Detection of anomalies in gas fluidized bed polymerization

• US 4,858,144 A
• Filed: 02/12/1987
• Issued: 08/15/1989
• Est. Priority Date: 02/19/1986
• Status: Expired due to Term

• Current Assignee: BP Chemicals Ltd. (BP PLC)
• Original Assignee: BP Chemicals Ltd. (BP PLC)
• Inventors: Morterol, Frederic R. M. M., Marsaly, Alain, Martens, Andre, Raufast, Charles
• Primary Examiner(s): Lall, Parshotam S.
• Assistant Examiner(s): Ramirez, Ellis B.
• Application Number:
  US07/013,696
• Time in Patent Office: 915 Days
• Field of Search: 364/496-500, 364/507, 364/558, 364/572, 364/579, 364/576, 73/23, 73/23.1
• US Class Current: 700/266
• CPC Class Codes: B01J 2208/00008 Controlling the process
• CPC Class Codes: B01J 2208/0007 Pressure measurement
• CPC Class Codes: B01J 2208/00681 Agglomeration
• CPC Class Codes: B01J 2219/00191 Control algorithm
• CPC Class Codes: B01J 8/1809 Controlling processes
• CPC Class Codes: C08F 10/00 Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
• CPC Class Codes: C08F 2/00 Processes of polymerisation
• CPC Class Codes: C08F 2/34 Polymerisation in gaseous state
• CPC Class Codes: C10G 11/187 Controlling or regulating

Abstract

A process for detecting anomalies in a fluidized bed, e.g. the incidence of agglomeration in gas-fluidized bed polymerization, comprises sensing and converting into electrical signals the pressure at one level, or the pressure difference between two or more levels in the reactor, processing these signals by computer to produce a pressure spectrum and comparing with a reference spectrum obtained in the absence of anomalies. The device comprises one or more pressure sensors 11,12,13, which measure the pressure at various levels in the reactor 1, and a computer 27.

Claims

1. A process for detecting anomalies in a fluidised bed contained in an enclosure and preventing further development of such anomalies comprising:

at least intermittently sensing the pressure at at least one level in the fluidised bed, the pressure being sensed by at least one pressure sensor which produces an analog signal;

determining the normal spectrum of frequencies present in the said signal when the fluidised bed operates under normal conditions free from anomalies;

detecting the appearance in the said signal of frequencies distinct from, and higher than, frequencies in said normal spectrum which correspond to the presence of anomalies in the fluid bed; and

modifying the fluid bed conditions causing the anomalies upon detection of said frequencies distinct from the frequencies in said normal spectrum to prevent continuation of the increase of said anomalies.

2. Process according to claim 1 wherein the sensing of the pressure is continuous.

3. Process according to claim 1 wherein the detection of frequencies distinct from frequecies in the normal spectrum is carried out by sampling the analog signal to obtain sample signals and Fourier transformation of said sample signals.

4. Process according to claim 1 wherein the detection of frequencies distinct from frequencies in the normal spectrum is obtained by detecting such distinct frequencies to the exclusion of the frequencies in the normal spectrum.

5. Process according to claim 1 wherein the pressure difference between two levels in the fluid bed is sensed by two pressure sensors at least one of which is in the fluidised bed.

6. Process according to claim 5 wherein said enclosure has a fluidisation grid and wherein one of said pressure sensors is disposed immediately above said grid and the other of said pressure sensors is disposed above said one of said sensors.

7. Process according to claim 6 wherein said other of said sensors is disposed above said fluidised bed.

8. Apparatus for detecting anomalies in a fluidised bed contained in an enclosure and controlling the conditions in said bed comprising:

at least one pressure sensor which measures the pressure at least at one level in the fluidised bed and provides analog signals corresponding to the pressure;

processing means for processing the analog signals produced by the said pressure sensor and providing output signals at frequencies above the signal frequencies present when the fluidised bed is operating under normal conditions; and

means connected to said processing means and responsive to said signals at frequencies above said signal frequencies under normal conditions for indicating the presence of anomalies of operation in the said fluidised bed.

9. Apparatus according to claim 8 wherein said processing means comprises sampling means for sampling said analog signals and providing digital signals corresponding thereto, calculating means connected to said sampling means for calculating the differences between the instantaneous value and the mean value of said digital signals, transforming said differences into Fourier transform data and calculating a correlation spectra from said data and indicating means for indicating the presence of frequencies in the last-mentioned said spectra which are above said signal frequencies present when the fluidised bed is operating under normal conditions and which correspond to anomalies in said bed.

10. Apparatus according to claim 8 wherein there are two pressure sensors, at least one of which is disposed in said fluidised bed and one of which is disposed above the other of said pressure sensors.

11. Apparatus according to claim 10 wherein each of said pressure sensors is a differential pressure sensor and each comprises two pressure-pickup tubes which enter the said enclosure at two different levels and the ends of which in the enclosure has a porous filter thereon, wherein said tubes are connected to a differential piezoelectric transducer and further comprising a duct for neutral purge gas which is connected to each pressure-pickup tube between the said transducer and each of the said filters.

12. Apparatus according to claim 8 wherein said processing means comprises means for comparing the analog signals with previously determined analog signals obtained when the fluidised bed is operating under normal conditions.

13. Appartus according to claim 12 wherein said processing means comprises means for discriminating between analog signals corresponding to pressure fluctuations and signals caused by background noise.