Process for preparing polymeric beads

• US 4,870,145 A
• Filed: 09/02/1987
• Issued: 09/26/1989
• Est. Priority Date: 02/21/1985
• Status: Expired due to Fees

• Current Assignee: Bausch & Lomb Incorporated (Bausch Health Cos., Inc.)
• Original Assignee: Bausch & Lomb Incorporated (Bausch Health Cos., Inc.)
• Inventors: Chromecek, Richard C.
• Primary Examiner(s): Ivy, C. Warren
• Assistant Examiner(s): Walker, Alex H.
• Application Number:
  US07/093,058
• Time in Patent Office: 755 Days
• Field of Search: 526/217, 526/89, 526/264, 526/270, 526/317.1, 526/310, 526/303.1
• US Class Current: 526/217
• CPC Class Codes: C08F 2/06 Organic solvent

Abstract

A process for preparing hydrophilic polymeric beads by suspension polymerization of one or more hydrophilic monomers and a cross-linking monomer in the presence of a free radical initiator and a regenerator amine at a temperature between 15° and 35° C. The beads are useful as abrasives in various cleaning compositions.

Claims

1. The process for preparing hydrophilic polymeric beads by polymerization in an organic liquid medium of one or more hydrophilic monomers and at least one cross linking monomer in the presence of a free radical initiator and a regenerator amine, said amine being selected from the group consisting of secondary amines and tertiary amines wherein the monomers are initially dissolved in the liquid medium and wherein the the copolymer is insoluble in the liquid medium, the polymerization being maintained at a temperature from 15°

to 35°

C. for a period of one half to 48 hours whereby cross linked polymeric beads having an average diameter from 0.1 to 10 microns are precipitated from said solvent.

2. The process of claim 1 wherein the free radical initiator has a 10 hour half life temperature of 75°

C. or less.

3. The process of claim 2 wherein the free radical initiator is present in an amount from 1 to 2.5 weight percent of the total monomer charge.

4. The process of claim 3, wherein the regenerator amine is present in an amount from 0.1 to 5.0 weight percent of the total monomer charge.

5. The process of claim 4 wherein the regenerator amine is a secondary amine.

6. The process of claim 4 wherein the regenerator amine is a tertiary amine.

7. The process of claim 6 wherein the solvent medium is present in an amount of 3 to 5 times the weight of the monomer charged.

8. The process of claim 7 wherein a modulus modifier monomer is added.

9. The process of claim 7 wherein one of the hydrophilic monomers present is an N-vinyl lactam.

10. The process of claim 7 wherein the reaction is carried out at a temperature from about 20°

to 30°

C.

11. The process of claim 7 wherein the solvent medium is selected from the group consisting of aromatic hydrocarbons, liquid alkanes and petroleum ethers.

12. The process of claim 11 wherein the solvent medium is an aromatic hydrocarbon.