Magnesium ions in a process for alkaline peroxide treatment of nonwoody lignocellulosic substrates

• US 4,859,283 A
• Filed: 04/15/1988
• Issued: 08/22/1989
• Est. Priority Date: 04/15/1988
• Status: Expired due to Term

• Current Assignee: OPTA Food Ingredients Incorporated (Sunopta Incorporated)
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Jayawant, Madhusudan D.
• Primary Examiner(s): Chin, Peter
• Application Number:
  US07/181,776
• Time in Patent Office: 494 Days
• Field of Search: 162/14, 162/78, 162/99, 162/90, 162/95, 162/94, 162/97, 426/807, 426/804, 426/615, 426/622, 426/635, 426/636
• US Class Current: 162/78
• CPC Class Codes: A21D 13/02 Products made from whole meal; Products containing bran or rough-ground grain
• CPC Class Codes: A23K 10/32 from hydrolysates of wood or straw
• CPC Class Codes: D21C 3/02 with inorganic bases or alkaline reacting compounds, e.g. sulfate processes
• CPC Class Codes: D21C 9/163 with peroxides
• CPC Class Codes: D21H 11/12 Pulp from non-woody plants or crops, e.g. cotton, flax, straw, bagasse
• CPC Class Codes: Y02P 60/87 Re-use of by-products of food processing for fodder production
• CPC Class Codes: Y10S 426/804 Low calorie, low sodium or hypoallergic
• CPC Class Codes: Y10S 426/807 Poultry or ruminant feed

Abstract

An improved process for delignifying and bleaching nonwoody, lignocellulosic material into products digestible by ruminants and ingestible by humans. The process comprises treating the substrate in an alkaline solution for a period of time and adding magnesium ions prior to adding peroxide or, alternatively, adding the magnesium to the peroxide prior to adding the peroxide to the alkaline slurry.

Claims

1. An improved process for converting nonwoody lignocellulosic substrates into products digestible by ruminants and ingestible by humans comprising the following steps:

(a) forming a slurry of the substrate with aqueous alkali in an amount at least sufficient to wet the substrate, the slurry having a pH in the range 10 to 13 and a temperature of about 25°

to 100°

C., the slurry being substantially free of peroxide;

(b) maintaining the slurry for a sufficient time under conditions of (a) for the alkali to wet the substrate;

(c) adding sufficient magnesium compound to provide about 00.5 to 1.0 percent magnesium ions based on the dry weight of the substrate;

(d) adding a water-soluble peroxide in an amount sufficient to bleach the substrate to the alkaline slurry after or with the addition of the magnesium ions;

(e)maintaining the substrate in contact with the alkaline peroxide solution at a sufficient temperature, pH and for a time sufficient to produce a substantially bleached, cellulosic fiber; and

(f) separating the bleached fiber from the alkaline liquid.

2. The process of claim 1 wherein the magnesium compound provides 0.1 to 0.8 percent magnesium ions based on the dry weight of the substrate.

3. The process of claim 1 wherein the magnesium compound provides 0.1 to 0.6 percent magnesium ions based on the dry weight of the substrate.

4. The process of claim 1 wherein the magnesium compounds in step (c) comprise soluble magnesium compounds.

5. The process of claim 1 wherein the magnesium compounds are magnesium sulfate or magnesium chloride.

6. The process of claim 1 wherein the magnesium compound is added after the substrate is wetted but before the addition of peroxide.

7. The process of claim 1 wherein the magnesium compound is dissolved in the peroxide before the peroxide is added to the alkaline slurry.

8. The process of claim 1 wherein the magnesium compound is added simultaneously but separately with the addition of peroxide.

9. The process of claim 1 wherein the substrate comprises the hulls of cereal grains.

10. The process of claim 9 wherein the substrate comprises oat hulls.

11. The process of claim 1 wherein the pH in step (a) is in the range 10.2 to 11.8.

12. The process of claim 11 wherein the pH is in the range 10.8 to 11.2.

13. The process of claim 1 wherein the alkali is sodium or potassium hydroxide or carbonate.

14. The process of claim 13 wherein the alkali is sodium hydroxide.

15. The process of claim 1 wherein the alkali, calculated as sodium hydroxide, is about 5 to 15 percent of the dry weight of the substrate.

16. The process of claim 15 wherein the alkali is about 7 to 12 percent of the dry weight of the substrate.

17. The process of claim 1 wherein the slurry in step (a) has a consistency of about 5 to 30 percent.

18. The process of claim 1 wherein the temperature of step (a) is about 60°

to 75°

C.

19. The process of claim 18 wherein the temperature of step (a) is about 65°

to 70°

C.

20. The process of claim 1 wherein the pH of step (e) is about 9.5 to 11.0.

21. The process of claim 20 wherein the pH of step (e) is about 10.0 to 10.5.

22. The process of claim 1 wherein the peroxide added in step (d) is hydrogen peroxide.

23. The process of claim 22 wherein peroxide is about 2 to 15 percent of the dry weight of the substrate.

24. The process of claim 23 wherein peroxide is about 4 to 10 percent of the dry weight of the substrate.

25. The process of claim 24 wherein peroxide is about 5 to 8 percent of the dry weight of the substrate.

26. The process of claim 1 wherein the temperature of step (e) is about 25°

to 90°

C.

27. The process of claim 26 wherein the temperature of step (e) is about 50°

to 85°

C.

28. The process of claim 27 wherein the temperature of step (e) is about 65°

to 80°

C.

29. A process for making a reduced calorie dietary flour comprising blending and milling the product of the process of claim 1 with wheat, rice, barley, rye, millet, oat, corn and other cereal grains to obtain a uniformly distributed mixture of regular flour and dietary flour.