Melt adhesive compositions

• US 4,857,594 A
• Filed: 04/28/1988
• Issued: 08/15/1989
• Est. Priority Date: 04/28/1988
• Status: Expired due to Term

• Current Assignee: General Parts International Incorporated (Advance Auto Parts Incorporated)
• Original Assignee: Baychem International, Inc.
• Inventors: Nguyen, Son T., Lakshmanan, Pallavoor R.
• Primary Examiner(s): Seccuro, Carman J.
• Application Number:
  US07/187,546
• Time in Patent Office: 474 Days
• Field of Search: 525/98
• US Class Current: 525/98
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 2666/24 Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
• CPC Class Codes: C09J 123/12 Polypropene
• CPC Class Codes: C09J 153/00 Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers

Abstract

A melt adhesive composition containing an amorphous polypropylene, a selectively hydrogenated monoalkenyl arene/conjugated diene block copolymer and a tackifier.

Claims

1. A melt adhesive composition especially useful in adhering polyolefin bodies to themselves, to other polyolefin bodies and to other non-polyolefinic bodies consisting of (A) from about 60 to 100 weight percent of a mixture consisting of an amorphous polypropylene, a block copolymer selected from the group consisting of styrene-ethylene/butene-1 block copolymers and styrene-ethylene/propylene block copolymers and a hydrocarbon tackifier, wherein said amorphous polypropylene has a crystallinity of less than about 10 weight percent and a molecular weight in the range of about 300 to about 50,000 and said hydrocarbon tackifier has a ring and ball softening point in the range of about 10°

to about 150°

C.;

the above components being present in the following relative amounts;

space="preserve" listing-type="tabular">______________________________________ Weight Percent ______________________________________ Amorphous Polypropylene 5-95 Block Copolymer 2.5-40 Hydrocarbon Tackifier 2.5-55 ______________________________________

(B) from about 0 to about five weight percent, based on the weight of the final adhesive composition of an antioxidant and (C) from about 0 to about 40 weight percent, based on the weight of the final adhesive composition of a compound or a mixture of compounds selected from the group consisting of an isotactic polypropylene, ethylene-propylene copolymers, paraffin and microcrystalline waxes, Fischer-Tropsch waxes, low molecular weight polybutenes, polyisobutylene, low molecular weight polyethylene, low density polyethylene and process oils.

2. The melt adhesive composition of claim 1 wherein said amorphous polypropylene is obtained as a byproduct during the production of crystalline polypropylene.

3. The melt adhesive composition of claim 1 wherein said amorphous polypropylene is obtained as a direct product of the polymerization of propylene without the formation of crystalline polypropylene.

4. The melt adhesive composition of claim 1 wherein said amorphous polypropylene has a crystallinity of less than about five weight percent and a molecular weight in the range of about 1000 to about 25,000.

5. The melt adhesive of claim 1 wherein the total average molecular weight range of the styrene portion of said block copolymer is in the range of about 2000 to about 125,000.

6. The melt adhesive of claim 1 wherein the total average molecular weight range of the styrene portion of said block copolymer is in the range of about 5000 to about 50,000.

7. The melt adhesive of claim 1 wherein the average molecular weight range of the ethylene/butene-1 and ethylene/propylene blocks is in the range of about 10,000 to about 500,000.

8. The melt adhesive of claim 1 wherein the average molecular weight range of the ethylene/butene-1 and ethylene/propylene blocks is in the range of about 20,000 to about 300,000.

9. The melt adhesive of claim 1 wherein the total weight of the styrene portion of said block copolymer is in the range of about five to about 50 weight percent.

10. The melt adhesive of claim 1 wherein the total weight of the styrene portion of said block copolymer is in the range of about 10 to about 35 weight percent.

11. The melt adhesive of claim 1 wherein the (A) components are present in the following relative amounts:

space="preserve" listing-type="tabular">______________________________________ Weight Percent ______________________________________ Amorphous polypropylene 30-90 Block Copolymer 5-20 Hydrocarbon Tackifier 5-50 ______________________________________

12. The melt adhesive of claim 1 wherein said styrene blocks are composed of styrene.

13. The melt adhesive of claim 1 wherein said styrene blocks are composed of alpha methyl styrene.

14. The melt adhesive of claim 1 wherein said styrene blocks are composed of a ring substituted styrene.

15. The melt adhesive of claim 1 wherein said styrene blocks are composed of a ring alkylated styrene.

16. The melt adhesive of claim 1 wherein said composition consists of said amorphous polypropylene, a styrene-ethylene/butene-1 block copolymer and said tackifier.

17. The melt adhesive of claim 1 wherein said composition consists of said amorphous polypropylene, a styrene-ethylene/propylene block copolymer and said tackifier.

18. The melt adhesive composition of claim 1 wherein said hydrocarbon tackifier has a ring and ball softening point in the range of about 25°

to about 125 C.