Electrochemical cell

• US 4,859,305 A
• Filed: 06/04/1987
• Issued: 08/22/1989
• Est. Priority Date: 08/30/1984
• Status: Expired due to Fees

• Current Assignee: Mine Safety Appliances Company (MSA Safety, Inc.)
• Original Assignee: Mine Safety Appliances Company (MSA Safety, Inc.)
• Inventors: Price, John F., Stewart, David A., Jolson, Joseph D., Schneider, Alan A., Auel, RaeAnn M.
• Primary Examiner(s): TUNG, TA HSUNG
• Application Number:
  US07/058,029
• Time in Patent Office: 810 Days
• Field of Search: 204/1 P, 204/1 K, 204/1 T, 204/412, 204/415, 204/432, 204/435
• US Class Current: 204/412
• CPC Class Codes: G01N 27/4045 for gases other than oxygen

Abstract

The present invention is for an electrochemical cell and method for quantitatively detecting noxious gas which comprises a first working electrode comprising a gas diffusion membrane having bonded thereto a catalytic portion electrochemically reactive with the noxious gas; a second working electrode having electrochemical activity with the oxidation/reduction products produced at the first working electrode; a counter electrode; a reference electrode; an electrolyte; means for containing said electrolyte and said electrodes; means for maintaining a fixed potential on said first working electrode relative to said reference electrode of from about 1.0 to 1.8 volts with respect to the potential of the reversible hydrogen couple of the electrolyte of the cell; and means for maintaining a fixed potential on said second working electrode relative to said reference electrode of from about 1.0 to 2.2 volts with respect to the potential of the reversible hydrogen couple of the electrolyte of the cell, the fixed potential on said working electrode being maintained at a voltage higher than the fixed potential being maintained on said first working electrode.

Claims

1. An electrochemical cell for quantitatively detecting a noxious gas comprising:

(a) a first end plate;

(b) a second end plate;

(c) a first working electrode comprising a gas diffusion membrane having bonded thereto a catalytic portion electrochemically reactive with the noxious gas;

(d) a second working electrode having electrochemical activity with oxidation/reduction products produced at the first working electrode;

(e) a counter electrode;

(f) a reference electrode;

(g) an electrolyte in contact with the catalytic portion of the first working electrode and in contact with the second working, counter and reference electrodes;

(h) means for containing said electrolyte and said first and second working electrodes, said counter electrode and said reference electrode, said means positioned between said first and second end plates;

(i) means for maintaining a fixed potential on said first working electrode relative to said reference electrode of from about 1.0 to 1.8 volts with respect to the potential of the reversible hydrogen couple in the electrolyte of the cell; and

(j) means for maintaining a fixed potential on said second working electrode relative to said reference electrode of from above 1.0 to about 2.2 volts with respect to the potential of the reversible hydrogen couple in the electrolyte of the cell, the fixed potential on said second working electrode being maintained at a voltage higher than the fixed potential being maintained on said first working electrode.

2. The electrochemical cell of claim 1 wherein said counter and reference electrodes are a single electrode.

3. The electrochemical cell of claim 1 wherein the catalytic portion of the first working electrode is selected from the group consisting of palladium, platinum, iridium, ruthenium, rhodium, osmium and alloys and mixtures thereof with gold.

4. The electrochemical cell of claim 3 wherein the catalytic portion of the first working electrode is iridium black.

5. The electrochemical cell of claim 1 wherein the second working electrode is a gas diffusion membrane having bonded thereto a catalytic portion selected from the group consisting of palladium, platinum, iridium, ruthenium, rhodium, osmium and alloys and mixtures thereof with gold.

6. The electrochemical cell of claim 5 wherein the catalytic portion of the second working electrode is iridium black.

7. The electrochemical cell of claim 1 wherein the counter electrode is a gas diffusion membrane having bonded thereto a catalytic portion selected from the group consisting of palladium, platinum, iridium, gold, ruthenium, rhodium, osmium and alloys and mixtures thereof.

8. The electrochemical cell of claim 7 wherein the catalytic portion of the counter electrode is platinum black.

9. The electrochemical cell of claim 1 wherein the electrolyte is selected from the group consisting of aqueous electrolytes, non-aqueous electrolytes and solid electrolytes that remain stable and inert during operation of the cell.

10. The electrochemical cell of claim 9 wherein the aqueous electrolyte is an aqueous solution of sulfuric acid.

11. The electrochemical cell of claim 10 wherein the reference electrode is selected from the group consisting of a normal hydrogen electrode, a saturated calomel electrode, a silver/silver chloride electrode, a glass or pH electrode, a mercury/mercury sulfate electrode, and a quinhydrone electrode.

12. The electrochemical cell of claim 1 wherein the reference electrode is a chloranil/graphite electrode coated with an intimate mixture of polycarbonate or synthetic rubber and sodium sulfate.

13. The electrochemical cell of claim 1 wherein said means for containing the electrolyte and the electrodes comprise a housing having an electrolyte receiving cavity coextensively positioned therethrough and end plates sealingly mounted at opposite ends of said housing.

14. The electrochemical cell of claim 1 wherein the first working electrode, the second working electrode and the counter electrode are made from a porous fluorocarbon material.

15. The electrochemical cell of claim 1 further including,

(k) means for continuously measuring current flow between the first working electrode and the counter electrode of the cell, said measured current being a measured of the concentration of the gas being detected.

16. The electrochemical cell of claim 1 wherein said means for maintaining a fixed potential on said first working electrode relative to said reference electrode is a potentiostat.

17. The electrochemical cell of claim 1 wherein said means for maintaining a fixed potential on said second working electrode relative to said reference electrode is a potentiostat.

18. The electrochemical cell of claim 1 wherein the noxious gas is selected from the group consisting of ethylene oxide, ethylene glycol, acetaldehyde, ethanol, isopropanol, propylene oxide, acetone and other two to four carbon chain gases.

19. The electrochemical cell of claim 1 wherein the noxious gas is ethylene oxide.

20. An electrochemical cell for quantitatively detecting a noxious gas comprising:

(a) a first end plate;

(b) a second end plate;

(c) a first working electrode comprising a gas diffusion membrane having bonded thereto a catalytic portion electrochemically reactive with the noxious gas;

(d) a second working electrode having electrochemical activity with oxidation/reduction products produced at the first working electrode;

(e) a counter electrode;

(f) a reference electrode;

(g) an electrolyte in contact with the catalytic portion of the first working electrode and in contact with the second working, counter and reference electrodes;

(h) means for containing said electrolyte and said first and second working electrodes, said counter electrode and said reference electrode, said means positioned between said first and second end plates;

(i) means for maintaining a fixed potential on said first working electrode relative to said reference electrode of from about 1.0 to 1.8 volts with respect to the potential of the reversible hydrogen couple in the electrolyte of the cell; and

(j) means for maintaining a fixed current through said second working electrode of from about 1 mA to 30 mA.