Method for continuous quantitative detection of sulphur dioxide and an arrangement for implementing this method

• US 4,857,472 A
• Filed: 05/25/1988
• Issued: 08/15/1989
• Est. Priority Date: 05/27/1987
• Status: Expired due to Term

• Current Assignee: AVL AG
• Original Assignee: AVL AG
• Inventors: Wolfbeis, Otto S.
• Primary Examiner(s): Marcus, Michael S.
• Assistant Examiner(s): Griffith, Rebekah A.
• Application Number:
  US07/198,759
• Time in Patent Office: 447 Days
• Field of Search: 422/55, 422/58, 422/91, 436/122, 436/164, 436/172, 250/458.1, 250/459.1, 250/461.1
• US Class Current: 436/122
• CPC Class Codes: G01N 2021/6432 Quenching
• CPC Class Codes: G01N 21/643 non-biological material
• CPC Class Codes: Y10T 436/186 Sulfur dioxide

Abstract

In order to obtain a higher measuring accuracy and better selectivity in the optical quantitative analysis of sulphur dioxide in gaseous or liquid media, it is proposed that the medium to be analyzed be brought into contact with a fluorescent indicator which emits fluorescent light upon excitation and which is from the group of triphenylmethane dyes, and that the extent to which fluorescence is quenched by the SO₂ quencher be used as a measurable variable for quantitative determination of the content of sulphur dioxide in the medium.

Claims

1. A method for the continuous quantitative detection of sulphur dioxide in gaseous or liquid media, comprising the steps of bringing said medium to be analyzed into contact with a fluorescent indicator emitting fluorescence radiation upon excitation, said fluorescent indicator being selected from the group consisting of triphenylmethane dyes, and measuring the extent of fluorescence-quenching caused by sulphur dioxide contained in said gaseous or liquid media to enable a quantitative determination of the content of sulphur dioxide in said medium to be obtained.

2. A method according to claim 1, wherein said fluorescent indicator used in rhodamin 6G.

3. A method according to claim 1, wherein said fluorescent indicator is added to an SO₂ -permeable polymer, and a polymer membrane containing said fluorescent indicator is formed and brought into contact with said medium to be analyzed.

4. A method according to claim 1, wherein said fluorescent indicator is chemically immobilized on a substrate.

5. A method according to claim 4, wherein said substrate is glass.

6. A method according to claim 1, including the step of bringing a temperature sensor into thermal contact with said medium to be analyzed to obtain a temperature value thereof, said temperature value being used to adjust the quantitative determination of sulphur dioxide content in said medium.

7. A method according to claim 1, wherein said fluorescent indicator is physically immobilized on a substrate.

8. A method according to claim 7, wherein said substrate is glass.

9. An arrangement for the continuous quantitative detection of sulphur dioxide in gaseous or liquid media, comprising a fluorescent indicator on a substrate, said fluorescent indicator being selected from the group consisting of triphenylmethane dyes and at least partly in contact with said medium to be analyzed and emitting fluorescent light upon excitation, wherein said fluorescent indicator is dissolved in an SO₂ -permeable membrane.

10. An arrangement according to claim 9, wherein said SO₂ -permeable membrane containing said fluorescent indicator is placed on the end of an optical waveguide.

11. An arrangement according to claim 9, wherein said SO₂ -permeable membrane is made from silicone rubber, polyvinylchloride or polyethylene.