Laminates containing coextruded scrap

• US 4,877,682 A
• Filed: 02/24/1988
• Issued: 10/31/1989
• Est. Priority Date: 03/24/1986
• Status: Expired due to Fees

• Current Assignee: Amoco Corporation (BP PLC)
• Original Assignee: Amoco Corporation (BP PLC)
• Inventors: McMaster, Lee P., Hartsing, Tyler F. Jr., Sauers, Marvin E.
• Primary Examiner(s): Swisher, Nancy A. B.
• Application Number:
  US07/160,458
• Time in Patent Office: 615 Days
• Field of Search: 428/35, 428/412, 428/419, 428/473.5, 428/474.9, 428/475.8, 428/515, 428/903.3, 521/40, 156/244.11, 264/171, 264/DIG. 69, 264/37
• US Class Current: 428/412
• CPC Class Codes: B29B 17/00 Recovery of plastics or other constituents of waste material containing plastics; volume reduction of waste plastics, e.g. by mechanical compacting or melting disposal of solid waste B09B; chemical recovery C08J11/00
• CPC Class Codes: B29L 2009/00 Layered products
• CPC Class Codes: B29L 2031/712 Containers; Packaging elements or accessories, Packages closures therefor B29L2031/56; ink or toner cartridges B29L2031/7678; squeeze tubes B29L2023/20; suitcases B29L2031/7418
• CPC Class Codes: B32B 2272/00 Resin or rubber layer comprising scrap, waste or recycling material
• CPC Class Codes: B32B 2367/00 Polyesters, e.g. PET, i.e. polyethylene terephthalate
• CPC Class Codes: B32B 2369/00 Polycarbonates
• CPC Class Codes: B32B 2379/08 Polyimides
• CPC Class Codes: B32B 2439/70 Food packaging
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/281 comprising polyimides
• CPC Class Codes: B32B 27/286 comprising polysulphones; polysulfides
• CPC Class Codes: B32B 27/32 comprising polyolefins comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30
• CPC Class Codes: B32B 27/36 comprising polyesters
• CPC Class Codes: B32B 27/365 comprising polycarbonates
• CPC Class Codes: C08J 11/06 without chemical reactions
• CPC Class Codes: Y02W 30/62 Plastics recycling; Rubber recycling
• CPC Class Codes: Y10T 428/1352 Polymer or resin containing [i.e., natural or synthetic]
• CPC Class Codes: Y10T 428/31507 Of polycarbonate
• CPC Class Codes: Y10T 428/31533 Of polythioether
• CPC Class Codes: Y10T 428/31721 Of polyimide
• CPC Class Codes: Y10T 428/31732 : At least one layer is nylon type
• CPC Class Codes: Y10T 428/31743 : Next to addition polymer from unsaturated monomer[s]
• CPC Class Codes: Y10T 428/31909 : Next to second addition polymer from unsaturated monomers

Abstract

A continuous plastic laminate having improved stiffness at use temperature, comprising at least three melt coextruded sheets, each comprising a thermoplastic polymer or polymer blend, the outside sheets having a higher stiffness at use temperature than at least one inside sheet.

wherein said continuous laminate laminate scrap derived from the production of said laminate, said scrap being incorporated therein by melt coextruding said scrap as at least one additional discrete inside layer or by melt coextruding said scrap as part of at least one of said melt coextruded sheets,

whereby the stiffness at use temperature of said scrap-containing laminate is increased relative to a plastic laminate identical thereto except for the incorporation of said scrap, and

wherein said thermoplastic polymer or polymer blend comprises a polyarylethersulfone, a poly(aryl ether), a polyarylate, a polyetherimide, a polyester, an aromatic polycarbonate, a styrene resin, a poly(alkyl), a polyhydroxyether, a polyamide, a poly(arylene sulfide), a crystalline polyolefin, a polyphenylene oxide, or blends thereof.

Claims

1. A continuous plastic laminate comprising at least three melt coextruded sheets, each sheet comprising at least one thermoplastic polymer, the outside sheets having a higher stiffness at use temperature than at least one inside sheet, said inside sheet comprising laminate scrap derived from the production of said laminate comprising a blend of a thermoplastic polymer A and thermoplastic polymer B, thermoplastic polymer A having a higher glass transition temperature than thermoplastic polymer B and said outside sheets comprising thermoplastic polymer A, wherein said thermoplastic polymers are selected from the group consisting of one or more of the following:

a polyrylethersulfone, a poly(aryl ether), a polyarylate, a polyetherimide, a polyester, an aromatic polycarbonate, a styrene resin, a poly(alkyl acrylate), a polyhydroxyether, a polyamide, a poly(arylene sulfide), a crystalline polyolefin, and a polyphenylene oxide;

said laminate comprising the following;

space="preserve" listing-type="equation">A/ABA/B/A,

space="preserve" listing-type="equation">A/B/ABA/A,

space="preserve" listing-type="equation">A/ABA/B/ABA/A,

space="preserve" listing-type="equation">AABA/B/A,

space="preserve" listing-type="equation">A/B/AABA,

space="preserve" listing-type="equation">AABA/B/AABA,

space="preserve" listing-type="equation">A/ABAB/A,

space="preserve" listing-type="equation">AABA/ABAB/A,

space="preserve" listing-type="equation">A/ABAB/AABA, or

space="preserve" listing-type="equation">AABA/ABAB/AABA.

2. A continuous plastic laminate as defined in claim 1, wherein at least one layer of said laminate comprises a polyphenylene oxide having the formula:

##STR68## wherein the groups represented by R₂₅ may be the same or different and each represents a hydrogen atom or an alkyl radical containing from 1 to 4 carbon atoms,

X represents a group ##STR69## in which R₂₆ represents hydrogen or an alkyl radical containing from 1 to 4 carbon atoms, and

m and n represent an integer from 0 to 200.

3. A continuous plastic laminate, as defined in claim 1, which is suitable for use at a temperature between about 350°

and about 450°

F.

4. A continuous plastic laminate, as defined in claim 1, wherein at least two of the thermoplastic polymers comprising the sheets therein are melt incompatible.

5. A continuous plastic laminate, as defined in claim 1, wherein said laminate scrap is incorporated therein as at least one additional discrete inside sheet contiguous with at least one of said two outside sheets.

6. A continuous plastic laminate, as defined in claim 5, wherein said scrap is incorporated as two additional discrete inside sheets, each contiguous with an outside sheet.

7. A continuous plastic laminate, as defined in claim 1, wherein said scrap replaces a substantially equal volume of thermoplastic material from at least one inside sheet having a lower use temperature than said outside sheets.

8. A continuous plastic laminate, as defined in claim 1, wherein wherein at least one layer of said laminate comprises a polyarylethersulfone containing units of the following formula:

##STR70## wherein R is independently hydrogen, C₁ to C₆ alkyl or C₄ to C₈ cycloalkyl, X'"'"' is independently ##STR71## wherein R₁ and R₂ are independently hydrogen or C₁ to C₉ alkyl, or ##STR72## wherein R₃ and R₄ are independently hydrogen or C₁ to C₈ alkyl, --S--, --O--, or ##STR73## a is an integer of 0 to 4, a'"'"' is an integer of 3 to 8, and n is independently an integer of 1 to 3 and wherein the ratio of unit (I) to the sum of units (II) and/or (III) is greater than 1, wherein the units are attached to each other by an --O-- bond.

9. A continuous plastic laminate as defined in claim 8, wherein said polyarylethersulfone contains recurring units of the formula:

##STR74## said units being attached to each other an --O-- bond.

10. A continuous plastic laminate as defined in claim 8, wherein said polyarylethersulfone contains recurring units of the formula:

##STR75##

11. A continuous plastic laminate as defined in claim 1, wherein at least one layer of said laminate comprises a poly(arylether) containing recurring units of the following formula:

space="preserve" listing-type="equation">--O--E--O--E'"'"'--

wherein E is the residuum of a dihydric phenol, and E'"'"' is the residuum of a benzenoid compound having an inert electron withdrawing group in at least one of the positions ortho and para to the valence bonds;

both of said residua are valently bonded to the ether oxygens through aromatic carbon atoms.

12. A continuous plastic laminate as defined in claim 11, wherein said poly (aryl ether) contains units of the following formula:

##STR76##

13. A continuous plastic laminate as defined in claim 1, wherein at least one layer of said laminate comprises a polyarylate derived from a dihydric phenol and at least one aromatic dicarboxylic acid.

14. A continuous plastic laminate as defined in claim 13, wherein the polyarylate is derived from bisphenol A and terephthalic acid or isophthalic acid, or mixtures thereof.

15. A continuous plastic laminate as defined in claim 1, wherein at least one layer of said laminate comprises a polyetherimide polymer of the following formula:

##STR77## wherein e is an integer greater than 1, preferably from about 10 to about 10,000 or more, --O--R₁₂ --O-- is attached to the 3 or 4 and 3'"'"' or 4'"'"' positions and R₁₂ is selected from the group consisting of

(a) a substituted or unsubstituted aromatic radical such as ##STR78## (b) a divalent radical of the formula;

##STR79## wherein R₁₄ is independently C₁ to C₆ alkyl, aryl, or halogen and R₁₅ is selected from --O--, --S--, --C--, --SO₂ --, --SO--, alkylene of 1 to 6 carbon atoms, cycloalkylene of 4 to 8 carbon atoms, alkylidene of 1 to 6 carbon atoms or cycloalkylidene of 4 to 8 carbon atoms, R₁₃ is selected from an aromatic hydrocarbon radical having from 6 to 20 carbon atoms and halogenated derivatives thereof, or alkyl substituted derivatives thereof, wherein the alkyl group contains 1 to 6 carbon atoms, alkylene and cycloalkylene radicals having from 2 to 20 carbon atoms and C₂ to C₈ alkylene terminated polydiorganosiloxane or a divalent radical of the formula;

##STR80## wherein R₁₄ and R₁₅ are as previously defined.

16. A continuous plastic laminate as defined in claim 1, wherein at least one layer of said laminate comprises a polyether imide of the following formula:

##STR81## wherein --O--Z is a member selected from the group consisting of ##STR82## wherein R₁₆ is independently hydrogen, lower alkyl or lower alkoxy ##STR83## wherein the oxygen may be attached to either ring and located ortho or para to one of the bonds of the imide carbonyl groups, R₁₂ and R₁₃ and e are as defined in claim 15.

17. A continuous plastic laminate, as defined in claim 1, wherein at least one layer of said laminate comprises a polyetherimide having repeating units of the following formula:

##STR84##

18. A continuous plastic laminate as defined in claim 1, wherein at least one layer of said laminate comprises a polyester having repeating units of the general formula:

##STR85## wherein n is an integer of from 2 to 10.

19. A continuous plastic laminate as defined in claim 1, wherein at least one layer of said laminate comprises a polyester which is poly(ethylene terephthalate).

20. A continuous plastic laminate as defined in claim 1, wherein at least one layer of said laminate comprises an aromatic polycarbonate which is the reaction product of a dihydric phenol and a carbonate precursor.

21. A continuous plastic laminate as defined in claim 20, wherein said dihydric phenol is bisphenol A and the carbonate precursor is carbonyl chloride.

22. A continuous plastic laminate as defined in claim 1, wherein at least one layer of said laminate comprises a polycarbonated which is a poly(ester carbonate).

23. A continuous plastic laminate as defined in claim 1, wherein at least one layer of said laminate comprises a polycarbonate which is a polyaromatic sulfone carbonate.

24. A continuous plastic laminate as defined in claim 1, wherein at least one layer of said laminate comprises a styrene resin prepared by polymerizing a conjugated diene monomer, or a conjugated diene monomer and monomer copolymerizable therewith, or an acrylic acid ester, to provide an elastomeric backbone, and thereafter grafting at least one grafting monomer onto said backbone.

25. A continuous plastic laminate as defined in claim 1, wherein at least one layer of said laminate comprises a styrene resin which is a butadiene/styrene/acrylonitrile resin.

26. A continuous plastic laminate as defined in claim 1, wherein at least one layer of said laminate comprises a poly(alkyl acrylate) which is poly(methyl methacrylate).

27. A continuous plastic laminate as defined in claim 1, wherein at least one layer of said laminate comprises a polyhydroxyether having the following general formula:

space="preserve" listing-type="equation">--H--O--H'"'"'--O--.sub.j'"'"'

where H is the radical, residuum of a dihydric phenol, H'"'"' is a radical residuum of an epoxide selected from mono- and diepoxides and which contain from 1 to 2 hydroxyl groups, and j'"'"' is an integer which represents the degree of polymerization and is at least 30.

28. A continuous plastic laminate as defined in claim 1, wherein at least one layer of said laminate comprises a polyamide selected from the group consisting of nylon 6,6, nylon 6, or nylon 6,10.

29. A continuous plastic laminate as defined in claim 1, wherein at least one layer of said laminate comprises a poly(arylene sulfide) of the following formula:

##STR86## wherein p has a value of at least about 50.

30. A continuous plastic laminate as defined in claim 1, wherein at least one layer of said laminate comprises polyolefin selected from the group consisting of crystalline polyethylene, crystalline polypropylene, and ethylene-propylene copolymers.

31. A continuous plastic laminate as defined in claim 1, wherein at least one layer of said lamiate comprises a polyphenylene oxide which is a monofunctional polyphenylene oxide having an average hydroxyl group per molecule value greater than zero.

32. A continuous plastic laminate as defined in claim 1, wherein at least one layer of said laminate comprises a polyphenylene oxide which is a block copolymer containing polyphenylene oxide blocks which are coupled.

33. A continuous plastic laminate as defined in claim 1, wherein at least one layer of said laminate comprises a polyphenylene oxide blend.

34. A laminate as defined in claim 1, in the form of cookware.

35. A laminate as defined in claim 1, in the form of a container for hot food.

36. A laminate as defined in claim 1, in the form of a sterilizable container.

37. A continuous plastic laminate, as defined in claim 1, wherein thermoplastic polymer A is a polyetherimide.

38. A continuous plastic laminate, as defined in claim 1, wherein thermoplastic polymer B is a poly(ester carbonate).

39. A continuous plastic laminate, as defined in claim 1, which comprises five melt coextruded sheets.