Process for the continuous production of polymers and copolymers of water-soluble monomers

• US 4,857,610 A
• Filed: 12/16/1986
• Issued: 08/15/1989
• Est. Priority Date: 12/18/1985
• Status: Expired due to Term

• Current Assignee: Chemische Fabrik Stockhausen GmbH D-4150 Krefeld Germany
• Original Assignee: Chemische Fabrik Stockhausen GmbH (Rag-Stiftung)
• Inventors: Chmelir, Miroslav, Pauen, Josef
• Primary Examiner(s): Schofer, Joseph L.
• Assistant Examiner(s): TESKIN, FRED M
• Application Number:
  US06/942,330
• Time in Patent Office: 973 Days
• Field of Search: 526/88, 526/317.1, 526/240, 526/303.1, 526/306, 526/307, 526/307.3, 526/307.6, 526/317.1, 526/318.3, 526/318.5, 526/341, 526/342, 526/265, 526/330 , 526/328, 526/328.5, 526/329.3, 522/182, 522/184, 522/186, 522/3, 522/40, 522/33, 522/37, 522/43, 522/178, 427/54.1, 427/346, 427/385.5, 427/389.9, 427/391, 427/392, 427/393.5, 427/340, 427/342
• US Class Current: 526/88
• CPC Class Codes: B01J 19/22 in the form of endless belts

Abstract

The present invention relates to a process and an apparatus for the continuous production of polymers and copolymers of water-soluble monomers particularly arcylic acid and/or methacrylic acid, optionally with additional comonomers, by the polymerization of an aqueous monomer solution that is introduced into the trough that is formed by an endless conveyor belt. The trough-like shape of the conveyor belt changes continuously into an extended flat profile during the polymerization process; starting from the side edges and working towards the center of the trough formed by the conveyor belt, the resulting polymer gel strand is released continuously during the transition of the curved trough-like shape of the conveyor belt into the extended, flat form.

Claims

1. In a process for the continuous production of polymers and copolymers of water-soluble monomers, by polymerization of an aqueous monomer solution containing 2.2-8.3 moles of polymerizable double bonds per kilo of monomer solution at a temperature in the range from about -10 to 120°

C., the liquid reaction components being applied in a layer at least one centimeter thick on a moving endless conveyor belt and polymerized, the improvement which comprises adding the liquid reaction components to a trough formed by the moving conveyor belt, the trough shape of the conveyor belt being continuously changed to an extended and flat profile during the polymerization of the reaction components, and the resulting polymer gel strand being continuously released from the side edges towards the center of the trough formed by the conveyor belt, as the curved trough shape of the conveyor belt changes to the extended, flat profile, the release of the polymer gel strand from the surface of the conveyor belt, as a result of the changing shape of the trough formed by the conveyor belt during the course of polymerization, proceeding under the condition P>

A.F. wherein P is the force with which the conveyor belt is converted from the trough shape to the extended, flat profile;

A. is the contact area between the gel strand and the conveyor belt; and

F. is the force of adhesion of the gel strand to the conveyor belt.

2. A process according to claim 1, wherein the monomer solution is continuously metered into the trough formed by the conveyor belt to a coating thickness of at least 2 cm, and the polymer gel strand that is formed assumes the shape of the trough during the polymerization process.

3. A process according to claim 1, wherein the polymerization is completed within 60 minutes.

4. A process according to claim 1, wherein the pH of the monomer solution is below 10.

5. A process according to claim 1, wherein the aqueous monomer solution additionally contains at least one of a catalyst and photoinitiator.

6. A process according to claim 1, wherein the conveyor belt is at least partly flexible and matches the desired trough shape during the polymerization process.

7. A process according to claim 1, wherein the liquid reaction components are applied to a release sheet that is positioned on and advances with the conveyor belt, said sheet comprising a synthetic material, an impregnated textile fabric, a cellulosic sheet, an impregnated paper, or a low absorption paper.

8. A process according to claim 7, wherein the release sheet is based on cellulose or synthetic material, and the sheet and polymer gel strand produced thereon are together subjected to further processing, said sheet becoming a component of the polymer that is produced.

9. A process according to claim 1, wherein at least the uppermost layer of the conveyor belt that comes into contact with the reaction components consists of silicon rubber to which the reaction components are directly applied.

10. A process according to claim 1, wherein in order to form the trough shape, the side edges of the conveyor belt are curved upwardly from the horizontal plane forward to the area in which the reaction components are introduced.

11. A process according to claim 1, wherein the level of the conveyor belt in the area in which the trough is formed is lowered relative to the preceding level of the approaching flat conveyor belt.

12. A process according to claim 1, wherein the trough formed by the conveyor belt is sealed off forwardly of the area in which the reaction components are dispensed, with respect to the direction of movement of the conveyor belt.

13. A process according to claim 1, wherein natural or synthetic thickening agents are added to the monomer solution.

14. A process according to claim 1, wherein a monomer solution with a viscosity in the range of 5-5000 mPa.s is used.

15. A process according to claim 1, wherein polymerization of the monomer solution is initiated by means of ultraviolet radiation with the use of at least one photoinitiator or chemical catalyst.

16. A process according to claim 1, wherein said monomers are selected from acrylic acid and methacrylic acid.

17. A process according to claim 1, wherein the monomers are selected from acrylamide, methacrylonitrile, acrylonitrile, vinyl pyridine, vinyl acetate, polymerizable acids other than acrylic acid or methacrylic acid, salts of polymerizable acids other than acrylic acid or methacrylic acid, amino group-containing and ammonium group-containing esters and amides of polymerizable acids other than acrylic acid or methacrylic acid, alone or in admixture with one another or as comonomers together with acrylic acid and/or methacrylic acid.

18. A process according to claim 1, wherein for the polymerization of water-insoluble comonomers styrene and alkylated styrenes alone or in admixture in amounts up to 40 wt.-% based upon the total weight of the monomers are used.

19. A process according to claim 1, wherein up to 20 wt.-% based upon the total weight of the monomers are cross-linkable monomers with more than one polymerizable group.