Piezoelectric and pyroelectric polymers

• US 4,877,988 A
• Filed: 05/22/1985
• Issued: 10/31/1989
• Est. Priority Date: 03/01/1982
• Status: Expired due to Fees

• Current Assignee: Battelle Memorial Institute
• Original Assignee: Battelle Memorial Institute
• Inventors: McGinniss, Vincent D., Preston, Joseph R.
• Primary Examiner(s): BUDD, MARK OSBORNE
• Application Number:
  US06/736,982
• Time in Patent Office: 1,623 Days
• Field of Search: 310/306, 310/311, 310/800, 310/357
• US Class Current: 310/306
• CPC Class Codes: H10N 15/15 Thermoelectric active materials
• CPC Class Codes: H10N 30/857 Macromolecular compositions
• CPC Class Codes: Y10S 310/80 Piezoelectric polymers, e.g. PVDF

Abstract

Disclosed are new piezoelectric/pyroelectric materials of polarized homopolymer and copolymers of trifluorovinyl acetate. Also disclosed is a unique predictive relationship for determining the piezoelectricity of unknown material.

Claims

1. A pyroelectric element comprising a polarized copolymer or homopolymer of trifluorovinyl acetate disposed between two electrodes.

2. The element of claim 1 wherein said polarized trifluorovinyl acetate is in homopolymer form.

3. The element of claim 1 wherein said polarized trifluorovinyl acetate is in copolymer form.

4. The element of claim 3 wherein said copolymer is of trifluorovinyl acetate and an ethylenically unsaturated compound.

5. The element of claim 4 wherein said ethylenically unsaturated compound is selected from the group consisting of styrene, methyl methacrylate, trifluoroethyl methacrylate, tetrafluoroethylene, vinyl chloride, acrylonitrile, and combinations thereof.

6. The element of claim 1 wherein said polarized copolymer or homopolymer of trifluorovinyl acetate is a thin film thereof having an electrode disposed on both surfaces thereof.

7. A method for converting thermal energy into electrical energy through a pyroelectric transducer which comprises converting said energies through a pyroelectric element comprising a polarized copolymer or homopolymer of trifluorovinyl acetate interposed between two electrodes.

8. The method of claim 7 wherein said thin film is of polarized polytrifluorovinyl acetate homopolymer.

9. The method of claim 7 wherein said thin film is of polarized copolymer of trifluorovinyl acetate.

10. The method of claim 9 wherein said copolymer is of trifluorovinyl acetate and an ethylenically unsaturated compound.

11. The method of claim 10 wherein said ethylenically unsaturated compound is selected from the group consisting of styrene, methyl methacrylate, trifluoroethyl methacrylate, tetrafluoroethylene, vinyl chloride, acrylonitrile, and combinations thereof.