Curable latex composition, films and foams formed therefrom and method for curing the composition

• US 4,857,566 A
• Filed: 12/28/1987
• Issued: 08/15/1989
• Est. Priority Date: 04/21/1987
• Status: Expired due to Fees

• Current Assignee: The Dow Chemical Company (Dow, Inc.)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Helbling, Alois
• Primary Examiner(s): IVY, C WARREN
• Application Number:
  US07/137,984
• Time in Patent Office: 596 Days
• Field of Search: 523/409, 523/411, 523/412, 523/408, 523/410, 521/69, 521/135
• US Class Current: 523/409
• CPC Class Codes: C08G 59/68 characterised by the catalysts used
• CPC Class Codes: C08J 3/24 Crosslinking, e.g. vulcanising, of macromolecules mechanical aspects B29C35/00; crosslinking agents C08K
• CPC Class Codes: C08L 13/02 Latex
• CPC Class Codes: C08L 2666/08 Homopolymers or copolymers according to C08L7/00 - C08L21/00; Derivatives thereof
• CPC Class Codes: C08L 2666/14 Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
• CPC Class Codes: C08L 63/00 Compositions of epoxy resins; Compositions of derivatives of epoxy resins

Abstract

This invention relates to a curable latex composition, films and foams produced therefrom and method for preparing said curable latex composition. The composition comprises a carboxylated latex, an epoxy resin emulsion containing an organo-soluble or organo-miscible catalyst and a water-soluble catalytic curing agent. The carboxylated latex comprises a copolymer of from 0 to 75 percent by weight of a vinyl aromatic monomer, from 0 to 85 percent by weight of a diene monomer and from 0.5 to 25 percent by weight of an ethylentically unsaturated carboxylic acid monomer, all weight percentages based on the total weight of the copolymer. The latex is produced by emulsion polymerization of one or more monomers in an aqueous environment. The various components of the curable latex composition may be maintained separately until shortly before use because of their ambient temperature curing properties. In some instances two or more components which do not react with each other can be premixed. The present curable latex composition has improved shelf life, cures fast at relatively low temperature and provides plastic films or foams with improved moisture resistance and other physical properties. This composition is suitable for use as latex foam backing of textiles, textile and lamination adhesive and synthetic carpet grass coating.

Claims

1. A curable latex composition comprising

(a) a carboxylated latex comprising a copolymer of a vinyl aromatic monomer, a diene monomer and an ethylenically unsaturated carboxylic acid monomer,

(b) an epoxy resin emulsion comprising an epoxy resin having more than one 1,2-epoxy group, said emulsion additionally comprising a first catalyst selected from the group consisting of ethyltriphenyl phosphonium acetate, ethyltriphenyh phosphonium phosphate, methyltrioctyl ammonium chloride, alkybenzyl dimethyl ammonium chloride, benzyl trimethyl ammonium chloride, tetraethyl ammonium bromide, N-dodecyl pyridinium chloride and tetrabutyl ammonium iodine and

(c) a second catalyst selected from the group consisting of tridimethylaminomethyl phenol, dimethyl aminomethyl phenol, dicyandiamide, ethylenediamine, diethylenetriamine, triethylene tetramine, tetraethylene pentamine and isophorone diamine.

2. A curable latex composition as claimed in claim 1, wherein the copolymer of said carboxylated latex comprises the vinyl aromatic monomer in an amount of from zero to 75 percent by weight, the diene monomer in an amount of from zero to 85 percent by weight and the ethylenically unsaturated carboxylic acid monomer in an amount of from 0.5 to 25 percent by weight, all weight percentages based on the total weight of the copolymer.

3. A curable latex composition as claimed in claim 1 wherein the copolymer of said carboxylated latex further comprises a monomer selected from the group consisting of methyl methacrylate, ethyl acrylate, butyl acrylate, hexyl acrylate, 2-ethylhexyl acrylate, lauryl methacrylate, phenyl acrylate, acrylonitrile, methacrylonitrile, ethyl-chloroacrylate, diethyl maleate, polyglycol maleate, vinyl chloride, vinyl bromide, vinylidene chloride, vinylidene bromide, vinyl methyl ketone, methyl isopropenyl ketone and vinyl ethyl ester.

4. A curable latex composition as claimed in claim 2 wherein said carboxylated latex further comprises a surfactant.

5. A curable latex composition as claimed in claim 4 wherein said surfactant is an ethoxylated nonionic surfactant.

6. A curable latex composition as claimed in claim 4 wherein said surfactant is present in an amount of from 0.5 percent to 5 percent by weight, based on the dry weight of the copolymer.

7. A curable latex composition as claimed in claim 1 wherein said epoxy resin emulsion comprises a surfactant.

8. A curable latex composition as claimed in claim 7 wherein said surfactant is an ethoxylated nonionic surfactant.

9. A curable latex composition as claimed in claim 7 wherein said ethoxylated nonionic surfactant has an HLB of from 16 to 20.

10. A curable latex composition as claimed in claim 7 wherein said surfactant is present in an amount of from 5 to 10 percent by weight, based on the weight of the epoxy resin.

11. A curable latex composition as claimed in claim 1 wherein (1) said vinyl aromatic monomer is selected from the group consisting of styrene, methylstyrene, ethylstyrene, dimethylstyrene, t-butylstyrene, vinylnaphthalene, methoxystyrene, cyanostyrene, acetylstyrene, monochlorostyrene and mixtures thereof, (2) said diene monomer is selected from the group consisting of butadiene, isoprene, divinylbenzene, and mixtures thereof, and (3) said ethylenically unsaturated carboxylic acid is selected from the group consisting of acrylic acid, methacrylic acid, fur maric acid, maleic acid, itaconic acid and mixtures thereof.

12. A curable latex composition as claimed in claim 1 wherein said epoxy resin is selected from the polyglycidyl ethers of bisphenol compounds, the polyglycidyl ethers of a novolac resin, the polyglycidyl ethers of a polyglycol and mixtures thereof.

13. A curable latex composition as claimed in claim 12 wherein said epoxy resin is a polyglycidyl ether of bisphenol-A, a polyglycidyl ether of bisphenol-F or mixtures thereof.

14. A curable latex composition as claimed in claim 2 wherein said first catalyst is present in an amount of from 0.1 to 10 percent by weight, based on the weight of the epoxy resin.

15. A curable latex composition as claimed in claim 2 wherein said second catalyst is present in an amount of from 0.1 to 15 percent by weight, based on the weight of the copolymer.

17. A process for preparing a crosslinked latex product which comprises heating the curable latex composition of claim 1 at a temperature and for a time sufficient to cure the product.

16. A process for preparing a curable latex composition which comprises (a) blending a carboxylated latex comprising a copolymer of a vinyl aromatic monomer, a diene monomer and an ethylenically unsaturated carboxylic acid monomer, (b) an epoxy resin emulsion comprising an epoxy resin having more than one 1,2-epoxy group, said emulsion additionally comprising a first catalyst selected from the group consisting of ethyltriphenyl phosphonium, acetate, ethyltriphenyl phosphonium phosphate, methyltrioctyl ammonium chloride, alkylbenzyl dimethyl ammonium chloride, benzyl trimethyl ammonium chloride, tetraethyl ammonium bromide, N-dodecyl pyridinium chloride and tetrabutyl ammonium iodide and (c) a second catalyst selected from the group consisting of tridimethylaminomethyl phenol, dimethyl aminomethyl phenol, dicyandiamide, ethylenediamine, diethylenetriamine, triethylene tetramine, tetraethylene pentamine and isophorone diamine.