Olefin polymerization catalyst

• US 4,866,022 A
• Filed: 04/25/1988
• Issued: 09/12/1989
• Est. Priority Date: 03/23/1984
• Status: Expired due to Term

• Current Assignee: Amoco Corporation (BP PLC)
• Original Assignee: Amoco Corporation (BP PLC)
• Inventors: Karayannis, Nicholas M., Lee, Sam S., Arzoumanidis, Gregory G., Khelghatian, Habet M., Johnson, Bryce V.
• Primary Examiner(s): Garvin, Patrick P.
• Application Number:
  US07/186,359
• Time in Patent Office: 505 Days
• Field of Search: 502/118, 502/120, 502/121, 502/122, 502/123, 502/124, 502/125, 502/126, 502/127, 502/133
• US Class Current: 502/120
• CPC Class Codes: C08F 10/00 Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
• CPC Class Codes: C08F 4/02 Carriers therefor
• CPC Class Codes: C08F 4/654 with magnesium or compounds thereof
• CPC Class Codes: C08F 4/6546 organo-magnesium compounds
• CPC Class Codes: C08F 4/6565 and magnesium or compounds thereof

Abstract

A solid hydrocarbon-insoluble, alpha-olefin polymerization catalyst component with superior activity, stereospecificity and morphology characteristics comprises the product formed by (A) forming a solution of a magnesium-containing species from a magnesium carbonate or a magnesium carboxylate; (B) precipitating solid particles from such magnesium-containing solution by treatment with a transition metal halide and an organosilane; (C) reprecipitating such solid particles from a mixture containing a cyclic ether; and (D) treating the reprecipitated particles with a transition metal compound and an electron donor.

Claims

1. A solid, hydrocarbon-insoluble alpha-olefin polymerization catalyst component comprises a product formed by:

A. forming a solution of a magnesium-containing species from a magnesium carbonate or a magnesium carboxylate;

B. precipitating solid particles from such magnesium-containing solution by treatment with a transition metal halide and an organosilane having a formula;

R_n SiR'"'"'_4"n, wherein n=0 to 4 and wherein R is hydrogen or an alkyl, a haloalkyl or aryl radical containing one to about ten carbon atoms or a halosilyl radical or haloalkylsilyl radical containing one to about eight carbon atoms, and R, or a halogen;

C. reprecipitating such solid particles from a mixture containing a cyclic ether; and

D. treating the reprecipitated particles with a transition metal compound and an electron donor.

2. The catalyst component of claim 1 wherein the magnesium carbonate solution is formed from a magnesium alkoxide and carbon dioxide.

3. The catalyst component of claim 2 wherein the magnesium alkoxide is solubilized with an alcohol.

4. The catalyst hilide of claim 1 wherein the transition metal hilide in Step B is a titanium hilide.

5. The catalyst component of claim 1 wherein the transition metal hilide in Step B is a titanium tetrachloride.

6. The catalyst component of claim 1 wherein the transition metal compound in Step D is a titanium tetrachloride.

7. The catalyst compound of claim 1 wherein the cyclic ether is tetrahydrofuran, tetrahydropyran or 2-methyltetrahydrofuran

8. The catalyst component of claim 1 wherein the organosilane is trimethylchlorosilane, trimethylethoxysilane, dimethyldichlorosilane or tetraethoxysilane.

9. The catalyst component of claim 1 wherein the particles from the Step D are treated with titanium tetrachloride and then with titanium tetrachloride in the presence of an electrode donor.

25. An alpha-olefin polymerization catalyst comprising the solid component of claim 1, an alkylaluminum compound, and an organosilane.

26. The catalyst component of claim 1 wherein the transition metal compound in Step D is a titanium(IV) compound.

28. The catalyst component of claim 1 wherein the cyclic ether in Step C is a thioether.

29. The catalyst component of claim 1 wherein the cyclic ether in Step C is tetrahydrothiophene, 2,2,5,5-tetrahydrofuran or tetrahydropyran-2-methanol.

30. The catalyst component of claim 1 wherein cyclohexane oxide, cyclohexanone, ethyl acetate or phenyl acetate is used as a reprecipitation medium in Step C.

10. A solid, hydrocarbon-insoluble alpha-olefin polymerization catalyst component comprises a product formed by:

A. forming a solution in an alcohol medium of a magnesium containing species formed from a magnesium alkoxide and carbon dioxide.

B. precipitating solid particles from such magnesium-containing solution by treatment with a titanium halide and an organosilane having a formula;

R_n SiR'"'"'_4-n wherein n=0 to 4 and wherein R is hydrogen or an alkyl, a haloalkyl or aryl radical containing one to about ten carbon atoms of a halosilyl radical or haloalkylsilyl radical containing one to about eight carbon atoms, and R, is OR or a halogen;

C. reprecipitating such solid particles from a mixture containing a cyclic ether; and

D. treating the reprecipitated particles with a Ti(IV) compound and then with a mixture of a Ti(IV) compound and an electron donor.

11. The catalyst component of claim 10 wherein the titanium halide in Step B is a titanium tetrachloride.

12. The catalyst component of claim 11 wherein the cyclic ether in Step C is tetrahydrofuran.

13. The catalyst component of claim 12 wherein the Ti(IV) compound in Step D is a titanium tetrachloride.

14. The catalyst component of claim 13 wherein the organosilane is trimethylchlorosilane, trimethylethoxysilane, dimethyldichlorosilane or tetraethoxysilane.

15. The catalyst component of claim 14 wherein the electron donor in Step D is a dialkylphthalate ester.

16. The catalyst component of claim 15 wherein the electron donor in Step D is diisobutylphthalate, diethylphthalate or di-n-butylphthalate.

17. The catalyst component of claim 16 wherein in Step A the alcohol is 2-ethyl-1-hexanol, the organosilane in Step B is tetraethoxysilane, and the electron donor in Step D is di-n-butylphthalate, diisobutylphthalate or mixtures thereof.

18. The catalyst component of claim 17 wherein the electron donor in Step D is di-n-butylphthalate.

27. The catalyst component of claim 13 wherein in Step A the magnesium alkoxide is magnesium ethoxide.

19. A solid, hydrocarbon-insoluble alpha-olefin polymerization catalyst comprises a product formed by precipitating solid particles from a magnesium hydrocarbyl carbonate solution in an alcohol by treatment with titanium tetrachloride and an organosilane having a formula:

R_n SiR'"'"'_4-n, wherein n=1 to 4 and wherein R is hydrogen or an alkyl, a haloalkyl or aryl radical containing one to about ten carbon atoms or a halosilyl radical or haloalkylsilyl radical containing one to about eight carbon atoms, and R, is OR or a halogen and treating the resulting solid particles with titanium tetrachloride and an electron donor.

20. The catalyst component of claim 19 wherein the organosilane is trimethylchlorosilane, dimethyldichlorosilane or tetraethoxysilane.

21. The catalyst component of claim 19 wherein the electron donor is a dialkylphthalate ester.

22. The catalyst component of claim 19 wherein the electron donor is diisobutylphthalate, diethylphthalate, or di-n-butylphthalate.

23. The catalyst component of claim 19 wherein the magnesium hydrocarbyl carbonate solution is formed from a magnesium alkoxide and carbon dioxide.

24. The catalyst component of claim 19 wherein the magnesium hydrocarbyl carbonate solution is formed from magnesium ethoxide and carbon dioxide in 2-ethylhexanol.