Bilayer electronically conductive polymers and process for their production

• US 4,874,735 A
• Filed: 06/22/1987
• Issued: 10/17/1989
• Est. Priority Date: 02/27/1987
• Status: Expired due to Fees

• Current Assignee: University of Victoria A Canadian University
• Original Assignee: University of Victoria
• Inventors: O'Brien, R. N., Santhanam, K. S. V.
• Primary Examiner(s): Rutledge, L. Dewayne
• Assistant Examiner(s): Wyszomierski, George
• Application Number:
  US07/064,468
• Time in Patent Office: 848 Days
• Field of Search: 502/159, 428/457, 428/463
• US Class Current: 502/159
• CPC Class Codes: B01D 71/72 Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, not provided for in a single one of the groups B01D71/46 - B01D71/70 and B01D71/701 - B01D71/702
• CPC Class Codes: C08G 61/121 derived from organic halides
• CPC Class Codes: H01B 1/127 comprising five-membered aromatic rings in the main chain, e.g. polypyrroles, polythiophenes
• CPC Class Codes: Y10T 428/31678 Of metal
• CPC Class Codes: Y10T 428/31699 Ester, halide or nitrile of addition polymer
• CPC Class Codes: Y10T 428/31909 Next to second addition polymer from unsaturated monomers

Abstract

A film is provided herein which may be either as a coherent coating on an electrode or as an unbacked film. The film is a bilayer, electronically-conducting film comprising an outer film of a polycarbazole and a base film of a polypyrrole. The bilayer film is formed by depositing a coherent coating, consisting of a polycarbazole-on-polypyrrole bilayer film on an electrode and then stripping the bilayer film from the electrode. The electrode may be, e.g., gold, silver, copper, a platinum group metal (ruthenium, rhodium, palladium, osmium, iridium and platinum, with platinum or palladium being preferred) or a first transition series metal (e.g. iron, cobalt, or nickel). These electronically-conducting films may have catalysts absorbed therein, to exhibit catalytic behavior, or they may be used for the development of macromolecular electronics.

Claims

1. An article comprising:

an outer metal substrate; and

a coherent coating thereon comprising a bilayer, electronically-conductive film consisting of an outer film of a polycarbazole and an intermediate film of a polypyrrole in contact with said outer metal substrate.

2. The article of claim 1 having a catalyst absorbed on at least one of the polycarbazole film and the polypyrrole film.

3. The article of claim 1 comprising an outer film of a polypyrrole, an intermediate film of a polycarbazole having a catalyst absorbed thereon, and an outer metal substrate.

4. The article of claim 1 comprising an outer film of a polycarbazole, an intermediate film of a polypyrrole having a catalyst absorbed thereon, and an outer metal substrate.

5. The article of claim 1 comprising an outer film of a polypyrrole, having a catalyst absorbed thereon, an intermediate film of a polycarbazole having a catalyst absorbed thereon, and an outer metal substrate.

6. The article of claim 1 comprising an outer film of a polycarbazole having a catalyst absorbed thereon, an intermediate film of a polypyrrole having a catalyst absorbed thereon, and an outer metal substrate.

7. The article of claim 1 wherein the metal substrate is selected from the group consisting of gold, silver, copper, ruthenium, rhodium, palladium, osmium, iridium, platinum, iron, cobalt and nickel.

8. The article of claim 1 wherein the metal substrate is silver or copper, each said metal substrate having a few atomic layers of platinum or gold evaporated into the surface thereof.

9. An article comprising:

a bilayer, electronically-conductive film comprising an outer film of a polycarbazole and a base film of a polypyrrole, said bilayer film having been stripped from an electrode on which a coherent coating, consisting of said bilayer film had previously been applied, the polypyrrole component of said bilayer film having previously been in contact with said electrode.

10. The article of claim 9 having a catalyst absorbed on at least one of the polycarbazole film and the polypyrrole film.

11. The article of claim 9 comprising an outer film of a polypyrrole, and a base film of a polycarbazole having a catalyst absorbed thereon, said base film having previously been in contact with said electrode.

12. The article of claim 9 comprising an outer film of a polycarbazole, and a base film of a polypyrrole having a catalyst absorbed thereon, said base film having previously been in contact with said electrode.

13. The article of claim 9 comprising an outer film of a polypyrrole having a catalyst absorbed thereon, and a base film of a polycarbazole having a catalyst absorbed thereon, said base film having previously been in contact with said electrode.

14. The article of claim 9 comprising an outer film of a polycarbazole having a catalyst absorbed thereon, and a base film of a polypyrrole having a catalyst absorbed thereon, said base film having previously been in contact with said electrode.

15. The article of claim 9 wherein said electrode is formed from a metal selected from the group consisting of gold, silver, copper, ruthenium, rhodium, palladium, osmium, iridium, platinum, iron, cobalt and nickel.

16. The article of claim 9 wherein said electrode is formed from silver or copper, each said metal substrate having a few atomic layers of platinum of gold evaporated into the surface thereof.