Enhanced 2-hydroxy-4-methylthiobutanoic acid composition and method of preparation

• US 4,855,495 A
• Filed: 04/10/1986
• Issued: 08/08/1989
• Est. Priority Date: 09/06/1983
• Status: Expired due to Fees

• Current Assignee: Novus International, Inc. (Nippon Soda Company Limited)
• Original Assignee: Monsanto Company (Bayer AG)
• Inventors: Takano, Masaharu
• Primary Examiner(s): NOT, DEFINED
• Application Number:
  US06/849,971
• Time in Patent Office: 1,216 Days
• Field of Search: 562/581, 514/557
• US Class Current: 562/581
• CPC Class Codes: C07C 323/00 Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups

Abstract

An enhanced 2-hydroxy-4-methylthiobutanoic acid composition and method of preparation are disclosed. The enhanced composition comprises greater than 2.2 and less than about 10 moles of 2-hydroxy-4-methylthiobutanoic acid equivalent per mole of calcium.

Claims

1. A solid composition consisting essentially of calcium and 2-hydroxy-4-(methylthio)butanoic acid equivalent (HMBA), said composition having an HMBA/calcium molar ratio greater than 2.2 and less than 10 and first exhibitinq solid/liquid phase change at a temperature a above 100°

C. and comprising Ca(HMBA)₄ salt complex.

2. A composition of claim 1 in which said HMBA/calcium molar ratio is greater than 4 and less than about 6.

3. The composition of claim 1 in which said HMBA/calcium molar ratio is about 4 and exhibits a melting point at above 130°

C.

4. A method for preparing enhanced 2-hydroxy-4-(methylthio)butanoic acid compositions which comprises reacting the conventional calcium salt of 2-hydroxy-4-(methylthio)butanoic acid with 2-hydroxy-4-(methylthio)butanoic acid so that the overall content of the mixture comprises greater than 2.2 and less than 10 moles of 2-hydroxy-4-(methylthio)butanoic acid equivalent (HMB.A) per mole of calcium to produce a composition comprising Ca(HMBA)₄ salt complex.

5. A method for preparing enhanced 2-hydroxy-4-(methylthio)butanoic acid compositions which comprises reacting 2-hydroxy-4-(methylthio)butanoic acid with a calcium source selected from the group consisting of calcium oxide, calcium hydroxide and calcium carbonate so that the overall content of the mixture comprises greater than 2.2 and less than about 10 moles of 2-hydroxy-4-(methylthio)butanoic acid equivalent (HMBA) per mole of calcium to produce a composition comprising Ca(HMBA)₄ salt complex.

6. A method of claim 5 in which the reaction is carried out at a temperature of about 70°

C. or above.