Composite elastomeric material

• US 4,863,779 A
• Filed: 03/13/1987
• Issued: 09/05/1989
• Est. Priority Date: 03/24/1986
• Status: Expired due to Term

• Current Assignee: Kimberly-Clark Worldwide Incorporated (Kimberly-Clark Corporation)
• Original Assignee: Kimberly-Clark Corporation
• Inventors: Daponte, Diego H.
• Primary Examiner(s): Bell, James J.
• Application Number:
  US07/025,770
• Time in Patent Office: 907 Days
• Field of Search: 428/152, 428/198, 428/284, 428/286, 428/287, 428/297, 428/298, 428/340, 428/903
• US Class Current: 428/152
• CPC Class Codes: B32B 2038/0028 Stretching, elongating
• CPC Class Codes: B32B 2038/0048 Annealing, relaxing
• CPC Class Codes: B32B 2262/0223 Vinyl resin fibres
• CPC Class Codes: B32B 2262/0253 Polyolefin fibres vinyl or acrylic copolymers B32B2262/0223 or B32B2262/0246
• CPC Class Codes: B32B 2262/14 Mixture of at least two fibres made of different materials
• CPC Class Codes: B32B 2307/51 Elastic
• CPC Class Codes: B32B 2555/02 Diapers or napkins
• CPC Class Codes: B32B 37/144 using layers with different mechanical or chemical conditions or properties, e.g. layers with different thermal shrinkage, layers under tension during bonding constructional features for tensioning B32B38/1825
• CPC Class Codes: B32B 5/26 another layer next to it also being fibrous or filamentary relative arrangement of fibres or filaments of different layers B32B5/12
• CPC Class Codes: B32B 7/14 applied in spaced arrangements, e.g. in stripes
• CPC Class Codes: D04H 1/559 the fibres being within layered webs
• CPC Class Codes: Y10S 428/903 Microfiber, less than 100 micron diameter
• CPC Class Codes: Y10T 428/24446 Wrinkled, creased, crinkled or creped
• CPC Class Codes: Y10T 428/24826 Spot bonds connect components
• CPC Class Codes: Y10T 428/27 Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.]

Abstract

Describes improved composite material comprising an elastic web preferably formed of collected, entangled, nonwoven fibers comprising a copolymer made of ethylene and at least one other vinyl monomer selected from the group including vinyl ester monomers and unsaturated aliphatic monocarboxylic acids and alkyl esters of these monocarboxylic acids, where the amount of monomer other than the ethylene in the copolymer is sufficient to impart elasticity to a cohesive nonwoven web formed from melt-blown fibers of the material. This elastic web is bonded to at least one other web, and preferably is interrelated between two other nonwoven webs of spun-bonded or melt-blown fibers. Discloses processes of making these composite materials. The composites are useful for protective covers and wraps, outerwear, undergarments, menstrual and incontinence control articles, and garments such as disposable diapers and the like.

Claims

1. An elastic composite material comprising at least one elastic web joined at spaced-apart locations to at least one gatherable web, said gatherable web being gathered between said spaced-apart locations, said elastic web comprising a copolymer made of ethylene and from about 10% by weight to about 50% by weight of at least one other vinyl monomer selected from the group consisting of vinyl ester monomers and unsaturated aliphatic monocarboxylic acids and alkyl esters of said monocarboxylic acids.

2. The composite material of claim 1, said composite being made by:

(a) tensioning said elastic web to elongate it;

(b) bonding said elastic web to at least one gatherable web under conditions that soften at least portions of said elastic web, to form a bonded composite web, and

(c) relaxing said composite web immediately after the bonding step whereby said elongated elastic web can contract and the gatherable web is gathered to form said composite elastic material;

wherein said elastic web further comprises at least 10% by weight of said web of said copolymer and from greater than 0% by weight up to about 90% by weight of at least one other compatible modifying polymer that, when blended with said copolymer and subjected to an effective combination of elevated temperature and elevated pressure conditions, is adapted to be extruded, in blended form, with said copolymer.

3. The composite material of claim 2 wherein said modifying polymer is selected from the group including polyethylene, polypropylene, polybutene, polystyrene, copolymers and mixtures of these, and an ABA'"'"' block copolymer, where A and A'"'"' are each a thermoplastic polymer endblock that includes a styrenic moiety and where B is an elastomeric poly(ethylene-butene) midblock, and mixtures thereof.

4. The composite material of claim 3 wherein said copolymer is present in an amount sufficient to impart elasticity to a coherent web formed by collecting melt-blown fibers of said composition.

5. The composite material of claim 2 wherein said modifying polymer comprises at least one polymer selected from the group consisting of ethylene, propylene, polybutene, ethylene copolymers, propylene copolymers, and butene copolymers.

6. The composite material of claim 5 wherein said modifying polymer comprises a blend of two or more polymers selected from the group consisting of polyethylene, polypropylene, polybutene, ethylene copolymers, propylene copolymers, and butene copolymers.

7. The composite material of claim 5 wherein said modifying polymer comprises polyethylene.

8. The composite material of claim 5 wherein said modifying polymer comprises polypropylene.

9. The composite material of claim 5 wherein said modifying polymer is polybutene.

10. The composite material of claim 5 wherein said modifying polymer is an isobutylene-butene copolymer.

11. The composite material of claim 1 wherein said elastic web comprises a nonwoven coherent web of melt-blown microfibers.

12. The composite material of claim 5 wherein said elastic web comprises a nonwoven coherent web of melt-blown microfibers.

13. An elastic composite material comprising at least one elastic web joined at spaced-apart locations to at least one gatherable web, said gatherable web being gathered between said spaced-apart locations, said elastic web comprising poly(ethylene-vinyl acetate) having a nominal melt index in the range from 50 to 200 at 190°

C. and comprising from 18% by weight to about 36% by weight of vinyl acetate, said composite material being made by

(a) tensioning said elastic web to elongate it;

(b) bonding said elastic web to at least one gatherable web under conditions that soften portions of said elastic web at locations that are spaced from each other, to form a bonded composite web, and

(c) relaxing said composite web immediately after the bonding step whereby said elongated elastic web contract and the gatherable web is gathered to form said composite elastic material.

14. The composite material of claim 13 wherein said elastic web comprises a nonwoven coherent web of melt-blown microfibers.

15. The composite material of claim 14 further comprising secondary fibers intermixed with said melt-blown microfbers.

16. The composite material of claim 14 wherein said melt-blown microfibers are in the form of a nonwoven coherent web that exhibits the ability to be stretched to at least 150% of the web length as formed.

17. The composite material of claim 14 wherein said nonwoven elastomeric web comprises

(a) microfibers comprising poly(ethylene-vinyl acetate) having a nominal melt index in the range from 32 to 300 at 190°

C. and comprising from 18% by weight to about 36% by weight of vinyl acetate; and

(b) from greater than 0% by weight to about 80% by weight of at least one different secondary fiber that is generally uniformly distributed throughout said nonwoven web.

18. The composite material of claim 17 wherein said secondary fiber comprises a fibrous material selected from the group consisting of wood pulp fiber, staple natural fiber, staple artificial fiber, and mixtures thereof.

19. The composite material of claim 14 wherein said melt-blown fibers are formed form a blend of said poly(ethylene-vinyl acetate) with from greater than 0% by weight up to about 90% by weight of said fibers of at least one other compatible modifying polymer which, when blended with said copolymer and subjected to an effective combination of elevated temperature and elevated pressure conditions, is adapted to be extruded, in blended form, with said copolymer.

20. The composite material of claim 19 wherein said modifying polymer is selected from the group including polyethylene, polypropylene, polybutene, polystyrene, copolymers and mixtures of these, and an ABA'"'"' block copolymer, where A and A'"'"' are each independently a thermoplastic polymer endblock that includes a styrenic moiety and where B is an elastomeric poly(ethylene-butene) midblock, and mixtures thereof.

21. The composite material of claim 20 wherein said modifying polymer comprises at least one polymer selected from the group consisting of polyethylene, polypropylene, polybutene, ethylene copolymers, propylene copolymers, and butene copolymers.

22. The composite material of claim 21 wherein said modifying polymer comprises a blend of two or more polymers selected from the group consisting of polyethylene, polypropylene, polybutene, ethylene copolymers, propylene copolymers, and butene copolymers.

23. The composite material of claim 14 wherein said elastic web is bonded to the gatherable web at a plurality of spaced-apart locations in a repeating pattern and wherein the gatherable web is gathered between said bonded locations.

24. The composite material of claim 14 wherein said elastic web has a basis weight of up to about 300 grams per square meter.

25. The composite material of claim 13 wherein said gatherable web is a nonwoven coherent nonelastic material and is formed from an interlaced web of fibers selected from the group consisting of polyester fibers, polyolefin fibers, polyamide fibers, cellulosic fibers, and mixtures of two or more thereof.

26. The composite material of claim 25 wherein said gatherable web comprises spun-bonded or melt-brown fibers of polyethylene, polypropylene, a random copolymer of ethylene and propylene, and blends thereof.

27. An elastic composite material comprising at least one elastic web joined at spaced-apart locations to at least one gatherable web, said gatherable web being gathered between said spaced-apart locations, said elastic web comprising poly (ethylene-vinyl acetate) comprising from about 10% by weight to about 50% by weight of vinyl acetate.

28. The composite material of claim 27 wherein said elastic web comprises a nonwoven coherent web of melt-blown microfibers.

29. The composite material of claim 28 further comprising secondary fibers intermixed with said melt-blown microfibers.

30. The composite material of claim 28 wherein said melt-blown microfibers are in the form of a nonwoven coherent web that exhibits the ability to be stretched to at least 150 percent of the web length formed.

31. The composite material of claim 28 wherein said nonwoven elastomeric web comprises

(a) microfibers comprising poly(ethylene-vinyl acetate) having a nominal melt index in the range from 32 to 300 at 190°

C. and comprising from 10% by weight to about 50% by weight by weight of vinyl acetate; and

(b) from greater than 0% by weight to about 80% by weight of at least one different secondary fiber that is generally uniformly distributed throughout said nonwoven web.

32. The composite material of claim 31 wherein said secondary fiber comprises a fibrous material selected from the group consisting of wood pulp fiber, staple natural fiber, staple artificial fiber, and mixtures thereof.

33. The composite material of claim 28 wherein said melt-blown fibers are formed from a blend of said poly(ethylene-vinyl acetate) with from greater than 0% by weight up to about 90% by weight of aid fibers of at least one other compatible modifying polymer which, when blended with said copolymer and subjected to an effective combination of elevated temperature and elevated pressure conditions, is adapted to be extruded, in blended form, with said copolymer.

34. The composite material of claim 33 wherein said modifying polymer is selected from the group including polyethylene, polypropylene, polybutene, polystyrene, copolymers and mixtures of these, and an ABA'"'"' block copolymer, where A and A'"'"' are each independently a thermoplastic polymer endblock that includes a styrenic moiety and where B is an elastomeric poly(ethylenebutene) midblock, and mixtures thereof.

35. The composite material of claim 34 wherein said modifying polymer comprises a blend of two or more polymers selected from the group consisting of polyethylene, polypropylene, polybutene, ethylene copolymers, propylene copolymers, and butene copolymers.

36. The composite material of claim 28 wherein said elastic web has a basis weight of up to about 300 grams per square meter.

37. The composite material of claim 27 wherein said gatherable web is a nonwoven coherent nonelastic material and is formed form an interlaced web of fibers selected from the group consisting of polyester fibers, polyefin fibers, polyamide fibers, cellulosic fibers, and mixtures of two or more thereof.

38. The composite material of claim 37 wherein said gatherable web comprises spun-bonded or melt-blown fibers of polyethylene, polypropylene, a random copolymer of ethylene and propylene, and blends thereof.

39. An elastic composite material comprising at least one elastic web joined at spaced-apart locations to at least one gatherable web, said gatherable web being gathered between said spaced-apart locations, said elastic web comprising poly (ethylene-vinyl acetate comprising from about 18% by weight to about 36% by weight of vinyl acetate.

40. The composite material of claim 39 wherein said elastic web comprises a nonwoven coherent web of melt-blown microfibers.

41. The composite material of claim 40 further comprising secondary fibers intermixed with said melt-blown microfibers.

42. The composite material of claim 40 wherein said melt-blown microfibers are in the form of a nonwoven coherent web that exhibits the ability to be stretched to at least 150 percent of the web length formed.

43. The composite material of claim 40 wherein said nonwoven elastomeric web comprises

(a) microfibers comprising poly(ethylene-vinyl acetate) having a nominal melt index in the range from 32 to 300 at 190°

C. and comprising from 18% by weight to about 36% by weight by weight of vinyl acetate; and

(b) from greater than 0% by weight to about 80% by weight of at least one different secondary fiber that is generally uniformly distributed throughout said nonwoven web.

44. The composite material of claim 43 wherein said secondary fiber comprises a fibrous material selected from the group consisting of wood pulp fiber, staple natural fiber, staple artificial fiber, and mixtures thereof.

45. The composite material of claim 40 wherein said melt-blown fibers are formed from a blend of said poly(ethylene-vinyl acetate) with from greater than 0% by weight up to about 90% by weight of said fibers of at least one other compatible modifying polymer which, when blended with said copolymer and subjected to an effective combination of elevated temperature and elevated pressure conditions, is adapted to be extruded, in blended form, with said copolymer.

46. The composite material of claim 45 wherein said modifying polymer is selected from the group including polyethylene, polypropylene, polybutene, polystyrene, copolymers and mixtures of these, and ABA'"'"' block copolymer, where A and A'"'"' are each independently a thermoplastic polymer endblock that includes a styrenic moiety and where B is an elastomeric poly(ethylenebutene) midblock, and mixtures thereof.

47. The composite material of claim 46 wherein said modifying polymer comprises a blend of two or more polymers selected from the group consisting of polyethylene, polypropylene, polybutene, ethylene copolymers, propylene copolymers, and butene copolymers.

48. The composite material of claim 40 wherein said elastic web has a basis weight of up to about 300 grams per square meter.

49. The composite material of claim 39 wherein said gatherable web is a nonwoven coherent nonelastic material and is formed form an interlaced web of fibers selected from the group consisting of polyester fibers, polyolefin fibers, polyamide fibers, cellulosic fibers, and mixtures of two or more thereof.

50. The composite material of claim 49 wherein said gatherable web comprises spun-bonded or melt-blown fibers of polyethylene, polypropylene, a random copolymer of ethylene and propylene, and blends thereof.

51. An elastic composite material comprising at least one elastic web joined at spaced-apart locations to at least one gatherable web, said gatherable web being gathered between said spaced-apart locations, said elastic web comprising poly (ethylene-vinyl acetate) comprising from about 26% by weight to about 30% by weight of vinyl acetate.

52. The composite material of claim 51 wherein said elastic web comprises a nonwoven coherent web of melt-blown microfibers.

53. The composite material of claim 52 further comprising secondary fibers intermixed with said melt-blown microfibers.

54. The composite material of claim 52 wherein said melt-blown microfibers are in the form of a nonwoven coherent web that exhibits the ability to be stretched to at least 150 percent of the web length formed.

55. The composite material of claim 52 wherein said nonwoven elastomeric web comprises

(a) microfibers comprising poly(ethylene-vinyl acetate) having a nominal melt index in the range from 32 to 300 at 190°

C. and comprising from 26% by weight to about 30% by weight by weight of vinyl acetate; and

(b) from greater than 0% by weight to about 80% by weight of at least one different secondary fiber that is generally uniformly distributed throughout said nonwoven web.

56. The composite material of claim 55 wherein said secondary fiber comprises a fibrous material selected from the group consisting of wood pulp fiber, staple natural fiber, staple artificial fiber, and mixtures thereof.

57. The composite material of claim 52 wherein said melt-blown fibers are formed from a blend of said poly(ethylene-vinyl acetate) with from greater than 0% by weight up to about 90% by weight of said fibers of at least one other compatible modifying polymer which, when blended with said copolymer and subjected to an effective combination of elevated temperature and elevated pressure conditions, is adapted to be extruded, in blended form, with said copolymer.

58. The composite material of claim 57 wherein said modifying polymer is selected from the group including polyethylene, polypropylene, polybutene, polystyrene, copolymers and mixtures of these, and an ABA'"'"' block copolymer, where A and A'"'"' are each independently a thermoplastic polymer endblock that includes a styrenic moiety and where B is an elastomeric poly(ethylene-butene) midblock, and mixtures thereof.

59. The composite material of claim 58 wherein said modifying polymer comprises a blend of two or more polymers selected from the group consisting of polyethylene, polypropylene, polybutene, ethylene copolymers, propylene copolymers, and butene copolymers.

60. The composite material of claim 52 wherein said elastic web has a basis weight of up to about 300 grams per square meter.

61. The composite material of claim 51 wherein said gatherable web is a nonwoven coherent nonelastic material and is formed form an interlaced web of fibers selected from the group consisting of polyester fibers, polyolefin fibers, polyamide fibers, cellulosic fibers, and mixtures of two or more thereof.

62. The composite material of claim 61 wherein said gatherable web comprises spun-bonded or melt-blown fibers of polyethylene, polypropylene, a random copolymer of ethylene and propylene, and blends thereof.

63. An elastic composite material comprising at least one elastic web joined at spaced-apart locations to at least one gatherable web, said gatherable web being gathered between said spaced-apart locations, said elastic web comprising poly (ethylene-vinyl acetate) consisting essentially of from about 26% by weight to about 30% by weight of vinyl acetate.

64. The composite material of claim 63 wherein said elastic web comprises a nonwoven coherent web of melt-blown microfibers.

65. The composite material of claim 64 further comprising secondary fibers intermixed with said melt-blown microfibers.

66. The composite material of claim 64 wherein said melt-blown microfibers are in the form of a nonwoven coherent web that exhibits the ability to be stretched to at least 150 percent of the web length formed.

67. The composite material of claim 64 wherein said nonwoven elastomeric web comprises

(a) microfibers comprising poly(ehtylene-vinyl acetate) having a nominal melt index in the range from 32 to 300 at 190°

C. and consisting essentially of from about 26% by weight to about 30% by weight by weight of vinyl acetate; and

(b) from greater than 0% by weight to about 80% by weight of at least one different secondary fiber that is generally uniformly distributed throughout said nonwoven web.

68. The composite material of claim 67 wherein said secondary fiber comprises a fibrous material selected from the group consisting of wood pulp fiber, staple natural fiber, staple artificial fiber, and mixtures thereof.

69. The composite material of claim 64 wherein said melt-blown fibers are formed from a blend of said poly(ethylene-vinyl acetate) with from greater than 0% by weight up to about 90% by weight of said fibers of at least one other compatible modifying polymer which, when blended with said copolymer and subjected to an effective combination of elevated temperature and elevated pressure conditions, is adapted to be extruded, in blended form, with said copolymer.

70. The composite material of claim 69 wherein said modifying polymer is selected from the group including polyethylene, polypropylene, polybutene, polystyrene, copolymers and mixtures of these, and an ABA'"'"' block copolymer, where A and A'"'"' are each independently a thermoplastic polymer endblock that includes a styrenic moiety and where B is an elastomeric poly(ethylene-butene) midblock, and mixtures thereof.

71. The composite material of claim 70 wherein said modifying polymer comprises a blend of two or more polymers selected from the group consisting of polyethylene, polypropylene, polybutene, ethylene copolymers, propylene copolymers, and butene copolymers.

72. The composite material of claim 64 wherein said elastic web has a basis of weight of up to about 300 grams per square meter.

73. The composite material of claim 63 wherein said gatherable web is a nonwoven coherent nonelastic material and is formed form an interlaced web of fibers selected from the group consisting of polyester fibers, polyolefin fibers, polyamide fibers, cellulosic fibers, and mixtures of two or more thereof.

74. The composite material of claim 73 wherein said gatherable web comprises spun-bonded or melt-blown fibers of polyethylene, polypropylene, a random copolymer of ethylene and propylene, and blends thereof.