Method of processing exposed photographic silver dye bleach materials comprising heating after processing liquid application

• US 4,868,098 A
• Filed: 01/05/1988
• Issued: 09/19/1989
• Est. Priority Date: 01/06/1987
• Status: Expired due to Fees

• Current Assignee: Ilford AG
• Original Assignee: Ciba-Geigy AG (Novartis Ag)
• Inventors: Furholz, Urs J., Steiger, Rolf
• Primary Examiner(s): Michl, Paul R.
• Assistant Examiner(s): Doody, Patrick A.
• Application Number:
  US07/171,917
• Time in Patent Office: 623 Days
• Field of Search: 430/351, 430/378, 430/393, 430/406, 430/419, 430/431, 430/434, 430/436, 430/438, 430/441, 430/445, 430/460, 430/462, 430/463, 430/963
• US Class Current: 430/393
• CPC Class Codes: G03C 7/28 Silver dye bleach processes; Materials therefor; Preparing or processing such materials
• CPC Class Codes: Y10S 430/164 Rapid access processing

Abstract

The processing of exposed silver dye bleach materials by applying, to the uppermost layer of the material, an amount of processing liquid which corresponds to not more than the swelling volume of the material, followed by a heat treatment.

The process is particularly suitable for the production of positive colored images, especially in automatic copying or photographing machines.

Claims

1. A method of processing exposed photographic silver dye bleach materials using the process stages (1) development, (2) dye bleach, (3) silver bleach, (4) fixing and (5) washing, it being possible to combine process stage (3) with process stage (2), or with process stages (2) and (4) into one process stage, which comprises, for the process stages (1) and (2) or the process stages (1) and also (2) and (3) combined or the process stages (1) and also (2) and (3) and (4) combined, applying to the uppermost layer of the material an amount of corresponding processing liquid which is equivalent to not more than the swelling volume of the material, subjecting the material to a heat treatment after each treatment with processing liquid, and, if appropriate, washing and drying the material.

2. A process according to claim 1, wherein a processing liquid containing hydroquinone and phenidone is used for process stage (1), hydroquinone being present in a concentration of 15 to 35 g/l.

3. A process according to claim 1, wherein a processing liquid containing phenidone and benzotriazole in an amount such that virtually no development takes place at room temperature is used for process stage (1).

4. A process according to claim 3, wherein the concentrations of phenidone and benzotriazole are within the range from 0.1 to 0.6 and 0.9 to 1.6, respectively, g/l.

5. A process according to claim 1, wherein a processing liquid containing, per kg, 5 to 30 g of a water-soluble organic nitro compound, 15 to 40 g of iodide, 50 to 200 g of sulfuric acid, 2 to 15 g of dye bleach catalyst and 0.5 to 20 g of nonionic wetting agent is used for process stage (2).

6. A process according to claim 1, wherein a processing liquid containing, per kg, 5 to 30 g of a water-soluble organic nitro compound, 40 g to 250 g of iodide, 50 to 200 g of sulfuric acid, 2 to 15 g of dye bleach catalyst and 0.5 to 20 g of nonionic wetting agent is used for the process stages (2) and (3) combined.

7. A process according to claim 1, wherein a processing liquid containing, per kg, 2 to 30 g of a water-soluble organic nitro compound, 100 to 350 g of hydrobromic acid, 1 to 5 g of dye bleach catalyst and 0.5 to 20 g of nonionic wetting agent is used for the process stages (2) and (3) combined.

8. A process according to claim 1, wherein a processing liquid containing a strong acid, a water-soluble organic oxidizing agent, a dye bleach catalyst, a water-soluble phosphine and, if appropriate, thiocyanate, bromide, iodide and/or thiourea is used for the process stages (2) and (3) and (4) combined.

9. A process according to claim 1, wherein the material is heated at 30°

to 70°

C. in the heat treatment for process stage (1).

10. A process according to claim 1, wherein the material is heated at 30°

to 60°

C. in the heat treatment for process stage (1).

11. A process according to claim 1, wherein the material is heated at 30°

to 120°

C. in the heat treatment for the process stages (2), (2) and (3) combined, (2) and (3) and (4) combined, and (4).

12. A process according to claim 11, wherein the material is heated at 50°

to 120°

C.

13. A process according to claim 12, wherein the material is heated at 60°

to 90°

C.

14. A process according to claim 1, wherein the heat treatment is effected by means of a hotplate or IR or microwave irradiation.

15. A process according to claim 1, wherein the appropriate processing liquid is sprayed onto the uppermost layer of the material by means of jets such as are used in ink-jet printing processes.

16. A process according to claim 1, wherein the silver dye bleach material is a copying material.