Process for removing sulfur dioxide from flue gases

• US 4,861,568 A
• Filed: 09/16/1988
• Issued: 08/29/1989
• Est. Priority Date: 09/16/1988
• Status: Expired due to Fees

• Current Assignee: Samuel B. Robinson
• Original Assignee: Melville W. Robinson Jr
• Inventors: Robinson, Melville W. Jr.
• Primary Examiner(s): HELLER, GREGORY
• Application Number:
  US07/245,276
• Time in Patent Office: 347 Days
• Field of Search: 423/242 A, 423/244 R, 423/243, 423/242 R, 423/244 A
• US Class Current: 423/242.5
• CPC Class Codes: B01D 53/501 by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
• CPC Class Codes: B01D 53/502 characterised by a specific solution or suspension
• CPC Class Codes: C01F 11/464 Sulfates of Ca from gases containing sulfur oxides
• CPC Class Codes: C01P 2006/12 Surface area

Abstract

Sulfur dioxide is removed from flue gases resulting from combustion of sulfur-containing coal in a coal combustion unit by contacting the gases in the coal combustion unit with hydrated lime containing sugars and then adding an aqueous media, preferably containing an alkali metal compound, to the gases in ductwork leading from the coal combustion unit to an electrostatic precipitator.

Claims

1. In a dry process for the removal of sulfur dioxide from flue gases by the addition thereto of hydrated lime containing sugar in a coal combustion unit, wherein the flue gases result from the combustion of coal in a combustion chamber, and the flue gases are treated in an electrostatic precipitator prior to discharge to the atmosphere, the improvement comprising:

passing said flue gases, after the addition of said hydrated lime containing sugar, wherein said hydrated lime is of fine particles of a specific surface of 7 to 25 square meters per gram, through a conduit towards said electrostatic precipitator; and

adding an aqueous media to said flue gases in said conduit in an amount to increase the water content of the flue gases and cool the same by evaporative cooling to a temperature no lower than 20°

F. above the dew point of the gas, so as to avoid forming water droplets in the gas, so as to prevent condensation of water therefrom.

2. The improvement defined in claim 1 wherein said aqueous media is water containing from 1 to 50 percent by weight of an alkali metal compound selected from the group consisting of sodium hydroxide and sodium carbonate.

3. The process of claim 1 where the sugar content of the hydrated lime is from 0.5 to 10.0 weight percent sugar, and the sugar is selected from the group consisting of glucose, fructose, sucrose, maltose, lactose, and mixtures thereof.

4. The process of claim 1 where the mixture of hydrated lime and sugar is obtained by adding a water solution of sugar to soft burned quicklime in a mixer and allowing the temperature to rise to drive off excess water and produce a dry powder of very fine particle size.

5. The process of claim 1 wherein the aqueous media added in the ductwork is in the form of a fine spray or mist.

6. The process of claim 2 wherein the aqueous media containing sodium hydroxide or sodium carbonate added in the ductwork is in the form of a fine spray or mist.