Class Codes: B01D 53/9495 Controlling the catalytic process
• CPC Class Codes: F01N 2610/02 the substance being ammonia or urea
• CPC Class Codes: F01N 2610/146 Control thereof, e.g. control of injectors or injection valves
• CPC Class Codes: F01N 2900/08 said parameters being related to the engine
• CPC Class Codes: F01N 3/208 Control of selective catalytic reduction [SCR], e.g. dosing of reducing agent
• CPC Class Codes: F02B 1/04 with fuel-air mixture admission into cylinder
• CPC Class Codes: F02B 3/06 with compression ignition compression ignition engines using air or gas for blowing fuel into compressed air in cylinder F02B13/02
• CPC Class Codes: F02D 41/1462 with determination means using an estimation
• CPC Class Codes: Y02T 10/12 Improving ICE efficiencies

Abstract

A method for the removal of nitrogen oxides from the exhaust gas of a diesel engine through catalytic reduction by the use of honeycomb catalyst in the presence of ammonia, which method comprises feeding ammonia into said exhaust gas proportionately to the product of the revolution number of said diesel engine multiplied by the torque of said diesel engine.

Claims

1. A method for the removal of nitrogen oxides from the exhaust gas of a diesel engine through catalytic reduction by the use of a honeycomb catalyst in the presence of ammonia, which method comprises feeding ammonia into said exhaust gas proportionately to the product of the revolution speed of said diesel engine multiplied by the transmitted torque of said diesel engine.

2. A method according to claim 1, wherein the amount of ammonia to be fed is in the range of 0.3 to 2 parts by volume per one part by volume of NO_x.

3. A method according to claim 2, wherein said revolution speed of engine is detected by an engine revolution speed sensor and said torque is detected by torque meter, the two output signals from said sensors are calculated in an arithmetic unit, and the outcome of said calculation is fed into an ammonia flow volume control unit to effect control of the flow volume of ammonia.

4. A method according to claim 3, wherein the reaction temperature of the catalyst bed is in the range of 150°

to 650°

C. and the space velocity of the exhaust gas through the catalyst bed is in the range of 2,000 to 100,000 hr^-1.

5. A method according to claim 4, wherein the through holes in the catalyst possess an equivalent diameter in the range of 1.5 to 5 mm and the geometric surface area of the catalyst is in the range of 600 to 2,000 m² /m³.

6. A method according to claim 5, wherein the wall thickness of cell of the catalyst is in the range of 0.3 to 0.9 mm.

7. A system for the removal of nitrogen oxides from the exhaust gas of diesel engine, formed by providing a diesel engine with an arithmetic unit, an engine revolution speed sensor adapted to detect the revolution speed of said diesel engine and interconnected to said arithmetic unit, a torque meter adapted to detect the transmitted torque generated by said diesel engine and interconnected to said arithmetic unit, an ammonia flow volume controlling valve interconnected to an ammonia source adapted to effect control of the flow volume of ammonia by the signal received from said arithmetic unit, and an ammonia feed pipe connected to said ammonia flow volume controlling valve and to a converter packed with a honeycomb catalyst and fitted with a nozzle opening into the exhaust tube.

8. A system according to claim 7, wherein said arithmetic unit is adapted to calculate the product of the revolution speed of engine multiplied by the transmitted torque of engine and control the flow volume of ammonia proportionately to the outcome of the multiplication.