Water-tree stable electrical insulating polymeric compositions

• US 4,859,810 A
• Filed: 02/18/1988
• Issued: 08/22/1989
• Est. Priority Date: 07/11/1986
• Status: Expired due to Fees

• Current Assignee: BP Chemicals Ltd. (BP PLC)
• Original Assignee: BP Chemicals Ltd. (BP PLC)
• Inventors: Cloetens, Rudolphe C., Umpleby, Jeffrey D.
• Primary Examiner(s): Hoke, Veronica P.
• Application Number:
  US07/162,335
• Time in Patent Office: 551 Days
• Field of Search: 524/183, 117/110 PM, 117/110 SR
• US Class Current: 174/110.0PM
• CPC Class Codes: C08K 5/55 Boron-containing compounds C08K5/0091 takes precedence
• CPC Class Codes: H01B 3/30 plastics; resins; waxes
• CPC Class Codes: Y10S 174/13 High voltage cable, e.g. above 10kv, corona prevention

Abstract

A composition suitable for use as an electrical insulation comprises a polymeric component and a water-tree retardant additive which is either an organo orthoborate of partial ester of boric acid having the formula B(OR) (OR¹) (OR²) or an organo orthoborate or partial ester of boric acid with a polyhydric hydrocarbyl alcohol.

Claims

1. An electrical wire or cable comprising an electrical conductor and insulation comprising a polymeric component and a water tree retardant additive wherein the water tree retardant additive is selected from the group consisting of:

(A) an organo orthoborate or partial ester of boric acid having the general formula;

space="preserve" listing-type="equation">B (OR) (OR.sup.1) (OR.sup.2)

in which R is an alkyl, aryl, aralkyl, alkaryl or cycloalkyl group having from 4 to 24 carbon atoms and R¹ and R² are individually hydrogen or an alkyl, aryl, aralkyl, alkaryl or cycloalkyl group having from 4 to 24 carbon atoms and

(B) an organo orthoborate or partial ester of boric acid with a polyhydric hydrocarbyl alcohol.

2. An electrical wire or cable as claimed in claim 1 in which the water tree retardant additive is a symmetrical orthoborate.

3. An electrical wire or cable as claimed in claim 2 in which the symmetrical orthoborate has the general formula B(OR)(OR¹)OR²) in which R, R¹ and R² are the same and comprise an alkyl group having from 8 to 24 carbon atoms.

4. An electrical wire and cable as claimed in claim 3 in which the water tree retardant additive is a symmetrical orthoborate having the general formula B(OR)(OR¹)(OR²) in which R, R¹ and R² are the same alkyl group selected from the group consisting of octyl, decyl, dodecyl, tetradecyl, hexadecyl and octadecyl.

5. A electrical wire and cable as claimed in claim 1 in which the water tree retardant additive is an organo orthoborate or partial ester of boric acid with a polyhydric hydrocarbyl alcohol selected from the group consisting of ethylene glycol, 1,3-propane diol, 1,4-butane diol, 1,5-pentane diol, 1,6-hexane diol, cyclohexane -1,4-diol, polyethylene glycol, polypropylene glycol, glycerol, pentaerythritol and poly vinyl alcohol.

6. An electrical wire or cable as claimed in any one of the claims 1 to 5 in which the amount of the water tree retardant additive is from 0.1 to 10% by weight based on the combined weight of the polymeric component and the water tree retardant additive.

7. An electrical wire or cable as claimed in claim 6 in which the amount of the water tree retardant additive is from 0.3 to 5% by weight.

8. An electrical wire or cable as claimed in any one of claims 1 to 18 in which the polymeric component is a homopolymer of ethylene or a copolymer comprising a major proportion of ethylene.

9. An electrical wire or cable as claimed in claim 8 in which the amount of the water tree retardant additive is from 0.1 to 10% by weight based on the combined weight of the polymeric component and the water tree retardant additive.

10. An electrical wire or cable as claimed in claim 9 in which the amount of the water tree retardant additive is from 0.3 to 5% by weight.

11. An electrical wire or cable as claimed in claim 8 in which the polymeric component is selected from the group consisting of low density polyethylene, high density polyethylene, linear low density polyethylene copolymers, copolymers of ethylene with alkyl acrylate, copolymers of ethylene with alkyl methacrylate, copolymers of ethylene with vinyl acetate, silyl polymers and blends thereof.

12. An electrical wire or cable as claimed in claim 11 in which the polymeric component comprises a blend of ethylene-ethyl acrylate copolymer with low density polyethylene in which the total ethyl acrylate content in the component is from 0.5 to 5% by weight.

13. An electrical wire or cable as claimed in claim 1 in which the water tree retardant additive is tridodecyl borate.

14. An electrical wire or cable as claimed in claim 12 in which the water tree retardant additive is tridodecyl borate.

15. A process for improving resistance to the initiation and/or growth of water trees in a polymeric composition used as electrical insulation which comprises insulating an electrical conductor with a polymeric composition comprising a polymeric component and a water tree retardant additive wherein the water tree retardant is selected from the group consisting of:

(A) an organo orthoborate or partial ester of boric acid having the general formula;

space="preserve" listing-type="equation">B (OR) (OR.sup.1) (OR.sup.2)

in which R is an alkyl, aryl, aralkyl, alkaryl or cycloalkyl group having from 4 to 24 carbon atoms and R¹ and R² are individually hydrogen or an alkyl, aryl, aralkyl, alkaryl or cycloalkyl group having from 4 to 24 carbon atoms and

(B) an organo orthoborate or partial ester of boric acid with a polyhydric hydrocarbyl alcohol.

16. A process as claimed in claim 15 in which the polymeric component is a homopolymer of ethylene or a copolymer comprising a major proportion of ethylene.

17. A polymeric composition suitable for use as electrical insulation, comprising:

a polymeric component which comprises a blend of ethylene-ethyl acrylate copolymer with low density polyethylene in which the total ethyl acrylate content is from 0.5 to 5% by weight, and a water tree retardant additive which is an organo orthoborate or partial ester of boric acid with a polyhydric hydrocarbyl alcohol.