Impact resistant thermoplastic molding materials

• US 4,866,129 A
• Filed: 07/13/1988
• Issued: 09/12/1989
• Est. Priority Date: 04/07/1981
• Status: Expired due to Term

• Current Assignee: BASF AG (BASF SE)
• Original Assignee: BASF AG (BASF SE)
• Inventors: Haaf, Franz, Brandstetter, Franz, Naarmann, Herbert, Echte, Adolf
• Primary Examiner(s): Ziegler, Jacob
• Application Number:
  US07/220,423
• Time in Patent Office: 426 Days
• Field of Search: 525/364, 525/533, 525/658, 525/715, 525/931, 525/470, 525/92, 525/905
• US Class Current: 525/92.00D
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 51/04 grafted on to rubbers
• CPC Class Codes: C08L 71/123 not modified by chemical after-treatment
• CPC Class Codes: Y10S 525/905 Polyphenylene oxide

Abstract

Impact resistant thermoplastic molding materials containing a styrene polymer modified with rubber to be impact resistant, a hydrogenated styrene containing block copolymer and a polyphenylene ether as well as optional additives in which 50 to 98 percent by weight of the particles of the flexible component of the impact resistant styrene polymer have an average particle diameter of equal to or less than 1.0 micron and 2 to 50 percent by weight of the particles of the flexible have an average particle diameter of equal to or greater than 2 microns.

Claims

1. An impact resistant thermoplastic molding composition, comprising:

(A) from 5 to about 90 parts by weight of a mixture of;

(a) 50 to 99 percent by weight relative to the mixture (A) of an impact resistant styrene polymer, wherein said impact resistance is imparted by the presence of from 20 to about 60 percent by weight relative to the weight of said impact resistant styrene polymer (a) of particles of a flexible component having a particle size distribution of from 0.5 to 10 microns, from 50 to 98 percent by weight of said flexible component particles having a mean particle diameter of less than or equal to 1.0 micron, and 50 to 2 percent by weight having a mean diameter of greater than or equal to 2.0 microns, said flexible component particles comprising a rubber selected from the group consisting of natural rubber, polyisoprene, polybutadiene, copolymers of butadiene and styrene, copolymers of isoprene and styrene, and terpolymers of butadiene, isoprene, and styrene; and

(b) from 1 to about 50 percent by weight relative to said mixture (A), of a hydrogenated block copolymer of a monovinyl or monovinylidine aromatic compound and a conjugated diene; and

(B) from 95 to about 10 parts by weight of a polyphenylene ether.

2. The molding composition of claim 1, wherein said monovinyl or monovinylidene compound is selected from the group consisting of styrene, α

-methylstyrene, vinyltoluene, and ethylvinylbenzene.

3. The molding composition of claim 1, wherein said polyphenylene ether has an intrinsic viscosity of from about 0.45 to about 0.65 dl/g as measured in chloroform at 30°

C.