Flame retardant ternary blends of polyetherimide, polyphenylene ether and block copolymer of a vinyl aromatic hydrocarbon and an alkene compound

• US 4,873,287 A
• Filed: 12/30/1987
• Issued: 10/10/1989
• Est. Priority Date: 12/30/1987
• Status: Expired due to Term

• Current Assignee: General Electric Company
• Original Assignee: General Electric Company
• Inventors: Abolins, Visvaldis, Rock, John A., Holub, Fred F.
• Primary Examiner(s): Ziegler, Jacob
• Application Number:
  US07/139,575
• Time in Patent Office: 650 Days
• Field of Search: 525/92, 525/905, 525/397
• US Class Current: 525/92.00B
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 53/00 Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 71/00 Compositions of polyethers obtained by reactions forming an ether link in the main chain of polyacetals C08L59/00; of epoxy resins C08L63/00; of polythioether-ethers C08L81/02; of polyether-sulfones C08L81/06; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 71/12 Polyphenylene oxides
• CPC Class Codes: C08L 79/08 Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
• CPC Class Codes: Y10S 525/905 Polyphenylene oxide

Abstract

The present invention relate to a ternary polymer blend containing in admixture (a) a polyetherimide; (b) a polyphenylene ether; and (c) a block copolymer of a vinyl aromatic compound and an alkene compound. These ternary blends exhibit high glass transition temperatures and excellent flexural properties.

Claims

1. A ternary polymer blend comprising (a) a polyetherimide;

(b) a polyphenylene ether of the structural formula;

##STR12## wherein the oxygen ether atom of one structural unit is connected to the benzene nucleus of the next adjoining unit, b is a positive integer and is at least 50 and Y₁, Y₂, Y₃ and Y₄, which may be the same or different, are monovalent substituents selected from the group consisting of hydrogen, halogen, hydrocarbon radicals, halo-hydrocarbon radicals having at least two carbon atoms between the halogen atom and the benzene nucleus, hydrocarboxy radicals and halohydrocarboxy radicals having at least two carbon atoms between the halogen atom and the benzene nucleus; and

(c) a block copolymer of a vinyl aromatic compound (A) and an alkene compound (B), of the A-B-A type, the center block being of higher molecular weight than that of the combined terminal blocks.

2. The ternary polymer blend of claim 1, wherein said polyetherimide is of the formula:

##STR13## where "a" represents a whole number in excess of 1, e.g., 10 to 10,000 or more, the group --O--A is selected from;

##STR14## R'"'"' being hydrogen, lower alkyl or lower alkoxy;

Z is a member selected from the class consisting of (1);

##STR15## and (2) divalent organic radicals of the general formula;

##STR16## where X is a member selected from the class consisting of divalent radicals of the formulas, ##STR17## where q is 0 or 1, y is a whole number from 1 to 5, R is a divalent organic radical selected from the class consisting of (1) aromatic hydrocarbon radicals having from 6 to about 20 carbon atoms and halogenated derivative thereof, (2) alkylene radicals and cycloalkylene radicals having from about 2 to about 20 carbon atoms, C(_2-8) alkylene terminated polydiorganosiloxane, and (3) divalent radicals of the formula;

##STR18## where Q is a member selected from the class consisting of ##STR19## where x is a whole number from 1 to 5 inclusive.

3. The ternary polymer blend of claim 2 wherein Z is ##STR20## and R is selected from:

##STR21##

4. The ternary polymer blend of claim 3 wherein said polyetherimide is of the formula:

##STR22##

5. The ternary polymer blend of claim 1 wherein the vinyl aromatic compound is styrene and the alkene compound is selected from the group consisting of ethylene, butylene, isoprene, butadiene or mixtures thereof.

6. The ternary polymer blend of claim 5 wherein said alkene compound is ethylene and butylene.

7. The ternary polymer blend of claim 1 wherein said blend comprises from about 1 to about 94 percent by weight of said polyetherimide;

from about 1 to about 94 percent by weight of said polyphenylene ether; and

from about 5 to about 20 percent by weight of said block copolymer of a vinyl aromatic compound and an alkene compound.

8. The ternary blend of claim 7 wherein said blend comprises from about 5 to about 87 percent by weight of said polyetherimide;

from about 5 to about 87 percent by weight of said polyphenylene ether; and

from about 8 to about 15 percent by weight of said block copolymer of a vinyl aromatic compound and an alkene compound.