Sheet type electrode for use in the measurement of ion concentrations

• US 4,872,966 A
• Filed: 11/24/1987
• Issued: 10/10/1989
• Est. Priority Date: 12/11/1986
• Status: Expired due to Fees

• Current Assignee: Horiba Limited
• Original Assignee: Horiba Limited
• Inventors: Tomita, Katsuhiko, Kotani, Haruo
• Primary Examiner(s): TUNG, TA HSUNG
• Application Number:
  US07/124,970
• Time in Patent Office: 686 Days
• Field of Search: 204/416-419, 204/414, 204/435, 204/420
• US Class Current: 204/414
• CPC Class Codes: G01N 27/333 Ion-selective electrodes or membranes glass electrodes G01N27/36

Abstract

An improved electrode assembly of a modular configuration for sensing ion concentration includes a substrate mounted in a housing and being sandwiched by a first and second support layer of non-conductive material. A gelantinized solution is positioned in an opening between the first support layer and a substrate, while a second gelatinized solution is positioned in an opening between a second support layer and a substrate. Electric leads and electrodes are appropriately positioned on the substrate for operative contact with the respective gelatinized solutions. An ion-responsive member contacts one gelatinized solution, while an acqueous junction member extends through the respective support layers and substrates to contact another gelatinized solution.

Claims

1. In a sheet-configured electrode for use in the measurement of ion concentrations, the improvement comprising:

a substrate of a non-conducting material defining a throughhole;

an electrode assembly having a glass electrode disposed side by side to a reference electrode, each electrode having a different internal construction from the other, the glass electrode being provided with an internal electrode portion directly aligned with said throughhole and a lead portion, said portions being adhered to a lower surface of the substrate, the lower surface being opposite a side of the substrate from which a sample is received by the sheet-configured electrode, and

a support layer of non-conducting material formed over a portion of the electrode assembly while exposing the lead portion.

2. The invention of claim 1 wherein another support layer of a non-conducting material is positioned on the upper surface of the substrate.

3. The invention of claim 2 further including a selective ion-responsive membrane of the glass electrode on the other support layer, the other support layer having a throughhole aligned with the throughhole of the substrate, the ion-responsive membrane being positioned over the aligned throughholes.

4. The invention of claim 3 wherein a gelatinized internal solution is positioned in the throughhole in the other support layer.

5. An improved structure for sensing ion-concentration comprising:

a housing member;

a substrate mounted in the housing member;

a first support layer of a non-conductive material positioned directly over the substrate;

a second support layer of a non-conductive material positioned below the substrate, the substrate, first support layer and second support layer having appropriately positioned openings to define a conduit among them;

a first gelatinized solution communicating through openings between the first support layer and the substrate;

a second gelatinized solution communicating through openings between the second support layer and the substrate;

an ion-responsive membrane positioned across the first gelatinized solution and above the first support layer;

means providing an electrical lead portion and an internal electrode portion on a bottom portion of the substrate for operative contact with the first and second gelatinized solutions, the lead portion extending outside of the housing, and

an aqueous junction member extending through openings in the first support layer, second support layer, and the substrate.

6. The invention of claim 5 wherein the first gelatinized solution is mounted in an opening in the first support layer.

7. The invention of claim 5 wherein said internal electrode portion is mounted on the lower surface of the substrate and extends into an opening in the second support layer for contact with the second gelatinized solution.

8. The invention of claim 5 wherein the aqueous junction member is a porous sintered plug member that extends from a surface of the first support layer through the substrate and the second support layer to contact the second gelatinized solution.

9. The invention of claim 5 wherein the substrate, support layers and gelatinized solutions are formed in a sheet-like construction.

10. The invention of claim 5 wherein the substrate is opaque to incident light.

11. In an improved sheet-configured structure having an electrode assembly on a bottom surface of a substrate, said electrode assembly having a sensing electrode including an internal electrode portion and a lead portion, said structure receiving a sample from above a top surface of the substrate, the substrate having a throughhole therein, wherein the improvement comprises:

said substrate having an end edge portion on which said lead portion is disposed, and also having a central portion;

a first support layer directly interfacing said top surface such that said end edge portion remains exposed, said first support layer having a first throughhole therein for communication between said sample and said electrode assembly, said first throughhole being directly aligned with said substrate throughhole; and

a second support layer directly interfacing said bottom surface and having a second throughhole therein such that said second support layer covers said central portion while leaving said end edge portion exposed.

12. The improvement of claim 11 further including an internal solution layer directly interfacing said second support layer from a side opposite to that on which said electrode assembly is located.

13. The improvement of claim 12 further including an internal solution element fixed in said first throughhole.