Thermoplastic polymer composition

• US 4,871,799 A
• Filed: 09/14/1988
• Issued: 10/03/1989
• Est. Priority Date: 10/28/1985
• Status: Expired due to Fees

• Current Assignee: Toyoda Gosei Company Limited (Toyota Motor Corporation)
• Original Assignee: Toyoda Gosei Company Limited (Toyota Motor Corporation)
• Inventors: Nishida, Takashi, Kobayashi, Shigeo
• Primary Examiner(s): Lieberman, Allan M.
• Assistant Examiner(s): Carrillo, A.
• Application Number:
  US07/246,016
• Time in Patent Office: 384 Days
• Field of Search: 525/64, 525/66, 525/92
• US Class Current: 525/64
• CPC Class Codes: C08F 287/00 Macromolecular compounds obtained by polymerising monomers on to block polymers
• CPC Class Codes: C08L 23/22 Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefins
• CPC Class Codes: C08L 2666/20 Macromolecular compounds having nitrogen in the main chain according to C08L75/00 - C08L79/00; Derivatives thereof
• CPC Class Codes: C08L 2666/24 Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
• CPC Class Codes: C08L 53/02 of vinyl-aromatic monomers and conjugated dienes
• CPC Class Codes: C08L 77/00 Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain of polyhydrazides C08L79/06; of polyamideimides or polyamide acids C08L79/08; Compositions of derivatives of such polymers

Abstract

A thermoplastic polymer composition containing (a) a polyester or polyamide thermoplastic polymer and (b) a block graft copolymer which comprises (i) as the backbone portion at least one of a block copolymer or a hydrogenated block copolymer containing blocks of a styrene-type polymer and blocks of a butadiene-type polymer, and (ii) as the graft portion a radical disintegrative polymer, said block graft copolymer having been chemically modified with molecular units containing a functional group which will combine or interact with said thermoplastic polymer a). The thermoplastic polymer composition is superior in flexibility, resistance to chemicals and oil, impact resistance, moldability and elasticity.

Claims

1. A thermoplastic polymer composition which comprises:

(a) a polyester or polyamide thermoplastic polymer; and

(b) a block graft copolymer which comprises (i) as the backbone portion at least one of a block copolymer or a hydrogenated block copolymer consisting of blocks of a vinyl-substituted aromatic compound polymer in a weight range of 5 to 60 weight percent and blocks of a conjugated diene compound polymer in a range of 95 to 40 weight percent, and (ii) as the graft portion, a polymer which in the presence of radicals disintegrates into smaller molecules by the cleavage of molecular chains in preference to rebonding and crosslinking of broken molecules, said block graft copolymer having been chemically modified with molecular units containing a functional group which combines with or interact with said thermoplastic polymer (a), the block copolymer and the radical disintegrative polymer being in a ratio of 20;

1 to 1;

2 by weight.

2. The thermoplastic polymer composition as claimed in claim 1, wherein the thermoplastic polymer (a) is a polyamide.

3. The thermoplastic polymer composition as claimed in claim 1, wherein the molecular unit containing a functional group is maleic anhydride.

4. The thermoplastic polymer composition as claimed in claim 1, wherein the vinyl-substituted aromatic compound polymer is in a range of 10 to 30 weight percent and the conjugated diene compound is in a range of 90 to 70 weight percent.

5. The thermoplastic polymer composition as claimed in claim 1, wherein the thermoplastic polymer composition has a melting point of 150°

-300°

C.

6. The thermoplastic polymer composition as claimed in claim 5, wherein the thermoplastic polymer is a polyamide and has a relative viscosity of not less than 1.8 as measured in 98% sulfuric acid at 30°

C.

7. The thermoplastic polymer composition as claimed in claim 1, wherein the radical disintegrative polymer is a member selected from the group consisting of:

polyisobutylene, polypropylene, poly-α

-methylstyrene, polymethacrylate, polymethacrylamide, polyvinylidene chloride, cellulose, cellulose derivatives, polytetrafluoroethylene, polytrifluorochloroethylene, butyl rubber and ethylene/propylene copolymers.

8. The thermoplastic polymer composition as claimed in claim 7, wherein the radical disintegrative polymer (ii) is a butyl rubber.