Recording medium

• US 4,857,427 A
• Filed: 08/19/1988
• Issued: 08/15/1989
• Est. Priority Date: 01/29/1986
• Status: Expired due to Fees

• Current Assignee: Nippon Oil Corporation (ENEOS Holdings, Inc.)
• Original Assignee: Nippon Oil Corporation (ENEOS Holdings, Inc.)
• Inventors: Itoh, Hiroyuki, Ishii, Takafumi, Satoh, Tetsuo
• Primary Examiner(s): Michl, Paul R.
• Assistant Examiner(s): Hamilton, Cynthia
• Application Number:
  US07/236,338
• Time in Patent Office: 361 Days
• Field of Search: 346/135.1, 430/19, 430/20, 430/21, 430/945, 428/1
• US Class Current: 430/19
• CPC Class Codes: C08G 69/10 Alpha-amino-carboxylic acids polysuccinimides C08G73/1092
• CPC Class Codes: C09K 19/389 Polypeptides
• CPC Class Codes: G11B 7/245 containing a polymeric component
• CPC Class Codes: G11B 7/25 containing liquid crystals
• CPC Class Codes: Y10S 430/146 Laser beam

Abstract

A recording medium having a base and a recording layer provided on said base, said recording layer consisting essentially of a thermotropic cholesteric liquid crystalline glutamate copolymer represented by the following general formula: ##STR1## wherein R₁ is an alkyl, cycloalkyl, aryl or arylalkyl group having not more than 10 carbon atoms, R₂ is an alkyl, cycloalkyl, aryl or arylalkyl group having 6 to 30 carbon atoms, provided R₁ and R₂ are not the same, and m and n are in the relation of 50≦m+n≦2,000, m/n=80˜10/20˜90.

Claims

1. a method of recording information on a recording medium which comprises:

(a) contacting a cholesteric liquid crystal forming recording layer with laser beam radiation effective to increase the temperature of the film to form a cholesteric liquid crystal; and

(b) removing the laser beam radiation from the layer, to rapidly cool the irradiated area of the layer and fix the cholesteric liquid crystal structure whereby information is recorded in the liquid crystal structure,

said cholesteric liquid crystal forming recording layer being provided on a base to form the recording medium and said recording layer consisting essentially of a thermotropic cholesteric liquid crystalline glutamate copolymer represented by the following general formula;

##STR3## wherein R₁ is an alkyl, cycloalkyl, aryl or arylalkyl group having not more than 10 carbon atoms, R₂ is an alkyl, cycloalkyl, aryl or arylalkyl group having 6 to 30 carbon atoms, provided R₁ and R₂ are not the same, m and n are in the relation of 50≦

m+n 2,000, m/n=80˜

10/20˜

90 and the number of carbon atoms of R₂ is larger by at least five than that of R₁.

2. A method according to claim 1 including the following additional step of reading information from the recording layer which comprises:

reflecting light of a specific wave length dependent on the cholesteric pitch of the cholesteric liquid crystal of step (b) from the irradiated area of the recording layer under conditions of reflectance or transmissivity effective to read the recorded information.

3. A method according to claim 1 including the following additional step of erasing recorded information from the recording layer which comprises:

heating and then cooling the irradiated area of the recording medium under conditions effective to cause relaxation of the cholesteric structure of the irradiated area to take place and the selective reflection ability of the irradiated area to be eliminated thereby causing the recorded information to be erased.

4. A method according to claim 1, wherein m/n is 70˜

40/30˜

60.