Electroluminescent panel having a layer of germanium nitride between an electroluminescent layer and a back electrode

• US 4,870,322 A
• Filed: 04/15/1986
• Issued: 09/26/1989
• Est. Priority Date: 04/15/1986
• Status: Expired due to Fees

• Current Assignee: Hoya Corporation
• Original Assignee: Hoya Corporation
• Inventors: Shimizu, Yasumoto, Matsudaira, Takeo
• Primary Examiner(s): Moore, David K.
• Assistant Examiner(s): O SHEA, SANDRA L
• Application Number:
  US06/852,296
• Time in Patent Office: 1,260 Days
• Field of Search: 313/506, 313/509, 313/505, 357/2
• US Class Current: 313/506
• CPC Class Codes: G09F 9/33 being semiconductor devices, e.g. diodes
• CPC Class Codes: H05B 33/22 characterised by the chemical or physical composition or the arrangement of auxiliary dielectric or reflective layers

Abstract

In an electroluminescent panel comprising a transparent electrode, a back electrode, and an electroluminescent layer between the transparent and the back electrodes, an intermediate layer is interposed between the electroluminescent layer and the back electrode and essentially consists of germanium and nitrogen. The intermediate layer serves as a light absorption layer for absorbing ambient light. A nitrogen distribution in the intermediate layer may be either substantially uniform or decreased from the electroluminescent layer side towards the back electrode side. The decrease may be made stepwise or continuously. The intermediate layer may be superposed through a dielectric layer or directly on the electroluminescent layer. Only oxygen may be added in intermediate layer to the germanium and the nitrogen, to provide either a substantially uniform oxygen distribution or a variable oxygen distribution which is continuously or stepwise decreased from the electroluminescent layer side towards the back electrode side.

Claims

1. An electroluminescent panel comprising a transparent electrode, a back electrode opposite said transparent electrode, and an electroluminescent layer for emitting electroluminescent light between said transparent and said back electrodes, said electroluminescent panel further comprising:

an intermediate layer between said electroluminescent layer and said back electrode, said intermediate layer consisting of germanium and nitrogen to form germanium nitride whereby said intermediate layer provides the electroluminescent panel with a high rate of brightness increase for an applied voltage.

2. An electroluminescent panel as claimed in claim 1, wherein said intermediate layer has a substantially uniform nitrogen distribution therein.

3. An electroluminescent panel as claimed in claim 1, said intermediate layer having a first surface directed towards said electroluminescent layer and a second surface directed towards said back electrode, wherein said intermediate layer has a nitrogen distribution which decreases from said first surface towards said second surface.

4. An electroluminescent panel as claimed in claim 3, wherein said nitrogen distribution is continuously decreased from said first surface to said second surface.

5. An electroluminescent panel as claimed in claim 3, wherein said nitrogen distribution is stepwise decreased from said first surface to said second surface.

6. An electroluminescent panel as claimed in claim 1, further comprising a dielectric layer between said electroluminescent and said intermediate layers, said dielectric layer being in contact with said electroluminescent and said intermediate layers.

7. An electroluminescent panel as claimed in claim 6, wherein said intermediate layer is in contact with said back electrode.

8. An electroluminescent panel as claimed in claim 1, further comprising a first dielectric layer between said electroluminescent and said intermediate layers and a second dielectric layer between said intermediate layer and said back electrode, said first dielectric layer being in contact with said electroluminescent and said intermediate layers, said second dielectric layer being in contact with said intermediate layer and said back electrode.

9. An electroluminescent panel as claimed in claim 1, said intermediate layer having a first surface directed towards said electroluminescent layer and a second surface directed towards said back electrode, wherein said first surface is in contact with said electroluminescent layer.

10. An electroluminescent panel as claimed in claim 9, further comprising a dielectric layer between said intermediate layer and said back electrode, said dielectric layer being in contact with said second surface.

11. An electroluminescent panel as claimed in claim 10, wherein said intermediate layer has a substantially uniform nitrogen distribution of said nitrogen.

12. An electroluminescent panel as claimed in claim 10, wherein said intermediate layer has a nitrogen distribution which decreases from said first surface towards said second surface.

13. An electroluminescent panel as claimed in claim 12, wherein said nitrogen distribution is continuously decreased from said first surface to said second surface.

14. An electroluminescent panel as claimed in claim 12, wherein said nitrogen distribution is stepwise decreased from said first surface to said second surface.

15. An electroluminescent panel as claimed in claim 9, wherein said intermediate layer has a first and a second film which provide said first and said second surfaces, respectively.

16. An electroluminescent panel as claimed in claim 15, further comprising a dielectric layer between said first and said second films, said dielectric layer being in contact with said first and said second films.

17. An electroluminescent panel as claimed in claim 16, wherein said first and said second films have a first and a second nitrogen distribution of said nitrogen, respectively, each of said first and said second nitrogen distributions being substantially uniform.

18. An electroluminescent panel as claimed in claim 17, wherein said first and said second films have a first and a second ratio of said nitrogen to said germanium, respectively, said second ratio being less than said first ratio.

19. An electroluminescent panel as claimed in claim 16, wherein said first film has a first nitrogen distribution of said nitrogen decreased from said first surface towards said second surface, said second film having a second nitrogen distribution of said nitrogen increased from said second surface towards said first surface.

20. An electroluminescent panel as claimed in claim 19, wherein said first nitrogen distribution is continuously decreased from said first surface towards said second surface, said second nitrogen distribution being continuously increased from said second surface towards said first surface.

21. An electroluminescent panel as claimed in claim 19, wherein said first nitrogen distribution is continuously decreased from said first surface towards said second surface, said second nitrogen distribution being stepwise increased from said second surface towards said first surface.

22. An electroluminescent panel as claimed in claim 19, wherein said first nitrogen distribution is stepwise decreased from said first surface towards said second surface, said second nitrogen distribution being continuously increased from said second surface towards said first surface.

23. An electroluminescent panel as claimed in claim 19, wherein said first nitrogen distribution is stepwise decreased from said first surface towards said second surface, said second nitrogen distribution being stepwise increased from said second surface towards said first surface.

24. An electroluminescent panel comprising a transparent electrode, a back electrode opposite said transparent electrode, and an electroluminescent layer for emitting electroluminescent light between said transparent and said back electrodes, said electroluminescent panel further comprising:

an intermediate layer between said electroluminescent layer and said back electrode, said intermediate layer consisting of germanium, nitrogen, and oxygen to form germanium oxynitride whereby said intermediate layer provides the electroluminescent panel with a high rate of brightness increase for an applied voltage.

25. An electroluminescent panel as claimed in claim 24, wherein said intermediate layer has a substantially uniform nitrogen distribution of said nitrogen.

26. An electroluminescent panel as claimed in claim 24, said intermediate layer having a first surface directed towards said electroluminescent layer and a second surface directed towards said back electrode, wherein said intermediate layer has a nitrogen distribution of said nitrogen decreased from said first surface towards said second surface.

27. An electroluminescent panel as claimed in claim 26, wherein said nitrogen distribution is continuously decreased from said first surface to said second surface.

28. An electroluminescent panel as claimed in claim 26, wherein said nitrogen distribution is stepwise decreased from said first surface to said second surface.

29. An electroluminescent panel as claimed in claim 24, wherein said intermediate layer has a substantially uniform oxygen distribution of said oxygen.

30. An electroluminescent panel as claimed in claim 29, wherein said intermediate layer has a substantially uniform nitrogen distribution of said nitrogen.

31. An electroluminescent panel as claimed in claim 29, said intermediate layer having a first surface directed towards said electroluminescent layer and a second surface directed towards said back electrode, wherein said intermediate layer has a nitrogen distribution of said nitrogen decreased from said first surface towards said second surface.

32. An electroluminescent panel as claimed in claim 31, wherein said nitrogen distribution is continuously decreased from said first surface to said second surface.

33. An electroluminescent panel as claimed in claim 31, wherein said nitrogen distribution is stepwise decreased from said first surface to said second surface.

34. An electroluminescent panel as claimed in claim 24, said intermediate layer having a first surface directed towards said electroluminescent layer and a second surface directed towards said back electrode, wherein said intermediate layer has an oxygen distribution of said oxygen decreased from said first surface towards said second surface.

35. An electroluminescent panel as claimed in claim 34, wherein said intermediate layer has a substantially uniform nitrogen distribution of said nitrogen.

36. An electroluminescent panel as claimed in claim 34, wherein said intermediate layer has a nitrogen distribution of said nitrogen decreased from said first surface towards said second surface.

37. An electroluminescent panel as claimed in claim 36, wherein said nitrogen distribution is continuously decreased from said first surface to said second surface.

38. An electroluminescent panel as claimed in claim 36, wherein said nitrogen distribution is stepwise decreased from said first surface to said second surface.

39. An electroluminescent panel as claimed in claim 34, wherein said oxygen distribution is continuously decreased from said first surface to said second surface.

40. An electroluminescent panel as claimed in claim 39, wherein said intermediate layer has a substantially uniform nitrogen distribution of said nitrogen.

41. An electroluminescent panel as claimed in claim 39, wherein said intermediate layer has a nitrogen distribution of said nitrogen decreased from said first surface towards said second surface.

42. An electroluminescent panel as claimed in claim 41, wherein said nitrogen distribution is continuously decreased from said first surface to said second surface.

43. An electroluminescent panel as claimed in claim 41, wherein said nitrogen distribution is stepwise decreased from said first surface to said second surface.

44. An electroluminescent panel as claimed in claim 34, wherein said oxygen distribution is stepwise decreased from said first surface to said second surface.

45. An electroluminescent panel as claimed in claim 44, wherein said intermediate layer has a substantially uniform nitrogen distribution of said nitrogen.

46. An electroluminescent panel as claimed in claim 44, wherein said intermediate layer has a nitrogen distribution of said nitrogen decreased from said first surface towards said second surface.

47. An electroluminescent panel as claimed in claim 46, wherein said nitrogen distribution is continuously decreased from said first surface to said second surface.

48. An electroluminescent panel as claimed in claim 46, wherein said nitrogen distribution is stepwise decreased from said first surface to said second surface.

49. An electroluminescent panel as claimed in claim 24, further comprising a dielectric layer between said electroluminescent and said intermediate layers, said dielectric layer being in contact with said electroluminescent and said intermediate layers.

50. An electroluminescent panel as claimed in claim 49, wherein said intermediate layer is in contact with said back electrode.

51. An electroluminescent panel as claimed in claim 24, further comprising a first dielectric layer between said electroluminescent and said intermediate layers and a second dielectric layer between said intermediate layer and said back electrode, said first dielectric layer being in contact with said electroluminescent and said intermediate layers, said second dielectric layer being in contact with said intermediate layer and said back electrode.