Primary source of electrical energy using a mixture of fuel and oxidizer

• US 4,863,813 A
• Filed: 09/15/1988
• Issued: 09/05/1989
• Est. Priority Date: 09/15/1988
• Status: Expired

• Current Assignee: Bell Communications Research, Inc. (Telefonaktiebolaget LM Ericsson)
• Original Assignee: Bell Communications Research, Inc. (Telefonaktiebolaget LM Ericsson)
• Inventors: Dyer, Christopher K.
• Primary Examiner(s): Skapars, Anthony
• Application Number:
  US07/244,350
• Time in Patent Office: 355 Days
• Field of Search: 429/30, 429/33, 429/191-193, 429/40, 429/41, 429/44
• US Class Current: 429/481
• CPC Class Codes: G01N 27/4071 using sensor elements of laminated structure
• CPC Class Codes: H01M 8/10 Fuel cells with solid electrolytes
• CPC Class Codes: H01M 8/1004 characterised by membrane-electrode assemblies [MEA] H01M8/12 takes precedence
• CPC Class Codes: H01M 8/1007 with both reactants being gaseous or vaporised H01M8/12 takes precedence
• CPC Class Codes: H01M 8/1009 with one of the reactants being liquid, solid or liquid-charged H01M8/12 takes precedence
• CPC Class Codes: H01M 8/1023 having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A solid electrolyte fuel cell capable of operating with a mixture of an oxidizer and a fuel includes a permeable catalytic electrode and an impermeable catalytic electrode separated by an electron insulating, ion conducting, gas permeable solid electrolyte. The device produces charge flow in an external circuit when the permeable electrode is exposed to a mixture including an oxidizer and a fuel such as hydrogen, methane or methanol.

The solid electrolyte can be a hydrated aluminum oxide, primarily of the pseudoboehmite structure and either electrode can be Pt or Pd. The solid electrolyte can be produced by exposing a bulk aluminum surface or a deposited layer of aluminum to water or water vapor or by exposing an anodically oxidized layer of aluminum oxide to water vapor. The device is produced in thin film form and can be produced by techniques compatible with thin film device fabrication.

The magnitude and direction of the charge flow is dependent on the particular fuel, so that the device can serve as a species selective, gas sensor which does not require the external application of sensing power in order to produce a measurable voltage.

Claims

1. A device which is a source of electrical current comprising a first electrode and a second electrode separated by and in contact with a solid electrolyte body characterized in that the first electrode is permeable to an oxidizer and a fuel, the second electrode is impermeable to the oxidizer and the fuel and the solid electrolyte body consists essentially of an electron insulating material which is also ionically conducting to at least a first ionic species and which material is permeable to the oxidizer, the fuel and products of the electrochemical reactions of the oxidizer and the fuel.

2. A device of claim 1 in which the said species is ionic hydrogen.

3. A device of claim 1 including means for exposing the first electrode to a mixture comprising the oxidizer and the fuel.

4. A device of claim 1 in which the oxidizer and fuel are gaseous.

5. A device of claim 1 in which the said material consists essentially of a hydrated oxide of aluminum consisting primarily of the pseudoboehmite structure.

6. A device of claim 5 in which the said material is at least 50% of the pseudoboehmite structure.

7. A device of claim 5 in which the solid electrolyte body is from 30 Angstroms to 10 microns in thickness.

8. A device of claim 1 in which the said material consists essentially of a crabon based polymer.

9. A device of claim 8 in which the carbon based polymer is polyacrylic acid.

10. A device of claim 1 in which the oxidizing gas is oxygen and the fuel is at least one member of the group consisting of hydrogen, methane and methanol.

11. A device of claim 1 including means for electrically connecting the first electrode and the second electrode to a utilizing device.

12. A device of claim 10 in which the solid electrolyte body is from 30 Angstroms to 1 millimeter in thickness.

13. A device of claim 12 in which the utilizing device includes means for differentiating between the presence or absence of a flow of electrons and the direction of the flow of electrons.

14. A device of claim 1 in which the said material is produced by a method including exposing a metallic aluminum body to H₂ O.

15. A device of claim 14 in which the temperature of the aluminum during the exposure is at least 20°

C.

16. A device of claim 2 in which the first electrode and the second electrode consist essentially of Pt or Pd or alloys of Pt and Pd.

17. A device of claim 1 in which the said material is produced by a method including the steps of anodizing a metallic aluminum body to produce an aluminum oxide film and subsequently exposing the aluminum oxide film to H₂ O.