Method of establishing standard composite material properties

• US 4,856,335 A
• Filed: 10/21/1987
• Issued: 08/15/1989
• Est. Priority Date: 10/21/1987
• Status: Expired due to Fees

• Current Assignee: The Expert System Technologies Incorporated
• Original Assignee: The Expert System Technologies Incorporated
• Inventors: Tornberg, Neal E.
• Primary Examiner(s): Levy, Stewart J.
• Assistant Examiner(s): Raevis, Robert R.
• Application Number:
  US07/111,694
• Time in Patent Office: 664 Days
• Field of Search: 73/597, 73/599, 73/818, 73/820, 73/821, 73/822, 73/825, 73/866, 73/32 A
• US Class Current: 73/597
• CPC Class Codes: G01N 2291/0231 Composite or layered materials
• CPC Class Codes: G01N 2291/0251 Solidification, icing, curing composites, polymerisation
• CPC Class Codes: G01N 2291/048 Transmission, i.e. analysed material between transmitter and receiver
• CPC Class Codes: G01N 29/07 by measuring propagation velocity or propagation time of acoustic waves
• CPC Class Codes: G01N 29/227 related to high pressure, tension or stress conditions

Abstract

A standard reference deformation of a composite material containing a flowable phase and compressible inclusions, such as a prepreg, is measured as the deformation whereat the dominant compressive mode of composite deformation changes from that characteristic of compressible inclusion collapse to that characteristic of resin flow, termed the optimal consolidation deformation. Establishment of this point permits measurement and correlation of physically significant composite properties. For example, material properties of such composite materials are measured under a compressive loading by an ultrasonic transducer at the optimal consolidation deformation. At this point, normally determined to be the deformation at which the second derivative of compressive displacement falls to about zero, compressible inclusions such as voids are eliminated but the flowable phase has not yet begun to flow significantly so as to change the fractions of the phases. This technique is particularly valuable in ultrasonically measuring properties such as phase fractions of resin matrix prepreg materials wherein the resin has not been cured and readily flows, and wherein there are typically voids that interfere with the measurement of properties.

Claims

1. A process for measuring a standard reference deformation for a composite material, comprising the steps of:

furnishing a specimen of a multiphase material wherein at least one phase is flowable, and which initially contains compressible inclusions within the specimen;

compressing the specimen; and

determining the deformation at which the dominant compressive displacement behavior of the composite material changes from that characteristic of collapse of the compressible inclusions to that characteristic of flow of the flowable phase, this deformation being the standard reference deformation.

2. The process of claim 1, including the further step of

collecting data at the standard reference deformation.

3. The process of claim 1, wherein said compressible inclusions are voids.

4. A process for measuring a standard property of the phases of a multiphase material, comprising the steps of:

furnishing a specimen of a multiphase material wherein at least one phase is flowable, and which initially contains compressible inclusions within the specimen;

applying a compressive force to the specimen so that its deformation increases with increasing time; and

measuring a property of the specimen at a standard specimen deformation at which the dominant compressive displacement behavior of the material changes from that characteristic of compressible inclusion collapse to that characteristic of flow of the flowable phase, the property measured at this point being the standard value of the property for the multiphase material.

5. The process of claim 4, wherein the standard specimen deformation is the deformation at which the second derivative of compressive displacement with time first falls to about zero.

6. The process of claim 4, wherein said steps of applying and measuring are performed by a single measurement means for measuring the property, which is forced against the surface of the specimen.

7. The process of claim 4, wherein said step of measuring is accomplished by

performing a series of simultaneous measurements of the material displacement and the property being measured, and

selecting from the series of data the property measured at the point whereat the dominant compressive behavior of the specimen changes from that characteristic of compressible inclusion collapse to that characteristic of flow of the flowable phase.

8. The process of claim 4, wherein the compressible inclusions are voids.

9. The process of claim 4, wherein the multiphase material is a composite prepreg.

10. The process of claim 4, wherein a property measured in said step of measuring is the time required for an ultrasonic wave to traverse the specimen.

11. A process for determining a standard property of a composite material, comprising the steps of:

furnishing a specimen of a multiphase material wherein at least one phase is flowable, and which initially contains compressible inclusions within the specimen;

contacting at least one surface of the specimen with an ultrasonic transducer under a compressive pressure so as to compress the composite material; and

measuring the ultrasonic property of the specimen at the deformation at which the dominant compressive displacement behavior of the composite material changes from that characteristic of compressible inclusion collapse to that characteristic of flow of the flowable phase, the property measured at this point being the standard value of the property for the composite material.

12. The process of claim 11, wherein the property measured is the ultrasonic slowness.

13. The process of claim 11, wherein the property is measured by the transit time technique.

14. The process of claim 11, wherein the property is measured by the sing around technique.

15. The process of claim 11, wherein the pressure applied varies during said step of measuring.

16. The process of claim 11, including the further step of:

comparing the standard value of the property for the specimen with standard values determined for other specimens whose phase fractions are known, to ascertain the phase fraction of the specimen.

17. A process for measuring the fractions of the phases of a composite material, comprising:

furnishing a specimen of a composite material having a reinforcement phase embedded within a flowable matrix phase, and further having voids therein;

contacting at least one surface of the specimen with an ultrasonic transducer under a downward compressive pressure;

determining the displacement of the transducer with time;

measuring the velocity of ultrasonic wave propagation of the specimen as the dominant compressive displacement behavior of the specimen changes from that characteristic of void collapse to that characteristic of flow of the flowable phase; and

calculating the fractions of the phases present in the composite material from the velocity of ultrasonic wave propagation measured in said step of measuring.

18. The process of claim 17, wherein the specimen deformation is measured as the deformation at which the second derivative of compressive displacement with time falls to about zero.