Method for making electrically conductive textile materials

• US 4,877,646 A
• Filed: 06/27/1988
• Issued: 10/31/1989
• Est. Priority Date: 06/27/1988
• Status: Expired due to Term

• Current Assignee: Milliken & Company
• Original Assignee: Milliken Research Corporation
• Inventors: Kimbrell, William C. Jr., Kuhn, Hans H.
• Primary Examiner(s): LUSIGNAN, MICHAEL R
• Application Number:
  US07/211,630
• Time in Patent Office: 491 Days
• Field of Search: 427/121, 427/341, 427/342, 427/389.9, 428/265, 428/267, 428/395
• US Class Current: 427/121
• CPC Class Codes: D06M 13/188 Monocarboxylic acids; Anhydrides, halides or salts thereof D06M13/1845 takes precedence
• CPC Class Codes: D06M 13/256 Sulfonated compounds esters thereof, e.g. sultones
• CPC Class Codes: D06M 13/352 having five-membered heterocyclic rings
• CPC Class Codes: H01B 1/127 comprising five-membered aromatic rings in the main chain, e.g. polypyrroles, polythiophenes
• CPC Class Codes: Y10T 428/2969 Polyamide, polyimide or polyester
• CPC Class Codes: Y10T 442/2459 Nitrogen containing

Abstract

Fabrics are made electrically conductive by contacting the fiber under agitation conditions with an aqueous solution of a pyrrole compound, an oxidizing agent and a doping agent or counter ion and then depositing onto the surface of individual fibers of the fabric a prepolymer of the pyrrole compound so as to uniformly and coherently cover the fibers with a conductive film of the polymerized pyrrole compound and wherein, furthermore, the oxidizing agent is a ferric salt and the aqueous solution further contains a weak complexing agent for ferric ions to effectively control the reaction rate such that the prepolymer is uniformly and coherently adsorbed onto the surface of the textile material, thereby providing improved films of electrically conductive polymerized compound on the textile material.

Claims

1. A method for imparting electrical conductivity to a textile material, which comprises:

(a) contacting the textile material with an aqueous solution of an oxidatively polymerizable pyrrole compound and an oxidizing agent capable of oxidizing said compound to a polymer, said contacting being carried out in the presence of a counter ion or doping agent which imparts electrical conductivity to said polymer when fully formed, said contacting being under conditions at which the pyrrole compound and the oxidizing agent react with each other to form a prepolymer in said aqueous solution;

(b) depositing onto the surface of the textile material the prepolymer of the polymerizable compound; and

(c) allowing the prepolymer to polymerize while deposited on the textile material so as to uniformly and coherently cover the textile material with a conductive film of polymerized compound;

the improvement wherein in step (a) a ferric salt is used as the oxidizing agent and a weak complexing agent for ferric ions is included in the aqueous solution, in an amount sufficient to effectively control the polymerization rate of steps (b) and (c) such that the prepolymer is uniformly and coherently adsorbed onto the surface of the textile material while effectively avoiding undesired formation of polymer in solution.

2. The method of claim 1 wherein said pyrrole compound is selected from the group consisting of pyrrole, a 3- and 3,4-alkyl or aryl substituted pyrrole, N-alkyl pyrrole and N-aryl pyrrole.

3. The method of claim 1 wherein said weak complexing agent is selected from aromatic, hydroxycarboxylic acids, and aromatic, hydroxysulfonic acids.

4. The method of claim 3 wherein said weak complexing agent is sulfosalicylic acid.

5. The method of claim 1 wherein said pyrrole compound is present in said solution in an amount of from about 0.01 to 5 grams per liter.

6. The method of claim 1 wherein said textile material comprises a knitted, woven or non-woven fibrous textile fabric.

7. The method of claim 6 where the fibers of said fabric are uniformly and coherently covered with said conductive film to a thickness of from about 0.05 to about 2 microns.

8. The method of claim 6 wherein said textile fabric is constructed of continuous filament yarns.

9. The method of claim 8 wherein said textile fabric comprises synthetic fibers selected from the group consisting of polyester, nylon and acrylic fibers.

10. The method of claim 8 wherein said textile fabric comprises high modulus fibers selected from aromatic polyester, aromatic polyamide and polybenzimidazole fibers.

11. The method of claim 8 wherein said textile material comprises high modulus inorganic fibers selected from glass and ceramic fibers.

12. The method of claim 7 wherein said treated textile fabric has a resistivity from about 50 to about 500,000 ohms per square.

13. The method of claim 7 wherein said textile material is or is comprised of basic dyeable polyester fibers.

14. The method of claim 1 wherein said textile material comprises a wound yarn, filament or fiber.

15. The method of claim 1 wherein said pyrrole compound is pyrrole, N-methylpyrrole or a mixture of pyrrole and N-methylpyrrole.

16. The method of claim 1 wherein said counter ion is an anionic counter ion selected from the group consisting of chloride, sulfate, alkyl or aryl-sulfonic acid, and aryl disulfonic acids.

17. An electrically conductive textile material which is the product of the process of claim 1, having a resistivity in the range of from about 50 to about 10⁶ ohms per square.

18. The electrically conductive material of claim 17 which is a fabric comprised of fibers, filaments or yarns of polyester or polyamide.

19. The electrically conductive material of claim 17 wherein the pyrrole compound is pyrrole and the polypyrrole film has a thickness of less than about 2 microns.