Water and oil repellant having desoiling properties

• US 4,859,754 A
• Filed: 10/20/1988
• Issued: 08/22/1989
• Est. Priority Date: 10/20/1987
• Status: Expired due to Term

• Current Assignee: Asahi Glass Company, Limited (AGC, Inc.)
• Original Assignee: Asahi Glass Company, Limited (AGC, Inc.)
• Inventors: Sakaguchi, Tomoko, Oharu, Kazuya, Maekawa, Takashige
• Primary Examiner(s): Schofer, Joseph L.
• Assistant Examiner(s): Sarofim, N.
• Application Number:
  US07/260,261
• Time in Patent Office: 306 Days
• Field of Search: 526/245, 526/243
• US Class Current: 526/245
• CPC Class Codes: C08F 220/24 containing perhaloalkyl radicals
• CPC Class Codes: D06M 15/277 containing fluorine

Abstract

A water and oil repellant having desoiling properties composed of a polyfluorinated group-containing copolymer obtained by copolymerizing the following monomers a and b as essential constituting components:

a: a polyfluorinated group-containing monomer

b: an amphipathic monomer having a hydrophilic moiety and a lipophilic moiety.

Claims

1. A water and oil repellant having desoiling properties composed of a polyfluorinated group-containing copolymer obtained by copolymerizing the following monomers a and b as essential constituting components:

a;

a polyfluorinated group-containing monomer

b;

an amphipathic monomer having a hydrophilic moiety and a lipophilic moiety.

2. The water and oil repellant according to claim 1, wherein the weight ratio of a/b in the polyfluorinated group-containing copolymer. is 65-95/5-35, and the total content of a and b in the copolymer is at least 80% by weight.

3. The water and oil repellant according to claim 1, wherein the polyfluorinated group-containing monomer is a monomer containing a perfluoroalkyl group having from 3 to 20 carbon atoms.

4. The water and oil repellant according to claim 1, wherein the polyfluorinated group-containing monomer is an acrylate or methacrylate containing a perfluoroalkyl group having from 3 to 20 carbon atoms.

5. The water and oil repellant according to claim 1, wherein the amphipathic monomer is a monomer containing mixed polyoxyalkylene groups constituting the hydrophilic moiety and the lipophilic moiety.

6. The water and oil repellant according to claim 1, wherein the amphipathic monomer is an acrylate or methacrylate having the following formula:

space="preserve" listing-type="equation">CH.sup.2 ═

C(R.sup.1)CO.sub.2 [(C.sub.3 H.sub.6 O).sub.m (C.sub.2 H.sub.4 O).sub.n ]R.sup.2

wherein R¹ is H or CH₃, R² is H or a C₁ -C₂₀ alkyl or aralkyl group, m≧

1, n≧

1, n≧

1, and 60≧

m+n≧

2.