Method of manufacturing a molten metal-resistant ceramic fiber composition

• US 4,868,142 A
• Filed: 12/16/1987
• Issued: 09/19/1989
• Est. Priority Date: 12/16/1987
• Status: Expired due to Fees

• Current Assignee: Metaullics Systems Company LP (Pyrotek Incorporated)
• Original Assignee: Stemcor Corporation
• Inventors: Sane, Ajit Y., Waisala, Steven J.
• Primary Examiner(s): Dixon, Jr., William R.
• Assistant Examiner(s): Brunsman, David M.
• Application Number:
  US07/133,898
• Time in Patent Office: 643 Days
• Field of Search: 501/35, 501/95, 501/128, 264/60, 264/63, 264/66, 264/43
• US Class Current: 501/85
• CPC Class Codes: C03C 14/002 the non-glass component being in the form of fibres, filaments, yarns, felts or woven material
• CPC Class Codes: C03C 2214/02 Fibres; Filaments; Yarns; Felts; Woven material
• CPC Class Codes: C04B 14/22 Glass ; Devitrified glass
• CPC Class Codes: C04B 14/30 Oxides other than silica ferrites C04B14/363
• CPC Class Codes: C04B 14/32 Carbides; Nitrides; Borides ; Silicides
• CPC Class Codes: C04B 14/46 Rock wool ; Ceramic or silicate fibres C04B14/40, C04B14/42 take precedence
• CPC Class Codes: C04B 14/4656 Al-silicates, e.g. clay
• CPC Class Codes: C04B 2111/00129 Extrudable mixtures
• CPC Class Codes: C04B 2111/0087 for metallurgical applications
• CPC Class Codes: C04B 24/383 Cellulose or derivatives thereof
• CPC Class Codes: C04B 30/02 containing fibrous materials
• CPC Class Codes: C04B 35/6365 Cellulose or derivatives thereof
• CPC Class Codes: C04B 35/653 Processes involving a melting step
• CPC Class Codes: C04B 40/0028 Aspects relating to the mixing step of the mortar preparation
• CPC Class Codes: C04B 40/0263 Hardening promoted by a rise in temperature C04B40/024 takes precedence

Abstract

A method of manufacturing a molten metal-resisting ceramic fiber composition includes mixing ceramic fibers, a frit, ceramic additives, a low temperature binder, and water. The mixture is formed into a desired shape, preferably by being extruded through a die. The shaped mixture is baked at low temperature, and then is fired at high temperature. During firing, the low temperature binder is oxidized and the frit is melted so as to substantially coat the fibers and fuse them into a porous matrix.

Claims

1. A method for producing a molten metal-resistant ceramic fiber composition, comprising the steps of:

providing a frit of CaO, Al₂ O₃, and B₂ O₃ ;

providing a low temperature organic binder;

mixing the low temperature organic binder with the frit;

providing alumino-silicate ceramic fibers having an average mean diameter of about 1.2 microns;

mixing the binder-frit mixture with the fibers;

adding water to the binder-frit-fiber mixture;

forming the binder-frit-fiber mixture into a desired shape;

drying the binder-frit-fiber mixture; and

firing the binder-frit-fiber mixture to oxidize the binder and melt the frit.

2. The method of claim 1, wherein the low temperature organic binder is selected from the group consisting of hydroxypropyl methylcellulose and methylcellulose ether.

3. The method of claim 1, wherein the step of providing the frit includes the steps of:

mixing finely divided calcium carbonate, finely divided alumina, and finely divided boric acid;

heating the mixture to cause it to fuse and form a homogeneous, glassy product;

cooling the product; and

comminuting the product.

4. The method of claim 1, wherein the step of mixing the low temperature organic binder includes mixing the binder with water and stirring the mixture, and thereafter mixing the frit with the binder-water mixture until a gel forms.

5. The method of claim 1, wherein the step of mixing the low temperature organic binder includes mixing the binder and the frit while dry and thereafter adding water and stirring until a gel forms.

6. The method of claim 1, wherein the step of forming constitutes extruding.

7. The method of claim 1, wherein the step of drying includes heating at about 100°

-120°

C. for about 12 hours.

8. The method of claim 1, wherein the step of firing includes heating at about 1050°

C. for about 2 hours.

9. The method of claim 1, further including the step of mixing one or more ceramic additives with the binder-frit-fiber mixture prior to carrying out the step of forming the binder-frit-fiber mixture into a desired shape.

10. The method of claim 9, wherein the additives are selected from the group consisting of boehmite, alumina, colloidal, silica, silicon carbide, silicon nitride, aluminum nitride, spinel, zircon, zirconia, magnesia, calcium aluminate, alumina-coated silica, and titanium diboride.

11. The method of claim 1, wherein the ceramic fibers consist of approximately 50 percent alumina and 50 percent silica.

19. The method of claim 8, wherein the step of firing includes cooling from about 1050°

C. to about 25°

C. over a period of about six hours.

12. A method for producing a molten metal-resistant ceramic fiber composition, comprising the steps of:

providing a frit of CaO, Al₂ O₃, and B₂ O₃ ;

providing a low temperature organic binder selected from the group consisting of hydroxypropyl methylcellulose and methylcellulose ether;

mixing the low temperature organic binder with the frit;

providing alumino-silicate fibers having an average means diameter of about 1.2 microns;

mixing the binder-frit mixture with the aluminosilicate fibers;

adding water to the binder-frit-binder mixture;

extruding the binder-frit-fiber mixture into a desired shape;

drying the binder-frit-fiber mixture; and

firing the binder-frit-fiber mixture to oxidize the binder and melt the frit.

13. The method of claim 12, wherein the step of providing a frit includes the steps of:

mixing finely divided calcium carbonate, finely divided alumina, and finely divided boric acid;

heating the mixture to cause it to fuse and form a homogeneous, glassy product;

cooling the product; and

comminuting the product.

14. The method of claim 12, wherein the step of mixing the low temperature organic binder includes mixing the binder with water and stirring the mixture, and thereafter mixing the frit with the binder-water mixture until a gel forms.

15. The method of claim 12, wherein the step of mixing the low temperature organic binder includes mixing the binder and the frit while dry and thereafter adding water and stirring until a gel forms.

16. The method of claim 12, wherein the step of drying includes heating at about 100°

-120°

C. for about 12 hours, and the step of firing includes heating at about 1050°

C. for about 2 hours.

17. The method of claim 12, further including the step of mixing one or more ceramic additives with the binder-frit-fiber mixture prior to carrying out the step of forming the binder-frit-fiber mixture into a desired shape.

18. The method of claim 17, wherein the additives are selected from the group consisting of boehmite, alumina, colloidal silica, silicon carbide, silicon nitride, aluminum nitride, spinel, zircon, zirconia, magnesia, calcium aluminate, alumina-coated silica, and titanium diboride.

20. The method of claim 12, wherein the step of firing includes heating at about 1050°

C. for about two hours and cooling from about 1050°

C. to about 25°

C. over a period of about six hours.

21. A method for producing a molten metal-resistant ceramic fiber composition, compromising the steps of:

providing a frit of CaO, Al₂ O₃, and B₂ O₃ ;

providing a low temperature organic binder;

mixing the low temperature organic binder with the frit;

providing alumino-silicate ceramic fibers;

Adding water to the binder-frit-fiber mixture

mixing the binder-frit-fiber mixture;

forming the binder-frit-fiber mixture into a desired shape;

drying the binder-frit-fiber mixture;

firing the binder-frit-fiber mixture at about 1050°

C. for about 2 hours to oxidize the binder and melt the frit; and

cooling the binder-frit-fiber mixture from about 1050°

C. to about 25°

C. over a period of about 6 hours.

22. The method of claim 21, wherein the low temperature organic binder is selected from the group consisting of hydroxypropyl methylcellulose and methylcellulose ether.

23. The method of claim 21, wherein the step of providing the frit includes the steps of:

mixing finely divided calcium carbonate, finely divided alumina, and finely divided boric acid,

heating the mixture to cause it to fuse and form a homogeneous, glassy product;

cooling the product; and

comminuting the product.

24. The method of claim 21, wherein the step of mixing the low temperature organic binder includes mixing the binder with water and stirring the mixture, and thereafter mixing the frit with the binder-water mixture until a gel forms.

25. The method of claim 21, wherein the step of mixing the low temperature organic binder includes mixing the binder and the frit while dry and thereafter adding water and stirring until a gel forms.

26. The method of claim 21, wherein the step of forming constitutes extruding.

27. The method of claim 21, wherein the step of drying includes heating at about 100-120°

C. for about 12 hours.

28. The method of claim 21, further including the step of mixing one or more ceramic additives with the binder-frit-fiber mixture prior to carrying out the step of forming the binder-frit-fiber mixture into a desired shape.

29. The method of claim 28, wherein the additives are selected from the group consisting of boehmite, alumina, colloidal silica, silicon carbide, silicon nitride, aluminum nitride, spinel, zircon, zirconia, magnesia, calcium aluminate, alumina-coated silica, and titanium diboride.

30. The method of claim 21, wherein the ceramic fibers consist of approximately 50 percent alumina and 50 percent silica.

31. The method of claim 21, wherein the ceramic fibers have an average mean diameter within the range of about 1.0-3.0 microns.

32. The methgod of claim 31, wherein the ceramic fibers have an average mean diameter of about 1.2 microns.