Process for the manufacture of a catalyst

• US 4,863,894 A
• Filed: 06/21/1988
• Issued: 09/05/1989
• Est. Priority Date: 06/22/1987
• Status: Expired due to Term

• Current Assignee: Johnson Matthey PLC
• Original Assignee: Imperial Chemical Industries PLC (IMPERIAL CHEMICAL INDUSTRIES)
• Inventors: Chinchen, Godfrey C., Jennings, James R.
• Primary Examiner(s): Shine, W. J.
• Application Number:
  US07/209,572
• Time in Patent Office: 441 Days
• Field of Search: 502/244, 502/307, 502/318, 502/340, 502/341, 502/342, 502/343
• US Class Current: 502/342
• CPC Class Codes: B01J 23/80 with zinc, cadmium or mercury
• CPC Class Codes: B01J 23/84 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
• CPC Class Codes: B01J 23/85 Chromium, molybdenum or tungsten
• CPC Class Codes: B01J 35/392 Metal surface area
• CPC Class Codes: C01B 3/16 using catalysts
• CPC Class Codes: Y02P 20/52 using catalysts, e.g. selective catalysts

Abstract

A catalyst suitable for a carbon oxides conversion process comprises metallic copper and oxides of zinc and/or magnesium and has a copper metal surface area of at least 70 m² per g of copper.

Whereas conventional catalysts are normally made by forming an intimate mixture of discrete particles of compounds of copper, and zinc and/or magnesium, and optionally at least one other element such as aluminum, calcining the composition to convert the constituents to oxides and then subjecting the calcined composition to reduction conditions so that the copper compounds therein are converted to copper, the high copper area catalysts are made by a process in which the calcination stage is omitted so that the copper compounds in the intimate mixture are reduced to metallic copper without the intimate mixture being heated to a temperature above 250° C.

Where the catalyst is required in pelleted form, it is preferably pelleted after reduction.

Claims

1. A process for the manufacture of a catalyst comprising

(a) forming an intimate mixture of precipitated compounds of copper, and of at least one metal selected from zinc and magnesium, by precipitation from an aqueous solution of salts of copper and said at least one metal using an alkali metal carbonate as precipitant, and

(b) without heating said mixture to a temperature above 200°

C., converting the precipitated compounds of said at least one metal to oxides and reducing the precipitated copper compound in said mixture to metallic copper, the maximum temperature at which said reduction is effected being in the range 150°

to 200°

C.,

whereby the copper metal surface area of said catalyst is at least 70 m² per gram of copper.

2. A process according to claim 1 wherein said intimate mixture also contains precipitated zinc and aluminum compounds formed by double decomposition of zinc nitrate and sodium aluminate.

3. A process according to claim 2 wherein the proportions of said precipitated compounds in said mixture are such that the catalyst contains 10 to 80% by weight of copper.

4. A process according to claim 2 wherein the proportions of said precipitated compounds in said mixture are such that the catalyst contains a total of 0.3 to 2.5 atoms of zinc and magnesium (if present) per atom of copper.

5. A process according to claim 2 wherein the proportions of said precipitated compounds in said mixture are such that the aluminum atoms constitute 4 to 30% of the total number of copper, aluminum, zinc, and magnesium (if present) atoms.

6. A process according to claim 1 wherein after reduction of the copper compounds, the composition is pelleted.