Process for the preparation of aqueous polyurethane-polyurea dispersions

• US 4,871,798 A
• Filed: 10/14/1988
• Issued: 10/03/1989
• Est. Priority Date: 10/21/1987
• Status: Expired due to Fees

• Current Assignee: Bayer AG, Mobay Corporation Pittsburgh United States of America
• Original Assignee: Bayer AG
• Inventors: Henning, Wolfgang, Dormish, Jeffrey
• Primary Examiner(s): WELSH JR, MAURICE
• Application Number:
  US07/258,230
• Time in Patent Office: 354 Days
• Field of Search: 524/591, 524/839, 524/840
• US Class Current: 524/591
• CPC Class Codes: C08G 18/0828 containing sulfonate groups or groups forming them
• CPC Class Codes: C08G 18/2805 Compounds having only one group containing active hydrogen vinylpolymers having terminal groups containing active hydrogen C08G18/62
• CPC Class Codes: C08G 18/283 Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
• CPC Class Codes: C08G 18/5042 containing ureum groups
• CPC Class Codes: C08G 18/7818 containing ureum or ureum derivative groups

Abstract

The present invention is directed to a process for the preparation of stable polyurethane-polyurea dispersions in a multi-stage process by forming an isocyanate-terminated prepolymer having an ionic group content of up to about 50 milliequivalents per 100 g of prepolymer by reacting an organic polyisocyanate (a) with at least two isocyanate-reactive components (b1) and (b2) wherein component (b1) has at least one ionic or potential ionic hydrophilic group, characterized in that

(1) the isocyanate (a) is initially reacted with component (b1), and

(2) the resulting product is then reacted with component (b2) and optionally with a component (b3) containing ethylene oxide units to form a prepolymer, and

(3) the resulting prepolymer is dispersed in water.

The present invention further release to products obtained according to this process and to their use for the preparation of coatings on flexible or rigid substrates and in particular to their use as ahdesives.

Claims

1. A process for the preparation of a stable polyurethane-polyurea dispersion in a multi-stage process which comprises forming an isocyanate-terminated prepolymer having an ionic group content of up to about 50 milliequivalents per 100 g of solids by

(1) reacting an organic polyisocyanate (a) with a compound (b1) having at least two isocyanate-reactive groups and at least one ionic or potential ionic hydrophilic group

(2) reacting the resulting product with a compound (b2) which contains at least two isocyanate-reactive groups and has a molecular weight of 300 to about 6000 and does not contain at least one ionic or potential ionic hydrophilic group and optionally a compound (b3) containing at least one isocyanate-reactive group and hydrophilic ethylene oxide units in a terminal and/or lateral position to form a prepolymer and

(3) dispersing said prepolymer in water.

2. The process of claim 1, wherein the prepolymer is a straight chain prepolymer having a molecular weight of up to about 25,000.

3. The process of claim 1 which comprises reacting said prepolymer with a chain lengthening agent having a molecular weight below 300 during or after dispersing the prepolymer in water.

4. The process of claim 1 wherein component (b2) has a molecular weight of about 1500 to 5000.

5. The process of claim 1 characterized in that compound (b1) is a difunctional compound containing SO.sup.⊖

₃ group.

6. The process of claim 1 wherein component (b1) is difunctional.

7. The process of claim 1 wherein organic polyisocyanate (a) comprises a member selected from the group consisting of isophorone diisocyanate, dicylohexylmethane-4,4'"'"'-diisocyanate, toluene diisocyanate, diphenylmethane-4,4'"'"'-diisocyanate and hexamethylene diisocyanate, compound (b1) comprises a propoxylated adduct of 2-butene diol-(1,4) and NaHSO₃ and compound (b2) comprises a member selected from the group consisting of an adipic acid/butane diol-(1,4) polyesters, adipic acid/hexane diol-(1,6) polyesters and adipic acid/hexane diol-(1,6)/neopentyl glycol polyesters.

8. The process of claim 1 wherein component b1) comprises a diol containing a sulphonic acid group which has been converted into an ionic group by neutralization before prepolymer formation.

9. A stable polyurethane-polyurea dispersion which is prepared in a multi-stage process which comprises forming an isocyanate-terminated prepolymer having an ionic group content of up to about 50 milliequivalents per 100 g of solids by

(1) reacting an organic polyisocyanate (a) with a compound (b1) having at least two isocyanate-reactive groups and at least one ionic or potential ionic hydrophilic group

(2) reacting the resulting product with a compound (b2) which contains at least two isocyanate-reactive groups and has a molecular weight of 300 to about 6000 and does not contain at least one ionic or potential ionic hydrophilic group and optionally a compound (b3) containing at least one isocyanate-reactive group and hydrophilic ethylene oxide units in a terminal and/or lateral position to form a prepolymer and

(3) dispersing said prepolymer in water.

10. The dispersion of claim 9, wherein the prepolymer is a straight chain prepolymer having a molecular weight of up to about 25,000.

11. The dispersion of claim 9 which comprises reacting said prepolymer with a chain lengthening agent having a molecular weight below 300 during or after dispersing the prepolymer in water.

12. The dispersion of claim 9 wherein component b2) has a molecular weight of about 1500 to 5000.

13. The dispersion of claim 9 characterized in that compound (b1) is a difunctional compound containing SO.sup.⊖

₃ group.

14. The dispersion of claim 9 wherein component (b1) is difunctional.

15. The dispersion of claim 9 wherein organic polyisocyanate (a) comprises a member selected from the group consisting of isophorone diisocyanate, dicylohexylmethane-4,4'"'"'-diisocyanate, toluene diisocyanate, diphenylmethane-4,4'"'"'-diisocyanate and hexamethylene diisocyanate, compound (b1) comprises a propoxylated adduct of 2-butene diol-(1,4) and NaHSO₃ and compound (b2) comprises a member selected from the group consisting of adipic acid/butane diol-(1,4) polyesters, adipic acid/hexane diol-(1,6) polyesters and adipic acid/hexane diol-(1,6)/neopentyl glycol polyesters.

16. The dispersion of claim 9 wherein component (b1) comprises a diol containing a sulphonic acid group which has been converted into an ionic group by neutralization before prepolymer formation.

17. A process for the production of a coating or an adhesive which comprises coating at least one substrate with the dispersion of claim 9 and subsequently curing said coated substrate.