Biodegradable packaging material and the method of preparation thereof

• US 4,863,655 A
• Filed: 12/30/1988
• Issued: 09/05/1989
• Est. Priority Date: 12/30/1988
• Status: Expired due to Term

• Current Assignee: Brunob II B.V. (Ingredion Incorporated)
• Original Assignee: National Starch and Chemical Holding Corporation (Nouryon BV)
• Inventors: Altieri, Paul A., Lacourse, Norman L.
• Primary Examiner(s): Foelak, Morton
• Application Number:
  US07/292,089
• Time in Patent Office: 249 Days
• Field of Search: 264/53, 264/186, 264/DIG. 5, 106/210, 106/213, 106/122, 521/79, 521/82, 521/84.1
• US Class Current: 264/53
• CPC Class Codes: B29C 44/3402 Details of processes or apparatus for reducing environmental damage or for working-up compositions comprising inert blowing agents or biodegradable components
• CPC Class Codes: C08B 30/20 Amylose or amylopectin chemical derivatives thereof C08B33/00, C08B35/00
• CPC Class Codes: C08L 3/12 Amylose; Amylopectin; Degradation products thereof
• CPC Class Codes: Y10S 264/05 Use of one or more blowing agents together

Abstract

A biodegradable packaging material comprising an expanded high amylose starch product having at least 45% by weight amylose content, said expanded product having a low density, closed cell structure with good resilience and compressibility.

Another embodiment provides a method of preparing a low density, biodegradable packaging material comprising extruding a starch having at least 45% by weight amylose content, in the presence of a total moisture content of 21% or less by weight, at a temperature of from 150° to 250° C.

Claims

1. A method of preparing an expanded, biodegradable, low-density packaging material comprising extruding starch containing at least 45% by weight amylose content in the presence of a total moisture content of 21% or less by weight and at a temperature of from about 150°

to 250°

C.

2. The method of claim 1 wherein said starch contains at least 65% by weight of amylose.

3. The method of claim 2 wherein said extruder is a twin-screw extruder and the temperature is maintained in at least the section of the extruder closest to the die and just before the material leaves the extruder.

4. The method of claim 3 wherein the total moisture content is from about 13 to 19% by weight and the temperature is from about 160°

C. to 210°

C.

5. The method of claim 4 wherein the starch is modified with up to about 10% by weight of propylene oxide.

6. The method of claim 2 wherein the starch is modified with up to about 15% by weight of alkylene oxide containing 2 to 6 carbon atoms.

7. The method of claim 6 wherein the total moisture content is from about 13 to 19% by weight and the temperature is from about 160°

to 210°

C.

8. The method of claim 7 wherein the starch is modified with up to about 10% by weight of propylene oxide.

9. The method of claim 8 wherein up to about 10% by weight of polyvinyl alcohol is added to the starch.