Thermally-transferable fluorescent diphenyl ethylenes

• US 4,871,714 A
• Filed: 08/31/1988
• Issued: 10/03/1989
• Est. Priority Date: 08/31/1988
• Status: Expired due to Fees

• Current Assignee: Eastman Kodak Company
• Original Assignee: Eastman Kodak Company
• Inventors: Byers, Gary W., Chapman, Derek D.
• Primary Examiner(s): Hess, Bruce H.
• Application Number:
  US07/238,652
• Time in Patent Office: 398 Days
• Field of Search: 8/471, 428/195, 428/480, 428/913, 428/914, 503/227
• US Class Current: 503/227
• CPC Class Codes: B41M 5/3854 Dyes containing one or more acyclic carbon-to-carbon double bonds, e.g., di- or tri-cyanovinyl, methine
• CPC Class Codes: Y10S 428/913 Material designed to be responsive to temperature, light, moisture
• CPC Class Codes: Y10S 428/914 Transfer or decalcomania
• CPC Class Codes: Y10T 428/31786 Of polyester [e.g., alkyd, etc.]

Abstract

A donor element for thermal transfer comprising a support having on one side thereof a fluorescent material dispersed in a polymeric binder, and on the other side thereof a slipping layer comprising a lubricant, the fluorescent material comprising a diphenyl ethylene having the formula: ##STR1## wherein: n is 1 to 6, with the proviso that when n is 1, at least one of the phenyl rings must be substituted with a conjugated moiety.

Claims

1. A donor element for thermal transfer comprising a support having on one side thereof a fluorescent material dispersed in a polymeric binder, and on the other side thereof a slipping layer comprising a lubricant, said fluorescent material comprising a diphenyl ethylene having the formula:

##STR33## wherein;

n is 1 to 6, with the proviso that when n is 1, at least one of the phenyl rings must be substituted with a conjugated moiety.

2. The element of claim 1 wherein n is 3 and the phenyl rings are unsubstituted.

3. The element of claim 1 wherein n is 1 and at least one phenyl ring is substituted with a vinylbenzene group.

4. The element of claim 1 wherein n is 1 and at least one phenyl ring is substituted with a naphthotriazole group.

5. The element of claim 1 wherein n is 1 and at least one phenyl ring is substituted with a diphenylamine group.

6. The element of claim 1 wherein n is 1 and at least one phenyl ring is substituted with a benzoxazole group.

7. The element of claim 1 wherein n is 1 and at least one phenyl ring is substituted with a benzothiazole group.

8. The element of claim 1 wherein said donor element comprises sequential repeating areas of magenta, yellow and cyan dye, and said fluorescent diphenyl ethylene.

9. A process of forming a transfer image comprising imagewise-heating a donor element comprising a support having on one side thereof a fluorescent material dispersed in a polymeric binder, and on the other side thereof a slipping layer comprising a lubricant, and transferring an image to a receiving element, said fluorescent material comprising a diphenyl ethylene having the formula:

##STR34## wherein;

n is 1 to 6, with the proviso that when n is 1, at least one of the phenyl rings must be substituted with a conjugated moiety.

10. The process of claim 9 wherein n is 3 and the phenyl rings are unsubstituted.

11. The process of claim 9 wherein n is 1 and at least one phenyl ring is substituted with a vinylbenzene group, a naphthotriazole group, a diphenylamine group, a benzoxazole group, or a benzothiazole group.

12. The process of claim 9 wherein said support is poly(ethylene terephthalate) which is coated with sequential repeating areas of magenta, yellow and cyan dye, and said fluorescent diphenyl ethylene, and said process steps are sequentially performed for each color to obtain a visible three-color dye transfer image and a fluorescent image.

13. A thermal transfer assemblage comprising:

(a) a donor element comprising a support having on one side thereof a layer comprising a fluorescent material dispersed in a polymeric binder, and on the other side thereof a slipping layer comprising a lubricant, and

(b) a receiving element comprising a support having thereon an image-receiving layer,

said receiving element being in a superposed relationship with said donor element so that said fluorescent material layer is in contact with said image-receiving layer, said fluorescent material comprising a diphenyl ethylene having the formula;

##STR35## wherein;

n is 1 to 6, with the proviso that when n is 1, at least one of the phenyl rings must be substituted with a conjugated moiety.

14. The assemblage of claim 13 wherein n is 3 and at the phenyl rings are unsubstituted.

15. The assemblage of claim 13 wherein n is 1 and at least one phenyl ring is substituted with a vinylbenzene group, a naphthotriazole group, a diphenylamine group, a benzoxazole group, or a benzothiazole group.

16. The assemblage of claim 13 wherein said support of said donor element is poly(ethylene terephthalate) which is coated with sequential repeating areas of magenta, yellow and cyan dye, and said fluorescent diphenyl ethylene.