Conductive resin composition and molded product using the same

• US 4,882,227 A
• Filed: 03/09/1988
• Issued: 11/21/1989
• Est. Priority Date: 03/09/1987
• Status: Expired due to Fees

• Current Assignee: Toshiba Chemical Corp. (Kyocera Corporation)
• Original Assignee: Toshiba Chemical Corp. (Kyocera Corporation)
• Inventors: Habata, Keiichi, Iwase, Hidehiro
• Primary Examiner(s): Bleutge, John C.
• Assistant Examiner(s): Buttner, David
• Application Number:
  US07/165,905
• Time in Patent Office: 622 Days
• Field of Search: 523/137, 523/205, 524/439, 524/440, 524/441, 524/117, 524/120, 524/151, 524/239, 524/270, 524/274, 524/320, 524/322, 252/512, 252/513, 428/407, 428/361, 428/379, 428/381, 428/385
• US Class Current: 428/407
• CPC Class Codes: B29B 9/14 fibre-reinforced
• CPC Class Codes: D04H 1/42 characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
• CPC Class Codes: G21F 1/125 comprising metals
• CPC Class Codes: H01B 1/22 the conductive material comprising metals or alloys
• CPC Class Codes: H05K 9/009 comprising electro-conductive fibres, e.g. metal fibres, carbon fibres, metallised textile fibres, electro-conductive mesh, woven, non-woven mat, fleece, cross-linked
• CPC Class Codes: Y10T 428/2907 with coating or impregnation
• CPC Class Codes: Y10T 428/294 including metal or compound thereof [excluding glass, ceramic and asbestos]
• CPC Class Codes: Y10T 428/2944 Free metal in coating
• CPC Class Codes: Y10T 428/2951 Metal with weld modifying or stabilizing coating [e.g., flux, slag, producer, etc.]
• CPC Class Codes: Y10T 428/2998 including synthetic resin or polymer

Abstract

There is provided an electric conductive resin composition formed into a pellet, which includes an electric conductive filler comprising electric conductive fibers and a low-melting point metal, and being coated on the surface thereof with a thermoplastic resin. Flux and/or a phosphorus-based antioxidant may be added to the filler. There is also provided an electromagnetic wave shielding molded product prepared by using the electric conductive resin composition mentioned above, wherein the electric conductive fibers dispersed within the molded product are fixed each other through the low-melting point metal.

Claims

1. A pelletized conductive resin composition comprising a thermoplastic resin layer formed on the surface of a conductive filler comprising conductive fibers and a low-melting point metal having a melting point higher than that of the thermoplastic resin and lower than the molding temperature of the conductive resin composition, and an effective amount of a phosphorus-based antioxidant to improve the wettability of the conductive fibers.

2. A composition according to claim 1, wherein a content of the conductive fibers is 0.5 to 80 wt% with respect to a total weight of the conductive resin composition, and a content of the low-melting point metal is 5 to 30 wt% with respect to the content of the conductive fibers.

3. A composition according to claim 1, wherein the conductive fibers comprise metal fibers.

4. A composition according to claim 3, wherein the metal fibers are at least one material selected from the group consisting of a copper fiber, a stainless steel fiber, a brass fiber, an aluminum fiber, and a nickel fiber.

5. A composition according to claim 3, wherein the metal fibers comprise copper fibers.

6. A composition according to claim 1, wherein the conductive fibers comprise organic or inorganic fibers covered with a metal layer.

7. A composition according to claim 6, wherein the metal layer is made of a material selected from the group consisting of copper, aluminum and nickel.

8. A composition according to claim 1, wherein each of the conductive fibers has a diameter falling within a range of 5 to 100 μ

m.

9. A composition according to claim 8, wherein 100 to 10,000 conductive fibers are contained per pellet.

10. A composition according to claim 1, wherein the low-melting point metal is at least one metal selected from the group consisting of tin (Sn) and tin-zinc (Sn-Pb).

11. A composition according to claim 1, wherein the low-melting point metal is fibrous.

12. A composition according to claim 1, wherein the low-melting point metal is granular.

13. A composition according to claim 1, wherein the low-melting point metal covers at least part of a surface of the conductive fibers.

14. A composition according to claim 1, further comprising a flux.

15. A composition according to claim 14, wherein a content of the flux is 0.1 to 5 wt% with respect to a content of the low-melting metal.

16. A composition according to claim 14, wherein the flux is an organic acid flux.

17. A composition according to claim 16, wherein the organic acid flux is an organic acid selected from the group consisting of stearic acid, lactic acid, oleic acid, and glutamic acid.

18. A composition according to claim 14, wherein the flux is a resin flux.

19. A composition according to claim 18, wherein the resin flux is a resin selected from the group consisting of rosin and synthetic rosin having a reactive group.

20. A composition according to claim 1, wherein the content of the phosphorus-based antioxidant is 0.1 to 5 wt% with respect to the content of the thermoplastic resin.

21. A composition according to claim 1, wherein the phosphorus-based antioxidant is mixed in the thermoplastic resin layer.

22. A composition according to claim 1, wherein the thermoplastic resin is a resin selected from the group consisting of polypropylene resin, polyethylene resin, polystyrene resin, acrylonitrile-butadiene-styrene resin, denatured polyphenylene oxide resin, polybutylene terephthalate resin, polycarbonate resin, polyamide resin, and polyetherimide resin.

23. A conductive resin composition comprising master pellets consisting of a mixture of a conductive resin composition as defined in claim 1, and thermoplastic resin pellets.

24. A conductive resin composition comprising master pellets consisting of a mixture of a conductive resin composition as defined in claim 14, and thermoplastic resin pellets.

25. A conductive resin composition according to claim 1, wherein the thermoplastic resin is present substantially only in said thermoplastic resin layer.

26. A conductive resin composition according to claim 14, wherein the thermoplastic resin is present substantially only in said thermoplastic resin layer.

27. An electromagnetic wave shielding molded product prepared by molding the conductive resin composition of claim 1 at a temperature higher than the melting point of the low-melting point metal.

28. An electromagnetic wave shielding molded product prepared by molding the conductive resin composition of claim 14 at a temperature higher than the melting point of the low-melting point metal.

29. An electromagnetic wave shielding molded product prepared by molding the conductive resin composition of claim 23 at a temperature higher than the melting point of the low-melting point metal.

30. An electromagnetic wave shielding molded product prepared by molding the conductive resin composition of claim 24 at a temperature higher than the melting point of the low-melting point metal.