Hydrocarbon gas processing
First Claim
1. In a process for the separation of a gas containing methane, C2 components and heavier hydrocarbon components into a volatile residue gas fraction containing a major portion of said methane and a relatively less volatile fraction containing a major portion of said C2 components and heavier components, in which process(a) said gas is cooled under pressure to provide a cooled stream;
- (b) said cooled stream is expanded to a lower pressure whereby it is further cooled; and
(c) said further cooled stream is fractionated at said lower pressure whereby the major portion of said C2 components and heavier hydrocarbon components is recovered in said relatively less volatile fraction;
the improvement wherein said gas is cooled sufficiently to partially condense it; and
(1) said partially condensed gas is separated thereby to provide a vapor stream and a condensed stream;
(2) said vapor stream is thereafter divided into gaseous first and second streams;
(3) said gaseous first stream is combined with at least a portion of said condensed stream to form a combined stream and said combined stream is cooled to condense substantially all of it and is thereafter expanded to a pressure below the fractionation pressure;
(4) the expanded cooled combined stream is then directed in heat exchange relation with a warmer distillation stream which rises from fractionation stages of a distillation column;
(5) the distillation stream is cooled by said combined stream sufficiently to partially condense it and said partially condensed distillation stream is separated thereby to provide said volatile residue gas and a reflux stream, said reflux stream is supplied to said distillation column at a top column feed position;
(6) the combined stream is separated thereby to provide a cold vapor stream and a liquid stream, the liquid stream is pumped to said column at a first mid-column feed position;
(7) the cold vapor stream is compressed and fed to the column at a second mid-column feed position;
(8) the gaseous second stream is expanded to said fractionation pressure and is supplied to said distillation column at a third mid-column feed position; and
(9) the temperatures of said feeds to the column are effective to maintain column overhead temperature at a temperature whereby the major portion of said C2 components and heavier hydrocarbon components is recovered in said relatively less volatile fraction.
5 Assignments
0 Petitions
Accused Products
Abstract
A process for the recovery of ethane and heavier hydrocarbon components from a hydrocarbon gas stream is disclosed. The stream is divided into first and second streams. The first stream is cooled to condense substantially all of it and is thereafter expanded to a pressure below that of the distillation column. After expansion, the cooled first stream is directed in heat exchange relation with a warmer distillation stream rising from fractionation stages of the distillation column. The warmed first stream is then separated to provide a cold vapor and a liquid stream. The liquid is supplied to the column at a first mid-column feed position and the cold vapor is supplied to the column at a second mid-column feed position. The second stream is expanded to the column pressure and is then supplied to the column at a third mid-column feed position. The distillation stream is cooled by the first stream sufficiently to partially condense it . The partially condensed distillation stream is then separated to provide volatile residue gas and a reflux stream feed. The reflux stream feed is supplied to the column at a top column feed position. In instances where the second stream is expanded in a work expansion machine, any condensation formed prior to work expansion is combined either in whole or in part with the first stream prior to cooling and/or expansion, or supplied either in whole or in part to the column as a condensed stream at a fourth mid-column feed position, or some combination thereof. The temperatures of the feeds to the column are effective to maintain the column overhead temperature at a temperature whereby the major portion of the C2 + components is recovered.
151 Citations
35 Claims
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1. In a process for the separation of a gas containing methane, C2 components and heavier hydrocarbon components into a volatile residue gas fraction containing a major portion of said methane and a relatively less volatile fraction containing a major portion of said C2 components and heavier components, in which process
(a) said gas is cooled under pressure to provide a cooled stream; -
(b) said cooled stream is expanded to a lower pressure whereby it is further cooled; and (c) said further cooled stream is fractionated at said lower pressure whereby the major portion of said C2 components and heavier hydrocarbon components is recovered in said relatively less volatile fraction; the improvement wherein said gas is cooled sufficiently to partially condense it; and (1) said partially condensed gas is separated thereby to provide a vapor stream and a condensed stream; (2) said vapor stream is thereafter divided into gaseous first and second streams; (3) said gaseous first stream is combined with at least a portion of said condensed stream to form a combined stream and said combined stream is cooled to condense substantially all of it and is thereafter expanded to a pressure below the fractionation pressure; (4) the expanded cooled combined stream is then directed in heat exchange relation with a warmer distillation stream which rises from fractionation stages of a distillation column; (5) the distillation stream is cooled by said combined stream sufficiently to partially condense it and said partially condensed distillation stream is separated thereby to provide said volatile residue gas and a reflux stream, said reflux stream is supplied to said distillation column at a top column feed position; (6) the combined stream is separated thereby to provide a cold vapor stream and a liquid stream, the liquid stream is pumped to said column at a first mid-column feed position; (7) the cold vapor stream is compressed and fed to the column at a second mid-column feed position; (8) the gaseous second stream is expanded to said fractionation pressure and is supplied to said distillation column at a third mid-column feed position; and (9) the temperatures of said feeds to the column are effective to maintain column overhead temperature at a temperature whereby the major portion of said C2 components and heavier hydrocarbon components is recovered in said relatively less volatile fraction. - View Dependent Claims (2, 3, 4, 17, 18, 19, 20, 21, 22, 24, 25, 26, 27)
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5. In a process for the separation of a gas containing methane, C2 components and heavier hydrocarbon components into a volatile residue gas fraction containing a major portion of said methane and a relatively less volatile fraction containing a major portion of said C2 components and heavier components, in which process
(a) said gas is cooled under pressure to provide a cooled stream; -
(b) said cooled stream is expanded to a lower pressure whereby it is further cooled; and (c) said further cooled stream is fractionated at said lower pressure whereby the major portion of said C2 components and heavier components is recovered in said relatively less volatile fraction; the improvement wherein prior to cooling, said gas is divided into gaseous first and second streams and (1) said gaseous first stream is cooled to condense substantially all of it and is thereafter expanded to a pressure below the fractionation pressure; (2) said gaseous second stream is cooled under pressure and is thereafter expanded to said lower pressure; (3) the expanded cooled first stream is directed in heat exchange relation with a warmer distillation stream which rises from fractionation stages of a distillation column; (4) the distillation stream is cooled by said first stream sufficiently to partially condense it and said partially condensed distillation stream is separated thereby to provide said volatile residue gas and a reflux stream, said reflux stream is supplied to said distillation column at a top column feed position; (5) the first stream is separated thereby to provide a cold vapor stream and a liquid stream, the liquid stream is pumped to said distillation column at a first mid-column feed position; (6) the cold vapor stream is compressed and fed to the column at a second mid-column feed position; (7) the expanded cooled second stream is supplied to said distillation column at a third mid-column feed position; and (8) the temperatures of said feeds to the column are effective to maintain column overhead temperature at a temperature whereby the major portion of said C2 components and heavier hydrocarbon components is recovered in said relatively less volatile fraction. - View Dependent Claims (6, 7, 8, 9, 10)
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11. In a process for the separation of a gas containing methane, C2 components and heavier hydrocarbon components into a volatile residue gas fraction containing a major portion of said methane and a relatively less volatile fraction containing a major portion of said C2 components and heavier components, in which process
(a) said gas is cooled under pressure to provide a cooled stream; -
(b) said cooled stream is expanded to a lower pressure whereby it is further cooled; and (c) said further cooled stream is fractionated at said lower pressure whereby the major portion of said C2 components and heavier hydrocarbon components is recovered in said relatively less volatile fraction; the improvement wherein following cooling, said cooled stream is divided into first and second streams and (1) said first stream is cooled to condense substantially all of it and is thereafter expanded to a pressure below the fractionation pressure; (2) said second stream is expanded to said lower pressure; (3) the expanded cooled first stream is directed in heat exchange relation with a warmer distillation stream which rises from fractionation stages of a distillation column; (4) the distillation stream is cooled by said first stream sufficiently to partially condense it and said partially condensed distillation stream is separated thereby to provide said volatile residue gas and a reflux stream, said reflux stream is supplied to said distillation column at a top column feed position; (5) the first stream is separated thereby to provide a cold vapor stream and a liquid stream, the liquid stream is pumped to said column at a first mid-column feed position; (6) the cold vapor stream is compressed and fed to the column at a second mid-column feed position; (7) the expanded second stream is supplied to said distillation column at a third mid-column feed position; and (8) the temperatures of said feeds to the column are effective to maintain column overhead temperature at a temperature whereby the major portion of said C2 components and heavier hydrocarbon components is recovered in said relatively less volatile fraction. - View Dependent Claims (12, 13, 14, 15, 16, 23, 29)
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28. In a process for the separation of a gas containing methane, C2 components and heavier hydrocarbon components into a volatile residue gas fraction containing a major portion of said methane and a relatively less volatile fraction containing a major portion of said C2 components and heavier components, in which process
(a) said gas is cooled under pressure to provide a cooled stream; -
(b) said cooled stream is expanded to a lower pressure whereby it is further cooled; and (c) said further cooled stream is fractionated at said lower pressure whereby the major portion of said C2 components and heavier hydrocarbon components is recovered in said relatively less volatile fraction; the improvement wherein said gas is cooled sufficiently to partially condense it; and (1) said partially condensed gas is separated thereby to provide a vapor stream and a condensed stream; (2) said vapor stream is thereafter divided into gaseous first and second streams; (3) said gaseous first stream is cooled to condense substantially all of it and is thereafter expanded to a pressure below the fractionation pressure; (4) the expanded cooled first stream is then directed in heat exchange relation with a warmer distillation stream which rises from fractionation stages of a distillation column; (5) the distillation stream is cooled by said first stream sufficiently to partially condense it and said partially condensed distillation stream is separated thereby to provide said volatile residue gas and a reflux stream, said reflux stream is supplied to said distillation column at a top column feed position; (6) the first stream is separated thereby to provide a cold vapor stream and a liquid stream, the liquid stream is pumped to said column at a first mid-column feed position; (7) the cold vapor stream is compressed and fed to the column at a second mid-column feed position; (8) the gaseous second stream is expanded to said fractionation pressure and is supplied to said distillation column at a third mid-column feed position; (9) said condensed stream is expanded to said fractionation pressure and is supplied to said distillation column at a fourth mid-column feed position; and (10) the temperatures of said feeds to the column are effective to maintain column overhead temperature at a temperature whereby the major portion of said C2 components and heavier hydrocarbon components is recovered in said relatively less volatile fraction.
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30. In an apparatus for the separation of a gas containing methane, C2 components and heavier hydrocarbons into a volatile residue gas fraction containing a major portion of said methane and a relatively less volatile fraction containing a major portion of said C2 components and heavier components, in said apparatus there being
(a) a first cooling means to cool said gas under pressure connected to provide a cooled stream under pressure; -
(b) a first expansion means connected to receive at least a portion of said cooled stream under pressure and to expand it to a lower pressure, whereby said stream is further cooled; and (c) a distillation column connected to said first expansion means to receive the further cooled stream therefrom; the improvement wherein said apparatus includes (1) first to cool said feed gas under pressure sufficiently to partially condense it; (2) first separation means connected to said first cooling means to receive said partially condensed feed and to separate it into a vapor and a condensed stream; (3) dividing means connected to said first separation means to receive said vapor and to divide said vapor into first and second streams; (4) combining means connected to combine said condensed stream and said first stream into a combined stream; (5) second cooling means connected to said combining means to receive said combined stream and to cool it sufficiently to substantially condense it; (6) second expansion means connected to said second cooling means to receive said substantially condensed combined stream and to expand it to a pressure below the fractionation pressure; (7) heat exchange means connected to said second expansion means to receive said expanded combined stream and to heat it, said heat exchange means being further connected to said distillation column at a point to receive a distillation stream rising from fractionation stages of the distillation column and to cool and partially condense said distillation stream;
said heat exchange means being further connected to second and third separation means;(8) said second separation means being connected to said heat exchange means to receive said combined stream and to separate it into a cold vapor stream and a liquid stream, said second separation means being further connected to (a) pumping means and (b) compressing means; (9) said pumping means being further connected to said distillation column at a first mid-column feed position to supply said liquid stream to said distillation column; (10) said compressing means being further connected to said distillation column at a second mid-column feed position to supply said cold vapor stream to said distillation column; (11) said third separation means being connected to said heat exchange means to receive said partially condensed distillation stream and to separate it into said volatile residue gas fraction and a reflux stream, said third separation means being further connected to said distillation column to supply said reflux stream to the distillation column at a top column feed position; (12) first expansion means being connected to said dividing means to receive said second stream and expand it to said lower pressure, said first expansion means being further connected to said distillation column to supply said expanded stream to said column at a third mid-column feed position; and (13) control means adapted to regulate the temperatures of said combined stream, said second stream and said reflux stream to maintain column overhead temperature at a temperature whereby the major portion of said C2 components and heavier components is recovered in said relatively less volatile fraction. - View Dependent Claims (33, 34, 35)
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31. In an apparatus for the separation of a feed gas containing methane, C2 components and heavier hydrocarbon components into a volatile residue gas fraction containing a major portion of said methane and a relatively less volatile fraction containing a major portion of said C2 components and heavier components;
- in said apparatus there being
(a) a first cooling means to cool said gas under pressure connected to provide a cooled stream under pressure; (b) a first expansion means connected to receive at least a portion of said cooled stream under pressure and to expand it to a lower pressure, whereby said stream is further cooled; and (c) a distillation column connected to said expansion means to receive the further cooled stream therefrom; the improvement wherein said apparatus includes (1) dividing means prior to said first cooling means to divide said feed gas into a first gaseous stream and a second gaseous stream; (2) second cooling means connected to said dividing means to receive said first stream and to cool it sufficiently to substantially condense it; (3) second expansion means connected to said second cooling means to receive the substantially condensed first stream therefrom and to expand it to a pressure below the fractionation pressure; (4) heat exchange means connected to said second expansion means to receive said expanded first stream and to heat it, said heat exchange means being further connected to said distillation column at a point to receive a distillation stream rising from fractionation stages of the distillation column wherein said heat exchange means cools and partially condenses said distillation stream;
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said heat exchange means being further connected to first and second separation means;(5) said first separation means being connected to said heat exchange means to receive said first stream and to separate it into a cold vapor stream and a liquid stream, said first separation means being further connected to (a) pumping means and (b) compressing means; (6) said pumping means being further connected to said distillation column at a first mid-column feed position to supply said liquid stream to said distillation column; (7) said compressing means being further connected to said distillation column at a second mid-column feed position to supply said cold vapor stream to said distillation column; (8) said second separation means being connected to said heat exchange means to receive said partially condensed distillation stream and to separate it into said volatile residue gas fraction and a reflux stream, said second separation means being further connected to said distillation column to supply said reflux stream to the distillation column at a top column feed position; (9) said first cooling means being connected to said dividing means to receive said second stream and to cool it; (10) said first expansion means being connected to said first cooling means to receive said cooled second stream and to expand and further cool it;
said first expansion means being further connected to said distillation column to supply said second stream to the column at a third mid-column feed position; and(11) control means adapted to regulate the temperatures of said first stream, said second stream and said reflux stream to maintain column overhead temperature at a temperature whereby the major portion of said C2 components and heavier components is recovered in said relatively less volatile fraction.
- in said apparatus there being
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32. In an apparatus for the separation of a gas containing methane, C2 components and heavier hydrocarbon components into a volatile residue gas fraction containing a major portion of said methane and a relatively less volatile fraction containing a major portion of said C2 components and heavier components;
- in said apparatus there being
(a) a first cooling means to cool said gas under pressure connected to provide a cooled stream under pressure; (b) a first expansion means connected to receive at least a portion of said cooled stream under pressure and to expand it to a lower pressure, whereby said stream is further cooled; and (c) a distillation column connected to said expansion means to receive the further cooled stream therefrom; the improvement wherein said apparatus includes (1) dividing means after said first cooling means to divide said cooled stream into a first stream and a second stream; (2) second cooling means connected to said dividing means to receive said first stream and to cool it sufficiently to substantially condense it; (3) second expansion means connected to said second cooling means to receive the substantially condensed first stream therefrom and to expand it to a pressure below the fractionation pressure; (4) heat exchange means connected to said second expansion means to receive said expanded first stream and to heat it, said heat exchange means being further connected to said distillation column at a point to receive a distillation stream rising from fractionation stages of the distillation column wherein said heat exchange means cools and partially condenses said distillation stream;
said heat exchange means being further connected to first and second separation means;(5) said first separation means being connected to said heat exchange means to receive said first stream and to separate it into a cold vapor stream and a liquid stream, said first separation means being further connected to (a) pumping means and (b) compressing means; (6) said pumping means being further connected to said distillation column at a first mid-column feed position to supply said liquid stream to said distillation column; (7) said compressing means being further connected to said distillation column at a second mid-column feed position to supply said cold vapor stream to said distillation column; (8) said second separation means being connected to said heat exchange means to receive said partially condensed distillation stream and to separate it into said volatile residue gas fraction and a reflux stream, said second separation means being further connected to said distillation column to supply said reflux stream to the distillation column at a top column feed position; (9) said first expansion means being connected to said dividing means to receive said second stream and to expand and cool it;
said first expansion means being further connected to said distillation column to supply said second stream to the column at a third mid-column feed position; and(10) control means adapted to regulate the temperatures of said first stream, said second stream and said reflux stream to maintain column overhead temperature at a temperature whereby the major portion of said C2 components and heavier components is recovered in said relatively less volatile fraction.
- in said apparatus there being
Specification