Method of forming volume phase reflection holograms

• US 4,874,213 A
• Filed: 06/09/1988
• Issued: 10/17/1989
• Est. Priority Date: 08/10/1987
• Status: Expired due to Term

• Current Assignee: Senshin Capital LLC (Intellectual Ventures LLC)
• Original Assignee: Polaroid Corporation (PLR IP Holdings LLC)
• Inventors: Cowan, James J.
• Primary Examiner(s): Arnold, Bruce Y.
• Assistant Examiner(s): NOT, DEFINED
• Application Number:
  US07/204,379
• Time in Patent Office: 495 Days
• Field of Search: 350/3.67, 350/3.69, 350/3.75, 350/3.77, 350/3.81, 350/3.82, 350/3.85, 350/3.86, 350/320
• US Class Current: 359/10
• CPC Class Codes: G02B 5/1857 using exposure or etching means, e.g. holography, photolithography, exposure to electron or ion beams
• CPC Class Codes: G03H 1/0244 Surface relief holograms replicating hologram without interference recording G03H1/0276
• CPC Class Codes: G03H 1/0248 Volume holograms
• CPC Class Codes: G03H 1/0252 Laminate comprising a hologram layer
• CPC Class Codes: G03H 1/028 by embossing
• CPC Class Codes: G03H 1/265 Angle multiplexing; Multichannel holograms G03H1/268 takes precedence
• CPC Class Codes: G03H 1/28 superimposed holograms only
• CPC Class Codes: G03H 2001/0296 Formation of the master hologram
• CPC Class Codes: G03H 2001/0413 for recording transmission holograms
• CPC Class Codes: G03H 2001/0415 for recording reflection holograms
• CPC Class Codes: G03H 2001/2231 Reflection reconstruction
• CPC Class Codes: G03H 2223/18 Prism
• CPC Class Codes: G03H 2260/63 Indirect etching, e.g. lithography photoresist G03H2260/14

Abstract

A hologram is fabricated by opening a volume phase reflection hologram formed in a recording medium such as a positive photoresist. The opening occurs by forming a second hologram, such as an off-axis hologram, in the same recording medium. The opening hologram can be replicated in metal and the metal can be used to emboss the fringe pattern of the opened hologram into plastic. A full range of colors in the visible spectrum may be obtained by metallizing the embossed plastic structure and then by overcoating it with appropriate clear dielectric layers.

Claims

1. A method for forming a volume phase reflection hologram comprising the steps of:

exposing a holographic phase medium by projecting onto one of its surfaces two beams disposed at an angle to one another to form in said medium interference fringes that are substantially perpendicular to said surface and have a predetermined periodicity; and

further exposing said medium with from opposite sides with two more beams to form therein interference fringes that are parallel to said medium surfaces and of finer periodically than that of said predetermined periodicity of said perpendicular fringes so that both said parallel and perpendicular interference fringes combine to provide as exposure pattern in said medium that varies in exposure level both over the surface and depth of said medium in the form of fine generally varying multiple steps distributed depthwise in the medium within a coarser surface pattern.

2. The method of claim 1 which further includes the step of coating the surface of the medium with a metal.

3. The method of claim 2 which further includes the step of overcoating the metal with a dielectric.

4. The method of claim 1 which further includes means for varying the angle with which the two beams enter the opposite sides of the medium.

5. The method of claim 1 further comprising the step of developing said medium to remove exposed material therefrom to provide a holographic stepped relief structure whose shape is substantially the complement of said exposure pattern.

6. The method of claim 1 wherein one of the beams used to further expose said medium from opposite sides thereof is a beam from an object.

7. The method of claim 6 wherein said medium is coated on a transparent substrate and said object is encapsulated in an index matching medium on the other side of said substrate and wherein said object is illuminated from a reference beam incident to the exposed surface of said medium whereby said parallel fringes are created by the interference between the reflection of the reference beam from the object with the incoming reference beam and said perpendicular fringes are created by the interference between the reflection of the reference beam off the interface between said substrate and said medium and the reference beam reflected from the object.

8. The method of claim 1 wherein the step of further exposing said medium from opposite sides thereof with two beams further comprises the step of placing a reflecting medium on one side thereof and projecting a single beam through said medium from one side thereof onto said reflecting medium to provide a reflected beam therefrom directed back through said medium from the same side on which the reflecting medium is placed so that the original beam and reflected beam interface to provide said parallel fringes.

9. The method of claim 1 wherein one of the beams used in making said further exposure of said medium is an object beam from a master hologram that is reconstructed by illuminating it with a reference beam.

10. The method of claim 9 wherein said holographic medium is disposed in front of and at a angle to a mirror and wherein a portion of the reference beam used to reconstruct said master hologram impinge on said mirror and is reflected thereby toward the other side of said holographic medium while another portion of said reference beam directly impinges on the other side of said holographic medium.

11. The method of claim 1 wherein the periodicity of both of said interference patterns is regular.

12. A method for forming a volume a volume phase reflection hologram comprising the steps of:

exposing a holographic phase medium to form in said medium interference fringes that are substantially perpendicular to said surface and have a predetermined periodicity; and

further exposing said medium from opposite sides with two more beams to form therein interference fringes that are parallel to said medium surfaces and of finer periodicity than that of said predetermined periodicity of said perpendicular fringes so that both said parallel and perpendicular interference fringes combine to provide an exposure pattern in said medium that varies in exposure level both over the surface and depth of said medium in the form of fine generally varying multiple steps distributed depthwise in the medium within a coarser surface pattern.